MSDS MIL-PRF-22750 PART B - ChemCenters

N12V10006 00MATERIAL SAFETY DATA SHEET===========================================================================Section 1 −− PRODUCT AND COMPANY IDENTIFICATION−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−PRODUCT NUMBERHMIS CODESHealth 3*N12V100 Flammability 3Reactivity 0PRODUCT NAMEMIL−PRF−22750F Coating, Epoxy, High−Solids (Part B), HardenerMANUFACTURER’S NAMEEMERGENCY TELEPHONE NO.THE SHERWIN−WILLIAMS COMPANY (216) 566−2917101 Prospect Avenue N.W.Cleveland, OH 44115DATE OF PREPARATIONINFORMATION TELEPHONE NO.11−FEB−05(216) 566−2902===========================================================================Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS% by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−26 67−63−0 2−PropanolACGIH TLV 400 ppm 33 mmACGIH TLV 500 ppm STELOSHA PEL 400 ppmOSHA PEL 500 ppm STEL45 84852−15−3 4−NonylphenolACGIH TLV Not AvailableOSHA PEL Not Available22 1477−55−0 1,3−BenzenedimethanamineACGIH TLV 0.1 mg/m3 CEILINGOSHA PEL 0.1 mg/m3 CEILING7 Proprietary PolyamineACGIH TLV Not AvailableOSHA PEL Not Available===========================================================================Section 3 −− HAZARDS IDENTIFICATION−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−ROUTES OF EXPOSUREINHALATION of vapor or spray mist.EYE or SKIN contact with the product, vapor or spray mist.EFFECTS OF OVEREXPOSUREEYES: Causes burns.SKIN: Causes burns.INHALATION: Causes burns of the upper respiratory system.May cause nervous system depression. Extreme overexposure may result inunconsciousness and possibly death.SIGNS AND SYMPTOMS OF OVEREXPOSUREHeadache, dizziness, nausea, and loss of coordination are indications ofexcessive exposure to vapors or spray mists.Redness and itching or burning sensation may indicate eye or excessiveskin exposure.Continued on page 2

N12V100 page 2===========================================================================MEDICAL CONDITIONS AGGRAVATED BY EXPOSUREMay cause allergic skin reaction in susceptible persons or skinsensitization.CANCER INFORMATIONFor complete discussion of toxicology data refer to Section 11.===========================================================================Section 4 −− FIRST AID MEASURES−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−EYES: Flush eyes with large amounts of water for 15 minutes.Get medical attention IMMEDIATELY.SKIN: Wash affected area thoroughly with soap and water.If irritation persists or occurs later, get medicalattention.Remove contaminated clothing and launder before re−use.INHALATION: If affected, remove from exposure. Restore breathing.Keep warm and quiet.INGESTION: Do not induce vomiting.Get medical attention immediately.===========================================================================Section 5 −− FIRE FIGHTING MEASURES−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−FLASH POINT LEL UEL53 F PMCC 2.0 12.7FLAMMABILITY CLASSIFICATIONRED LABEL −− Flammable, Flash below 100 FEXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, FoamUNUSUAL FIRE AND EXPLOSION HAZARDSClosed containers may explode when exposed to extreme heat.Application to hot surfaces requires special precautions.During emergency conditions overexposure to decomposition products maycause a health hazard. Symptoms may not be immediately apparent. Obtainmedical attention.SPECIAL FIRE FIGHTING PROCEDURESFull protective equipment including self−contained breathing apparatusshould be used.Water spray may be ineffective. If water is used, fog nozzles arepreferable. Water may be used to cool closed containers to preventpressure build−up and possible autoignition or explosion when exposed toextreme heat.===========================================================================Section 6 −− ACCIDENTAL RELEASE MEASURES−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDRemove all sources of ignition. Ventilate the area.Remove with inert absorbent.===========================================================================Section 7 −− HANDLING AND STORAGE−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−STORAGE CATEGORYDOL Storage Class IBContinued on page 3

