safety data sheet unibond repair all purpose power ... - Toolbank

Safety Data Sheet according to (EC) No 1907/2006UniBond Repair All Purpose 5 MinPage 1 of 11sds no. : 256595V003.0Revision: 13.02.2013printing date: 22.03.2014SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifierUniBond Repair All Purpose 5 Min Part A1.2. Relevant identified uses of the substance or mixture and uses advised againstIntended use:2-Component epoxy adhesive1.3. Details of the supplier of the safety data sheetHenkel LimitedApollo Court, 2 Bishop Square Business ParkAL10 9EY HatfieldGreat BritainPhone: +44 (1707) 635000Fax-no.: +44 (1707) 635099ua-productsafety.uk@uk.henkel.com1.4. Emergency telephone number24 Hours Emergency Tel: +44 0 8701 906777 - For further general health & safety, technical and practical advice on thisproduct, please call +44 (0) 1606 593933 or write to: Technical Services; Henkel Limited; Road 5; Winsford IndustrialEstate; Winsford; Cheshire; CW7 3QY- Email: technical.services@henkel.co.ukSECTION 2: Hazards identification2.1. Classification of the substance or mixtureClassification (DPD):Xi - IrritantR36/38 Irritating to eyes and skin.SensitizingR43 May cause sensitisation by skin contact.N - Dangerous for theenvironmentR51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.2.2. Label elements

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 2 of 11Label elements (DPD):Xi - IrritantN - Dangerous for theenvironmentRisk phrases:R36/38 Irritating to eyes and skin.R43 May cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Safety phrases:S2 Keep out of the reach of children.S24/25 Avoid contact with skin and eyes.S29 Do not empty into drains.S37 Wear suitable gloves.S46 If swallowed, seek medical advice immediately and show this container or label.Additional labeling:Contains epoxy constituents. See information supplied by the manufacturer.Contains:Bisphenol-A epichlorhydrin resin MW

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 3 of 11Declaration of ingredients according to DPD (EC) No 1999/45:Hazardous componentsCAS-No.Bisphenol-A epichlorhydrin resin MW 85 % R43Xi - Irritant; R36/38N - Dangerous for the environment; R51/53For full text of the R-Phrases indicated by codes see section 16 'Other Information'.Substances without classification may have community workplace exposure limits available.4.1. Description of first aid measuresGeneral information:In case of adverse health effects seek medical advice.Inhalation:Move to fresh air, consult doctor if complaint persists.SECTION 4: First aid measuresSkin contact:Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. If necessary, see adermatologist.Eye contact:Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remains (intensive smarting,sensivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital.Ingestion:Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice.4.2. Most important symptoms and effects, both acute and delayedEYE: Irritation, conjunctivitis.SKIN: Redness, inflammation.SKIN: Rash, Urticaria.4.3. Indication of any immediate medical attention and special treatment neededSee section: Description of first aid measuresSECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media:carbon dioxide, foam, powder, water spray jet, fine water sprayExtinguishing media which must not be used for safety reasons:High pressure waterjet5.2. Special hazards arising from the substance or mixtureIn the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released.5.3. Advice for firefightersWear protective equipment.Wear self-contained breathing apparatus.SECTION 6: Accidental release measures

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 4 of 116.1. Personal precautions, protective equipment and emergency proceduresWear protective equipment.Avoid contact with skin and eyes.Danger of slipping on spilled product.6.2. Environmental precautionsDo not empty into drains / surface water / ground water.6.3. Methods and material for containment and cleaning upRemove with liquid-absorbing material (sand, peat, sawdust).Dispose of contaminated material as waste according to Chapter 13.6.4. Reference to other sectionsSee advice in chapter 87.1. Precautions for safe handlingAvoid skin and eye contact.Hygiene measures:Do not eat, drink or smoke while working.Wash hands before work breaks and after finishing work.SECTION 7: Handling and storage7.2. Conditions for safe storage, including any incompatibilitiesStore in sealed original container.Keep container in a well ventilated place.Store in a cool, dry place.Temperatures between + 5 °C and + 40 °CDo not store together with food or other consumables (coffee, tea, tobacco, etc.).7.3. Specific end use(s)2-Component epoxy adhesiveSECTION 8: Exposure controls/personal protection8.1. Control parametersOccupational Exposure LimitsValid forGreat BritainNone

