safety data sheet unibond repair wood power epoxy ... - Toolbank

Safety Data Sheet according to (EC) No 1907/2006UniBond Repair WoodPage 1 of 1sds no. : 376217V001.1Revision: 07.05.2012printing date: 10.12.2013SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifierUniBond Repair Wood Comp. A1.2. Relevant identified uses of the substance or mixture and uses advised againstIntended use:2-c-epoxide adhesive1.3. Details of the supplier of the safety data sheetHenkel France S.A.Rue de Silly 16192100 Boulogne-BillancourtFrancePhone: +33 (0033) 1 4684 9000Fax-no.: +33 (0033) 1 4684 9090ua-productsafety.uk@uk.henkel.com1.4. Emergency telephone number24 Hours Emergency Tel: +44 0 8701 906777 - For further general health & safety, technical and practical advice on thisproduct, please call +44 (0) 1606 593933 or write to: Technical Services; Henkel Limited; Road 5; Winsford IndustrialEstate; Winsford; Cheshire; CW7 3QY- Email: technical.services@henkel.co.uk2.1. Classification of the substance or mixtureSECTION 2: Hazards identificationClassification (DPD):Xi - IrritantR36/38 Irritating to eyes and skin.SensitizingR43 May cause sensitisation by skin contact.N - Dangerous for theenvironmentR51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.2.2. Label elements

MSDS-No.: 376217V001.1UniBond Repair Wood Page 2 of 2Label elements (DPD):Xi - IrritantN - Dangerous for theenvironmentRisk phrases:R36/38 Irritating to eyes and skin.R43 May cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Safety phrases:S2 Keep out of the reach of children.S24/25 Avoid contact with skin and eyes.S29 Do not empty into drains.S37 Wear suitable gloves.S46 If swallowed, seek medical advice immediately and show this container or label.Additional labeling:Contains epoxy constituents. See information supplied by the manufacturer.Contains:Bisphenol-A epichlorhydrin resin MW

MSDS-No.: 376217V001.1UniBond Repair Wood Page 3 of 3For full text of the R-Phrases indicated by codes see section 16 'Other Information'.Substances without classification may have community workplace exposure limits available.4.1. Description of first aid measuresGeneral information:In case of adverse health effects seek medical advice.Inhalation:Move to fresh air, consult doctor if complaint persists.SECTION 4: First aid measuresSkin contact:Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. If necessary, see adermatologist.Eye contact:Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remains (intensive smarting,sensivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital.Ingestion:Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice.4.2. Most important symptoms and effects, both acute and delayedEYE: Irritation, conjunctivitis.SKIN: Redness, inflammation.SKIN: Rash, Urticaria.4.3. Indication of any immediate medical attention and special treatment neededSee section: Description of first aid measuresSECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media:carbon dioxide, foam, powder, water spray jet, fine water sprayExtinguishing media which must not be used for safety reasons:High pressure waterjet5.2. Special hazards arising from the substance or mixtureIn the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released.5.3. Advice for firefightersWear protective equipment.Wear self-contained breathing apparatus.SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresWear protective equipment.Avoid contact with skin and eyes.6.2. Environmental precautionsDo not empty into drains / surface water / ground water.6.3. Methods and material for containment and cleaning upRemove with liquid-absorbing material (sand, peat, sawdust).Dispose of contaminated material as waste according to Chapter 13.

MSDS-No.: 376217V001.1UniBond Repair Wood Page 4 of 46.4. Reference to other sectionsSee advice in chapter 8SECTION 7: Handling and storage7.1. Precautions for safe handlingAvoid skin and eye contact.Hygiene measures:Do not eat, drink or smoke while working.Wash hands before work breaks and after finishing work.7.2. Conditions for safe storage, including any incompatibilitiesStore in sealed original container.Keep container in a well ventilated place.Store in a cool, dry place.Temperatures between + 5 °C and + 40 °CDo not store together with food or other consumables (coffee, tea, tobacco, etc.).7.3. Specific end use(s)2-c-epoxide adhesiveSECTION 8: Exposure controls/personal protection8.1. Control parametersValid forGreat BritainNone

MSDS-No.: 376217V001.1UniBond Repair Wood Page 5 of 5Predicted No-Effect Concentration (PNEC):Name on listReaction product: bisphenol-A-(epichlorhydrin); epoxy resin (numberaverage molecular weight

MSDS-No.: 376217V001.1UniBond Repair Wood Page 6 of 6Derived No-Effect Level (DNEL):Name on listReaction product: bisphenol-A-(epichlorhydrin); epoxy resin (numberaverage molecular weight