N12V100 page 3===========================================================================PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEContents are FLAMMABLE. Keep away from heat, sparks, and open flame.During use and until all vapors are gone: Keep area ventilated − Do notsmoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,electric tools and appliances, and any other sources of ignition.Consult NFPA Code. Use approved Bonding and Grounding procedures.Keep container closed when not in use. Transfer only to approvedcontainers with complete and appropriate labeling. Do not take internally.Keep out of the reach of children.===========================================================================Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−PRECAUTIONS TO BE TAKEN IN USEUse only with adequate ventilation.Do not get in eyes, or on skin or clothing. Do not breathe vapor orspray mist.Wash hands after using.This coating may contain materials classified as nuisance particulates(listed "as Dust" in Section 2) which may be present at hazardous levelsonly during sanding or abrading of the dried film. If no specific dustsare listed in Section 2, the applicable limits for nuisance dusts are ACGIHTLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3(total dust), 5 mg/m3 (respirable fraction).VENTILATIONLocal exhaust preferable. General exhaust acceptable if the exposure tomaterials in Section 2 is maintained below applicable exposure limits.Refer to OSHA Standards 1910.94, 1910.107, 1910.108.RESPIRATORY PROTECTIONIf personal exposure cannot be controlled below applicable limits byventilation, wear a properly fitted organic vapor/particulate respiratorapproved by NIOSH/MSHA for protection against materials in Section 2.When sanding or abrading the dried film, wear a dust/mist respiratorapproved by NIOSH/MSHA for dust which may be generated from this product,underlying paint, or the abrasive.PROTECTIVE GLOVESTo prevent skin contact, wear gloves which are recommended by glovesupplier for protection against materials in Section 2.EYE PROTECTIONTo prevent eye contact, wear safety spectacles with unperforatedsideshields.OTHER PROTECTIVE EQUIPMENTUse barrier cream on exposed skin.OTHER PRECAUTIONSThis product must be mixed with other components before use. Beforeopening the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.Intentional misuse by deliberately concentrating and inhaling thecontents can be harmful or fatal.Continued on page 4

N12V100 page 4===========================================================================Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−PRODUCT WEIGHT 7.82 lb/gal 936 g/lSPECIFIC GRAVITY 0.94BOILING POINT 178 − 181 F 81 − 82 CMELTING POINT Not AvailableVOLATILE VOLUME 30 %EVAPORATION RATE Slower than etherVAPOR DENSITY Heavier than airSOLUBILITY IN WATER N.A.VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)1.99 lb/gal 239 g/l Less Water and Federally Exempt Solvents1.99 lb/gal 239 g/l Emitted VOC===========================================================================Section 10 −− STABILITY AND REACTIVITY−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−STABILITY −− StableCONDITIONS TO AVOIDNone known.INCOMPATIBILITYNone known.HAZARDOUS DECOMPOSITION PRODUCTSBy fire: Carbon Dioxide, Carbon MonoxideHAZARDOUS POLYMERIZATIONWill not occur===========================================================================Section 11 −− TOXICOLOGICAL INFORMATION−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−CHRONIC HEALTH HAZARDSNo ingredient in this product is an IARC, NTP or OSHA listed carcinogen.Reports have associated repeated and prolonged overexposure to solventswith permanent brain and nervous system damage.−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−TOXICOLOGY DATACAS No. Ingredient Name−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−67−63−0 2−PropanolLC50 RAT 4HR Not AvailableLD50 RAT 5045 mg/kg84852−15−3 4−NonylphenolLC50 RAT 4HR Not AvailableLD50 RAT Not Available1477−55−0 1,3−BenzenedimethanamineLC50 RAT 4HR Not AvailableLD50 RAT Not AvailableProprietary PolyamineLC50 RAT 4HR Not AvailableLD50 RAT Not Available===========================================================================Section 12 −− ECOLOGICAL INFORMATION−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−ECOTOXICOLOGICAL INFORMATIONNo data available.Continued on page 5

N12V100 page 5===========================================================================Section 13 −− DISPOSAL CONSIDERATIONS−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−WASTE DISPOSAL METHODWaste from this product may be hazardous as defined under the ResourceConservation and Recovery Act (RCRA) 40 CFR 261.Waste must be tested for ignitability to determine the applicable EPAhazardous waste numbers.Incinerate in approved facility. Do not incinerate closed container.Dispose of in accordance with Federal, State/Provincial, and Localregulations regarding pollution.===========================================================================Section 14 −− TRANSPORT INFORMATION−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−No data available.===========================================================================Section 15 −− REGULATORY INFORMATION−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATIONCAS No. CHEMICAL/COMPOUND % by WT % Element−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)Supplier Notification.TSCA CERTIFICATIONAll chemicals in this product are listed, or are exempt from listing,on the TSCA Inventory.===========================================================================Section 16 −− OTHER INFORMATION−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−This product has been classified in accordance with the hazard criteriaof the Canadian Controlled Products Regulations (CPR) and the MSDS containsall of the information required by the CPR.The above information pertains to this product as currently formulated,and is based on the information available at this time. Addition ofreducers or other additives to this product may substantially alter thecomposition and hazards of the product. Since conditions of use areoutside our control, we make no warranties, express or implied, and assumeno liability in connection with any use of this information.