Collaborate Spray Oil

Collaborate Spray OilProduct Name:Recommended Use:Section 1: SUBSTANCE IDENTIFICATION AND SUPPLIERCOLLABORATE SPRAY OILA spray oil for use with certain herbicides, insecticides and fungicidesCompany Identification:Ravensdown Fertiliser Co-operative LimitedAddress: Level 132 Oxford TerraceChristchurchCustomer Centre: 0800 100 123National Poisons Information Centre: 0800 POISON (0800 764 766)Emergency Telephone Number:Transport Emergency:0800 CHEMCALL (0800 243 622) (24hr) (Emergencies Only)111 Fire and PoliceHazard Classifications: 6.1E, 9.3APriority Identifiers:Secondary Identifiers:Section 2: HAZARD IDENTIFICATIONHARMFULECOTOXIC6.1E = May be harmful if swallowed, inhaled or absorbed through the skin9.3A = Very toxic to terrestrial vertebratesSection 3: COMPOSITION INFORMATIONINGREDIENT CAS No. CONTENTSuperior Paraffin Base Petroleum Oil 8012-95-1 83%Polyoxyethylated Polyol Fatty Acid Ester,68131-40-8Polyol Fatty Acid Ester and Antifoam9016-45-917%Section 4: FIRST AID MEASURESREVISED: 19/07/2012First Aid Measures:Inhalation:Ingestion:Skin:Eye:Advice to Doctor:Consult the National Poisons Centre on 0800 POISON (0800 764 766) or a doctor immediately in every caseof suspected poisoning.Remove patient to fresh air. Lay down and keep warm and rested. If breathing is shallow or has stoppedensure airway is clear and apply resuscitation. Seek medical assistance immediately.Never give anything by mouth to an unconscious person. If swallowed DO NOT induce vomiting. For advice,contact the National Poisons Centre on 0800 POISON (0800 764 766). Seek medical assistance immediately.Remove contaminated clothing and wash affected area thoroughly with soap and water. If a large area isaffected seek medical assistance.Flush with plenty of water holding eyelids open if necessary.No specific antidote. Treat symptomaticallySection 5: FIRE FIGHTING MEASURESFlammability:Hazardous Combustion Products:Extinguishing Media:If involved in a fire this product will not burn.If involved in a fire, may evolve carbon monoxideWater fog, foam, carbon dioxide or dry chemicalCollaborate Spray Oil Page 1 of 3

Protective Equipment:HAZCHEM Code:Location Certificate:Hazardous Atmosphere Zone:Fire Extinguishers:Full protective clothing and self-contained breathing apparatus2XNot applicableNot applicableNot applicableSpills and Disposal:Wear appropriate protective clothing. Exclude non-essential people from the area. Contain spill andabsorb with inert material such as soil, sand or absorbent granules and place in a sealable waste container.Dispose of waste safely in an approved landfill.Protective Clothing: For appropriate personal protective equipment see section 8.EnvironmentalPrecaution:Handling:Storage:Other Information:Exposure Limits:Protective Equipment:Engineering Controls:Hygiene Precautions:Appearance:Odour:Specific Gravity:Solubility in Water:pH:Flash PointOther Information:Stability:Prevent from entering drains, waterways or sewers. If spill does enter waterways contactlocal authority.Keep out of reach of children. Avoid contact with skin, eyes and inhalation of spray mist.Approved Handler: Not requiredTracking: Not requiredRecord Keeping: Records of use must be kept.Store in original container tightly closed and in a locked, dry, cool area away from foodstuffs, fertiliser andseed. Store in accordance with NZS 8409 Management of AgrichemicalsThis product is subject to emergency response plan, secondary containment and signage when stored inquantities of 100 litres or more, either alone or in aggregate with substances of the same hazardclassification. For full details refer to NZS 8409 Management of Agrichemicals and HSNO Regulations(Emergency Management and Identification Regulations).Always read the label before use. See label for further information on handling and storage.No exposure limits have been assigned for this product by OSHAWhen opening the container, preparing spray and when contact with concentrate or solution is likely, wearsafety goggles, waterproof gloves, cotton overalls buttoned to the neck and wrist, and boots.Handle in well ventilated area. Use process enclosures, local exhaust ventilation, or other engineeringcontrols to keep airborne levels below exposure limits. Avoid inhalation of spray mist.Do not eat, drink or smoke while using this product. Remove protective clothing and wash hands and facebefore meals and after work. Wash protective clothing daily after work.Clear light yellow liquidMild0.86gm/ccEmulsifies in waterNeutralNot determinedWhen stored appropriately this product should show no significant degradation for 2 years from the dateof manufacture.Hazardous Polymerisation: Hazardous polymerisation will not occurMaterials to Avoid:Conditions to Avoid:Strong oxidising substancesExtreme heatSection 6: ACCIDENTAL RELEASE MEASURESSection 7: HANDLING AND STORAGESection 8: EXPOSURE CONTROL/PERSONAL PROTECTIONSection 9: PHYSICAL AND CHEMICAL PROPERTIESSection 10: STABILITY AND REACTIVITYCollaborate Spray Oil Page 2 of 3

Section 11: TOXICOLOGICAL INFORMATIONERMA Classifications: 6.1EInhalation:Ingestion:Skin:Eye:Chronic Effects:Reproductive Toxicity:Mutagenicity:Carcinogenicity:Acute Inhalation – Not availableNo adverse effects are to be expected under normal use. When applying this product avoid inhalation ofspray mist. Some temporary irritation to the respiratory tract may be experienced if high concentrationsare inhaled.Acute Toxicity (Oral) LD 50 (rat) >30g/kgAmounts swallowed incidental to normal handling are unlikely to cause injury. Large amounts swallowedmay cause injury. Symptoms include: nausea, vomiting, gastrointestinal discomfort and diarrhoea.Acute Toxicity (Dermal) LD 50 (rat) >2000mg/kgThe concentrate may cause mild skin irritation.May irritate the eye.No information available.Not considered to be a reproductive toxinNo mutagenic or teratogenic effects expectedBased on the results of animal studies the product is not considered to be carcinogenic.ERMA Classifications: 9.3AEcotoxicity:Persistence/Mobility:Bioaccumulation:Acute Toxicity (fish)No information availableAcute Toxicity (daphnia magna)No information availableNo information availableNo information availableSection 12: ECOLOGICAL INFORMATIONSection 13: DISPOSAL INFORMATIONProduct Disposal:Container Disposal:Dispose of product only by using according to label or at an approved landfillTriple rinse container and add rinsate to spray tank. Burn in an appropriate incinerator if circumstance,such as wind direction permit. Otherwise crush and bury in an approved landfill. Do not use container forany other purpose.RAIL/ROAD: UN Number: Not applicableProper Shipping Name: Not applicableDG Class:Not applicablePacking Group:Not applicableMarine Pollutant: Not applicableERMA:Section 14: TRANSPORT INFORMATIONSection 15: REGULATORY INFORMATIONApproved pursuant to the HSNO Act 1996, Code: HSR002503See www.epa.govt.nz for approval controls.Section 16: OTHER INFORMATIONThis SDS supersedes all others and was reviewed to include HSNO requirements.The data in this SDS relates only to the specific material designated herein and does not relate to use in combination with any othermaterial. The information is provided in good faith based on current knowledge and experience. No warranty with regard to theproduct properties is expressed or implied.Collaborate Spray Oil Page 3 of 3