MSDS-No.: 376217V001.1UniBond Repair Wood Page 7 of 7pH6 - 7(20 °C (68 °F))Initial boiling point > 260 °C (> 500 °F)Flash point > 150 °C (> 302 °F); no methodDecomposition temperature No data available / Not applicableVapour pressure< 0,13 kPa(180 °C (356 °F))Density1,10 - 1,18 g/cm3(20 °C (68 °F))Bulk density No data available / Not applicableViscosity6.000 - 8.000 cp(; 30 °C (86 °F))Viscosity (kinematic) No data available / Not applicableExplosive properties No data available / Not applicableSolubility (qualitative)low solubility(20 °C (68 °F); Solvent: Water)Solidification temperature No data available / Not applicableMelting point No data available / Not applicableFlammability No data available / Not applicableAuto-ignition temperature No data available / Not applicableExplosive limits No data available / Not applicablePartition coefficient: n-octanol/water No data available / Not applicableEvaporation rate No data available / Not applicableVapor density No data available / Not applicableOxidising properties No data available / Not applicable9.2. Other informationNo data available / Not applicable10.1. ReactivityReacts with amines, alcohols, acids and alkalis.Reaction with oxidants.10.2. Chemical stabilityStable under recommended storage conditions.10.3. Possibility of hazardous reactionsSee section reactivity10.4. Conditions to avoidNone if used for intended purpose.10.5. Incompatible materialsNone if used properly.10.6. Hazardous decomposition productsNone knownSECTION 10: Stability and reactivity11.1. Information on toxicological effectsSECTION 11: Toxicological informationGeneral toxicological information:Persons suffering from allergic reactions to epoxides should avoid contact with the product.The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Skin irritation:Primary skin irritation: irritatingEye irritation:Primary eye irritation: irritating

MSDS-No.: 376217V001.1UniBond Repair Wood Page 8 of 8Sensitizing:Dermal sensitization: sensitizing.Cross-reactions with other epoxide compounds possible.Germ cell mutagenicity:Hazardous componentsCAS-No.Bisphenol-Aepichlorhydrin resin MW

MSDS-No.: 376217V001.1UniBond Repair Wood Page 9 of 9Inland water transport ADN:Class: 9Packaging group:IIIClassification code:M6Hazard ident. number:UN no.: 3082Label: 9Technical name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,N.O.S. (Bisphenol-A Epichlorhydrin resin)Marine transport IMDG:Class: 9Packaging group:IIIUN no.: 3082Label: 9EmS:F-A ,S-FSeawater pollutant:Marine pollutantProper shipping name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,N.O.S. (Bisphenol-A Epichlorhydrin resin)Air transport IATA:Class: 9Packaging group:IIIPackaging instructions (passenger) 964Packaging instructions (cargo) 964UN no.: 3082Label: 9Proper shipping name:Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-AEpichlorhydrin resin)SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureVOC content0 %(VOCV 814.018 VOC regulationCH)

MSDS-No.: 376217V001.1UniBond Repair Wood Page 10 of 10SECTION 16: Other informationThe labelling of the product is indicated in Section 2. The full textof all abbreviations indicated by codes in this safety data sheet are as follows:R36/38 Irritating to eyes and skin.R43 May cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H411 Toxic to aquatic life with long lasting effects.Further information:This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It isintended to describe our products from the point of view of safety requirements and is not intended to guarantee anyparticular properties.

Safety Data Sheet according to (EC) No 1907/2006UniBond Repair WoodPage 1 of 1sds no. : 376216V001.1Revision: 07.05.2012printing date: 10.12.2013SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifierUniBond Repair Wood Comp. B1.2. Relevant identified uses of the substance or mixture and uses advised againstIntended use:2-c-epoxide adhesive1.3. Details of the supplier of the safety data sheetHenkel France S.A.Rue de Silly 16192100 Boulogne-BillancourtFrancePhone: +33 (0033) 1 4684 9000Fax-no.: +33 (0033) 1 4684 9090ua-productsafety.uk@uk.henkel.com1.4. Emergency telephone number24 Hours Emergency Tel: +44 0 8701 906777 - For further general health & safety, technical and practical advice on thisproduct, please call +44 (0) 1606 593933 or write to: Technical Services; Henkel Limited; Road 5; Winsford IndustrialEstate; Winsford; Cheshire; CW7 3QY- Email: technical.services@henkel.co.uk2.1. Classification of the substance or mixtureClassification (DPD):No classification required.2.2. Label elementsSECTION 2: Hazards identificationLabel elements (DPD):Safety phrases:S2 Keep out of the reach of children.2.3. Other hazardsPersons suffering from allergic reactions to amines should avoid contact with the product.General chemical description:HardenerBase substances of preparation:PolymercaptanAminesSECTION 3: Composition/information on ingredients