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 5 of 11Predicted No-Effect Concentration (PNEC):Name on listReaction product: bisphenol-A-(epichlorhydrin); epoxy resin (numberaverage molecular weight

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 6 of 11Derived No-Effect Level (DNEL):Name on listReaction product: bisphenol-A-(epichlorhydrin); epoxy resin (numberaverage molecular weight

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 7 of 11Skin protection:Suitable protective clothingSECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesAppearanceliquidviscousclearOdour thresholdNo data available / Not applicablepH(20 °C (68 °F))Initial boiling pointFlash pointDecomposition temperatureVapour pressure(180 °C (356 °F))Density(20 °C (68 °F))Bulk densityViscosity(; 30 °C (86 °F))Viscosity (kinematic)Explosive propertiesSolubility (qualitative)(20 °C (68 °F); Solvent: Water)Solidification temperatureMelting pointFlammabilityAuto-ignition temperatureExplosive limitsPartition coefficient: n-octanol/waterEvaporation rateVapor densityOxidising properties6 - 7> 260 °C (> 500 °F)> 150 °C (> 302 °F); no methodNo data available / Not applicable< 0,13 kPa1,10 - 1,18 g/cm3No data available / Not applicable6.000 - 8.000 cpNo data available / Not applicableNo data available / Not applicablelow solubilityNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicable9.2. Other informationNo data available / Not applicable10.1. ReactivityReacts with amines, alcohols, acids and alkalis.Reaction with oxidants.10.2. Chemical stabilityStable under recommended storage conditions.10.3. Possibility of hazardous reactionsSee section reactivity10.4. Conditions to avoidNone if used for intended purpose.10.5. Incompatible materialsNone if used properly.10.6. Hazardous decomposition productsNone knownSECTION 10: Stability and reactivity

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 8 of 1111.1. Information on toxicological effectsSECTION 11: Toxicological informationGeneral toxicological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Persons suffering from allergic reactions to epoxides should avoid contact with the product.Cross-reactions with other epoxide compounds possible.Skin irritation:Primary skin irritation: irritatingEye irritation:Primary eye irritation: irritatingSensitizing:May cause sensitization by skin contact.Skin corrosion/irritation:Hazardous componentsCAS-No.Bisphenol-Aepichlorhydrin resin MW

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 9 of 1112.1. ToxicityHazardous componentsCAS-No.Bisphenol-A epichlorhydrinresin MW

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 10 of 11SECTION 14: Transport information14.1. UN numberADR 3082RID 3082ADNR 3082IMDG 3082IATA 308214.2. UN proper shipping nameADRRIDADNRIMDGIATAENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Bisphenol-A Epichlorhydrin resin)ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Bisphenol-A Epichlorhydrin resin)ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Bisphenol-A Epichlorhydrin resin)ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Bisphenol-A Epichlorhydrin resin)Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-A Epichlorhydrinresin)14.3. Transport hazard class(es)ADR 99RID 99ADNR 99IMDG 99IATA 9914.4. Packaging groupADRRIDADNRIMDGIATAIIIIIIIIIIIIIII14.5. Environmental hazardsADRRIDADNRIMDGIATAnot applicablenot applicablenot applicableMarine pollutantnot applicable14.6. Special precautions for userADRRIDADNRIMDGIATAnot applicableTunnelcode: (E)not applicablenot applicablenot applicablenot applicable14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Codenot applicable

MSDS-No.: 256595V003.0UniBond Repair All Purpose 5 Min Page 11 of 11SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureVOC content0 %(VOCV 814.018 VOC regulationCH)15.2. Chemical safety assessmentA chemical safety assessment has not been carried out.SECTION 16: Other informationThe labelling of the product is indicated in Section 2. The full textof all abbreviations indicated by codes in this safety data sheet are as follows:R36/38 Irritating to eyes and skin.R43 May cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H411 Toxic to aquatic life with long lasting effects.Further information:This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It isintended to describe our products from the point of view of safety requirements and is not intended to guarantee anyparticular properties.

