The study of using of nanofillers in polyolefinic matrix - DSpace UTB
The study of using of nanofillers in polyolefinic matrix - DSpace UTB
The study of using of nanofillers in polyolefinic matrix - DSpace UTB
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5. COMPOUNDING<br />
Tomas Bata University <strong>in</strong> Zlín, Faculty <strong>of</strong> Technology<br />
Compound<strong>in</strong>g is a technological process <strong>of</strong> nanocomposite preparation. <strong>The</strong> compound<strong>in</strong>g <strong>of</strong><br />
only pure polymer <strong>matrix</strong> and clay m<strong>in</strong>eral is not possible due to different polarity <strong>of</strong> polymer<br />
<strong>matrix</strong> and a nature clay m<strong>in</strong>eral. <strong>The</strong> f<strong>in</strong>ally product will be separated <strong>in</strong>to two different<br />
phases because the effect will be the same as a mix<strong>in</strong>g <strong>of</strong> water and oil.<br />
Fig. 5 shows levels <strong>of</strong> dispergation <strong>of</strong> clay m<strong>in</strong>eral <strong>in</strong> polymer <strong>matrix</strong>. Fig 5 shows two<br />
different phases’ clay m<strong>in</strong>eral and polymeric material. Fig. 5 a) shows two different phases –<br />
polymer and nan<strong>of</strong>iller. Polymer is not <strong>in</strong>tercalated between layers <strong>of</strong> nan<strong>of</strong>iller. As it can be<br />
seen from Fig. 5 b), polymeric material is <strong>in</strong>tercalated between layers <strong>of</strong> clay m<strong>in</strong>erals <strong>in</strong><br />
second level. <strong>The</strong> layers are delayed but the bonds are not cut. Exfoliation is the highest level<br />
<strong>of</strong> dispergation <strong>of</strong> clay m<strong>in</strong>eral layers <strong>in</strong> polymer and this situation is represented by Fig 5 c).<br />
<strong>The</strong> attractive forces are cut and layers <strong>of</strong> clay m<strong>in</strong>erals are dispersed <strong>in</strong> materials. [41-43]<br />
Fig. 5 Levels <strong>of</strong> dispergation <strong>of</strong> clay m<strong>in</strong>eral <strong>in</strong> polymer <strong>matrix</strong><br />
Maleic anhydride polymer is used <strong>in</strong> order to <strong>in</strong>crease the compatibility between polymeric<br />
materials and clay m<strong>in</strong>eral. <strong>The</strong> concentration cannot be higher than 5 wt. % due to a change<br />
<strong>of</strong> mechanical properties. [44-48]<br />
Type <strong>of</strong> compound<strong>in</strong>g device, conditions <strong>of</strong> preparation, used materials can <strong>in</strong>fluence f<strong>in</strong>al<br />
level <strong>of</strong> distribution and dispergation <strong>of</strong> clay m<strong>in</strong>eral <strong>in</strong> polymer <strong>matrix</strong>.<br />
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