MSDS-No.: 376216V001.1UniBond Repair Wood Page 2 of 2Declaration of the ingredients according to CLP (EC) No 1272/2008:Hazardous componentsCAS-No.1,3-bis[3-(dimethylamino)propyl]urea52338-87-1EC NumberREACH-Reg No.contentClassification257-861-2 >= 10- = 10 -

MSDS-No.: 376216V001.1UniBond Repair Wood Page 3 of 3SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresWear protective equipment.6.2. Environmental precautionsDo not empty into drains / surface water / ground water.6.3. Methods and material for containment and cleaning upRemove with liquid-absorbing material (sand, peat, sawdust).Dispose of contaminated material as waste according to Chapter 13.6.4. Reference to other sectionsSee advice in chapter 87.1. Precautions for safe handlingNo particular measures required.Hygiene measures:Do not eat, drink or smoke while working.Wash hands before work breaks and after finishing work.SECTION 7: Handling and storage7.2. Conditions for safe storage, including any incompatibilitiesStore in sealed original container.Keep container in a well ventilated place.Store in a cool, dry place.Temperatures between + 5 °C and + 40 °CDo not store together with food or other consumables (coffee, tea, tobacco, etc.).7.3. Specific end use(s)2-c-epoxide adhesiveSECTION 8: Exposure controls/personal protection8.1. Control parametersValid forGreat BritainNone8.2. Exposure controls:Respiratory protection:Not needed.Hand protection:Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation time < 30s).Gloves should bereplaced after each short time contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist'sshops.Eye protection:Protective gogglesSkin protection:Suitable protective clothing

MSDS-No.: 376216V001.1UniBond Repair Wood Page 4 of 4SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesAppearanceliquidviscousclearpH3 - 5(20 °C (68 °F))Initial boiling point No data available / Not applicableFlash point 257 °C (494.6 °F); no methodDecomposition temperature No data available / Not applicableVapour pressure No data available / Not applicableDensity1,00 - 1,10 g/cm3(20 °C (68 °F))Bulk density No data available / Not applicableViscosity10.000 - 15.000 cp(; 30 °C (86 °F))Viscosity (kinematic) No data available / Not applicableExplosive properties No data available / Not applicableSolubility (qualitative)Dispersible(20 °C (68 °F); Solvent: Water)Solidification temperature No data available / Not applicableMelting point No data available / Not applicableFlammability No data available / Not applicableAuto-ignition temperature No data available / Not applicableExplosive limits No data available / Not applicablePartition coefficient: n-octanol/water No data available / Not applicableEvaporation rate No data available / Not applicableVapor density No data available / Not applicableOxidising properties No data available / Not applicable9.2. Other informationNo data available / Not applicable10.1. ReactivityReacts with acids, with strong oxidants and epoxides.10.2. Chemical stabilityStable under recommended storage conditions.10.3. Possibility of hazardous reactionsSee section reactivity10.4. Conditions to avoidNone if used for intended purpose.10.5. Incompatible materialsNone if used properly.10.6. Hazardous decomposition productsNone knownSECTION 10: Stability and reactivity11.1. Information on toxicological effectsSECTION 11: Toxicological informationGeneral toxicological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Persons suffering from allergic reactions to amines should avoid contact with the product.

MSDS-No.: 376216V001.1UniBond Repair Wood Page 5 of 5Skin irritation:Primary skin irritation: slightly irritating, does not require labelingEye irritation:Primary eye irritation: slightly irritating, does not require labelingSensitizing:Cross-reactions with other amine compounds are possible.SECTION 12: Ecological informationGeneral ecological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Do not empty into drains, soil or bodies of water.SECTION 13: Disposal considerations13.1. Waste treatment methodsProduct disposal:Dispose of waste and residues in accordance with local authority requirements.Disposal of uncleaned packages:Use packages for recycling only when totally empty.Waste code08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substancesRoad transport ADR:Not dangerous goodsRailroad transport RID:Not dangerous goodsInland water transport ADN:Not dangerous goodsMarine transport IMDG:Not dangerous goodsAir transport IATA:SECTION 14: Transport informationClass: 9Packaging group:Packaging instructions (passenger)Packaging instructions (cargo)UN no.: 3334Label: 9Proper shipping name:Aviation regulated liquid, n.o.s. (Mercaptan polymer)SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureVOC content0 %(VOCV 814.018 VOC regulationCH)

MSDS-No.: 376216V001.1UniBond Repair Wood Page 6 of 6SECTION 16: Other informationThe labelling of the product is indicated in Section 2. The full textof all abbreviations indicated by codes in this safety data sheet are as follows:R36/38 Irritating to eyes and skin.H315 Causes skin irritation.H319 Causes serious eye irritation.Further information:This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It isintended to describe our products from the point of view of safety requirements and is not intended to guarantee anyparticular properties.