Safety Data Sheet according to (EC) No 1907/2006UniBond Repair All Purpose 5 MinPage 1 of 7sds no. : 256597V003.0Revision: 13.02.2013printing date: 22.03.2014SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifierUniBond Repair All Purpose 5 Min Part B1.2. Relevant identified uses of the substance or mixture and uses advised againstIntended use:2-Component epoxy adhesive1.3. Details of the supplier of the safety data sheetHenkel LimitedApollo Court, 2 Bishop Square Business ParkAL10 9EY HatfieldGreat BritainPhone: +44 (1707) 635000Fax-no.: +44 (1707) 635099ua-productsafety.uk@uk.henkel.com1.4. Emergency telephone number24 Hours Emergency Tel: +44 0 8701 906777 - For further general health & safety, technical and practical advice on thisproduct, please call +44 (0) 1606 593933 or write to: Technical Services; Henkel Limited; Road 5; Winsford IndustrialEstate; Winsford; Cheshire; CW7 3QY- Email: technical.services@henkel.co.uk2.1. Classification of the substance or mixtureClassification (DPD):No classification required.2.2. Label elementsSECTION 2: Hazards identificationLabel elements (DPD):Safety phrases:S2 Keep out of the reach of children.Additional information:The product is not subject to classification according to the calculation methods of the "General Classification Guideline forPreparations of the EC" as issued in the last version.2.3. Other hazardsPersons suffering from allergic reactions to amines should avoid contact with the product.

MSDS-No.: 256597V003.0UniBond Repair All Purpose 5 Min Page 2 of 7General chemical description:HardenerBase substances of preparation:PolymercaptanAminesSECTION 3: Composition/information on ingredientsDeclaration of the ingredients according to CLP (EC) No 1272/2008:Hazardous componentsCAS-No.1,3-bis[3-(dimethylamino)propyl]urea52338-87-1EC NumberREACH-Reg No.contentClassification257-861-2 >= 10- = 10 -

MSDS-No.: 256597V003.0UniBond Repair All Purpose 5 Min Page 3 of 75.2. Special hazards arising from the substance or mixtureIn the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released.5.3. Advice for firefightersWear protective equipment.Wear self-contained breathing apparatus.SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresWear protective equipment.Danger of slipping on spilled product.6.2. Environmental precautionsDo not empty into drains / surface water / ground water.6.3. Methods and material for containment and cleaning upRemove with liquid-absorbing material (sand, peat, sawdust).Dispose of contaminated material as waste according to Chapter 13.6.4. Reference to other sectionsSee advice in chapter 87.1. Precautions for safe handlingNo particular measures required.Hygiene measures:Do not eat, drink or smoke while working.Wash hands before work breaks and after finishing work.SECTION 7: Handling and storage7.2. Conditions for safe storage, including any incompatibilitiesStore in sealed original container.Keep container in a well ventilated place.Store in a cool, dry place.Temperatures between + 5 °C and + 40 °CDo not store together with food or other consumables (coffee, tea, tobacco, etc.).7.3. Specific end use(s)2-Component epoxy adhesiveSECTION 8: Exposure controls/personal protection8.1. Control parametersOccupational Exposure LimitsValid forGreat BritainNoneBiological Exposure Indices:None8.2. Exposure controls:Respiratory protection:Not needed.

