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In the Beginning was Information

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For some laws of nature <strong>the</strong> direction does not play any role (e. g.energy), but for o<strong>the</strong>rs <strong>the</strong> process is unidirectional like a one-waystreet. <strong>In</strong> <strong>the</strong> latter case one can clearly distinguish between pastand future. <strong>In</strong> all cases where friction is involved, <strong>the</strong> processes areirreversible; <strong>the</strong>y proceed in one direction only. Examples of suchlaws are <strong>the</strong> law of entropy (see <strong>the</strong> Appendix), <strong>the</strong> chemicalprinciple of Le Chatelier (Henry Le Chatelier, French chemist,1850 – 1936; see Q20 pp. 128-130), and <strong>the</strong> law of mass action.Impossibility <strong>the</strong>orems: Most laws of nature can be expressed in<strong>the</strong> form: “It is impossible that ...” The energy law for example, canbe stated as follows: “It is impossible that energy can come intoexistence by itself.” R. Clausius formulated <strong>the</strong> second law of <strong>the</strong>rmodynamicsas an impossibility: “Heat cannot of itself pass from acolder to a hotter body” The impossibility <strong>the</strong>orems are very useful,because <strong>the</strong>y effectively distinguish between possible and impossibleevents. This type of scientific formulation will be encounteredfrequently when we come to <strong>the</strong> information <strong>the</strong>orems.Geometrical impossibilities can also be devised. Three differentgeometric representations appear in Figure 6, but such bodies arejust as impossible to construct as it is to expect results that are precludedby laws of nature.Laws which describe processes: If <strong>the</strong> future (prognosis) or <strong>the</strong>past (retrognosis) states of a system can be described when <strong>the</strong> valuesof <strong>the</strong> relevant variables are known for at least one moment intime, such a formulation is known as a process law. A typical physicalexample is <strong>the</strong> description of radio-active decay.Co-existence laws: These describe <strong>the</strong> simultaneous existence of<strong>the</strong> properties of a system. The formula describing <strong>the</strong> statechanges of an ideal gas, p x v = R x T, is a typical physical coexistencelaw. The values of <strong>the</strong> three quantities, pressure p, specificvolume v, and absolute temperature T, comprise a completedescription of <strong>the</strong> “state” of an ideal gas. This means that it doesnot depend on <strong>the</strong> previous history of <strong>the</strong> gas, and nei<strong>the</strong>r doesit depend on <strong>the</strong> way <strong>the</strong> present pressure or <strong>the</strong> present volumehas been obtained. Quantities of this type are known as state variables.38

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