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Diffuse interface models in fluid mechanics

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It can be shown that this system of equations is thermodynamically consistent <strong>in</strong> the sensethat the total energy of the system is a decreas<strong>in</strong>g function of time:∫ddt V[F 0 (c) + λ 2 (∇c)2 + ρ 0 v 22] ∫dV = −{κ [ ∇ ( µ 0 (c) − λ∇ 2 c )] }2+ τ : ∇v dV < 0VTo account for buoyancy effects the gravity term ρ g (where g is the acceleration of gravity)has to be added <strong>in</strong> the momentum balance equation. If ρ = ρ 0 <strong>in</strong> this force, this force has noeffect on the flow: it only modifies the pressure (the pressure P can be replaced by the pressure(P − ρ 0 g z), which does not modify the structure of the equations). For the gravity to have aneffect on the flow and <strong>in</strong> particular to account for a buoyancy effect, variations of the density mustbe accounted for. However, these variations are a priori not compatible with the <strong>in</strong>compressibilityapproximation. That is why the Bouss<strong>in</strong>esq approximation is generally used: the variation of thedensity is neglected except <strong>in</strong> the gravity term where it is l<strong>in</strong>earized. The momentum balanceequation therefore readswhereρ 0∂v∂t + ρ 0 v · ∇v = −∇P − ∇ · (λ∇c ⊗ ∇c) + ∇ · τ + ρ 0 (1 + β(c − c 0 )) gWe summarize the system of equations:β ˆ= 1 ( ) dρρ 0 dc0∇ · v = 0 (63)∂c+ v · ∇c = ∇ · [κ ∇˜µ] (64)∂t˜µ ˆ= µ 0 (c) − λ∇ 2 c (65)∂vρ 0∂t + ρ 0 v · ∇v = −∇P − ∇ · (λ∇c ⊗ ∇c) + ∇ · τ + ρ 0 (1 + β(c − c 0 )) g (66)(µ 0 (c) = 4 A (c − c 1 ) (c − c 2 ) c − c )1 + c 2(67)2It is worth not<strong>in</strong>g that, like <strong>in</strong> the van der Waals model (cf. section 2.3), the “stress form” of themomentum balance equation can be transformed <strong>in</strong>to an equivalent “potential form” <strong>in</strong> whichthe generalized chemical potential appears [Jacqm<strong>in</strong>, 1999]:ρ 0∂v∂t + ρ 0 v · ∇v = −∇ ˜P + ˜µ ∇c + ∇ · τ + ρ 0 (1 + β(c − c 0 )) g (68)˜P ˆ= P + FThis form of the momentum balance equation shows the <strong>in</strong>fluence of the curvature on themomemtum balance equation. Indeed, we showed <strong>in</strong> the previous section that, at equilibriumof a spherical <strong>in</strong>clusion, the value of the chemical potential is proportional to the local <strong><strong>in</strong>terface</strong>curvature (cf. (61)). Therefore, the term ˜µ ∇c represents a spread<strong>in</strong>g (over the <strong><strong>in</strong>terface</strong> thickness)of a force proportional to the <strong><strong>in</strong>terface</strong> curvature and oriented <strong>in</strong> the direction normal to the <strong><strong>in</strong>terface</strong>approximated by ∇c. This <strong>in</strong>terpretation is very close to the Cont<strong>in</strong>uous Surface Forcecommonly used <strong>in</strong> sharp <strong><strong>in</strong>terface</strong> numerical methods [Brackbill et al., 1992].This system of equations is particularly attractive numerically. Indeed, we one has a numericalcode dedicated to the simulation of <strong>in</strong>compressible flows, it can be very easily generalized totwo-phase capillary flows. Indeed, one only needs to implement a source term <strong>in</strong> the momentum25

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