MSDS-No.: 256597V003.0UniBond Repair All Purpose 5 Min Page 4 of 7Hand protection:In the case of longer contact protective gloves made from nitrile rubber are recommended according to EN 374.Perforation time > 480 minutesmaterial thickness > 0.1 mmIn the case of longer and repeated contact please note that in practice the penetration times may be considerably shorter thanthose determined according to EN 374. The protective gloves must always be checked for their suitability for use at thespecific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must bereplaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in therelevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan isdrawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operatingconditions.Eye protection:Protective gogglesSkin protection:Suitable protective clothingSECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesAppearanceliquidviscousclearOdour thresholdNo data available / Not applicablepH(20 °C (68 °F))Initial boiling pointFlash pointDecomposition temperatureVapour pressureDensity(20 °C (68 °F))Bulk densityViscosity(; 30 °C (86 °F))Viscosity (kinematic)Explosive propertiesSolubility (qualitative)(20 °C (68 °F); Solvent: Water)Solidification temperatureMelting pointFlammabilityAuto-ignition temperatureExplosive limitsPartition coefficient: n-octanol/waterEvaporation rateVapor densityOxidising properties3 - 5No data available / Not applicable257 °C (494.6 °F); no methodNo data available / Not applicableNo data available / Not applicable1,00 - 1,10 g/cm3No data available / Not applicable10.000 - 15.000 cpNo data available / Not applicableNo data available / Not applicableDispersibleNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicableNo data available / Not applicable9.2. Other informationNo data available / Not applicable10.1. ReactivityReacts with acids, with strong oxidants and epoxides.10.2. Chemical stabilityStable under recommended storage conditions.10.3. Possibility of hazardous reactionsSee section reactivitySECTION 10: Stability and reactivity

MSDS-No.: 256597V003.0UniBond Repair All Purpose 5 Min Page 5 of 710.4. Conditions to avoidNone if used for intended purpose.10.5. Incompatible materialsNone if used properly.10.6. Hazardous decomposition productsNone known11.1. Information on toxicological effectsSECTION 11: Toxicological informationGeneral toxicological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Persons suffering from allergic reactions to amines should avoid contact with the product.Cross-reactions with other amine compounds are possible.Skin irritation:Primary skin irritation: slightly irritating, does not require labelingEye irritation:Primary eye irritation: slightly irritating, does not require labelingSECTION 12: Ecological informationGeneral ecological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Do not empty into drains, soil or bodies of water.12.1. ToxicityNo data available.12.2. Persistence and degradabilityNo data available.12.3. Bioaccumulative potential / 12.4. Mobility in soilNo data available.12.5. Results of PBT and vPvB assessmentNo data available.12.6. Other adverse effectsNo data available.13.1. Waste treatment methodsSECTION 13: Disposal considerations

MSDS-No.: 256597V003.0UniBond Repair All Purpose 5 Min Page 6 of 7Product disposal:Dispose of waste and residues in accordance with local authority requirements.Disposal of uncleaned packages:Use packages for recycling only when totally empty.Waste code08 04 10 Waste adhesives and sealants other than those mentioned in 08 04 09.SECTION 14: Transport information14.1. UN numberADR Not dangerous goodsRIDNot dangerous goodsADNR Not dangerous goodsIMDG Not dangerous goodsIATA 333414.2. UN proper shipping nameADRRIDADNRIMDGIATANot dangerous goodsNot dangerous goodsNot dangerous goodsNot dangerous goodsAviation regulated liquid, n.o.s. (Mercaptan polymer)14.3. Transport hazard class(es)ADR Not dangerous goodsRIDNot dangerous goodsADNR Not dangerous goodsIMDG Not dangerous goodsIATA 9914.4. Packaging groupADRRIDADNRIMDGIATANot dangerous goodsNot dangerous goodsNot dangerous goodsNot dangerous goodsIII14.5. Environmental hazardsADRRIDADNRIMDGIATAnot applicablenot applicablenot applicablenot applicablenot applicable14.6. Special precautions for userADRRIDADNRIMDGIATAnot applicablenot applicablenot applicablenot applicableNo dangerous good according to ADR/RID/ADNR. Carriage in accordance with1.1.4.2.1 ADR/RID/ADNR.14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Codenot applicable

MSDS-No.: 256597V003.0UniBond Repair All Purpose 5 Min Page 7 of 7SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureVOC content0 %(VOCV 814.018 VOC regulationCH)15.2. Chemical safety assessmentA chemical safety assessment has not been carried out.SECTION 16: Other informationThe labelling of the product is indicated in Section 2. The full textof all abbreviations indicated by codes in this safety data sheet are as follows:R36/38 Irritating to eyes and skin.H315 Causes skin irritation.H319 Causes serious eye irritation.Further information:This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It isintended to describe our products from the point of view of safety requirements and is not intended to guarantee anyparticular properties.