List of used abbreviations - RosDok - Universität Rostock

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′electrophilically assisted ring openings′ and ′spiro-activations′. 27 In the present case, a ′spiro-activation′ is combined with the activation by an electrophile. 28 Figure 1. Structure of 6f 22
3a O OSiMe 3 O OMe + Me Me Cl 3TiO Me SPh 7a SPh E TiCl4 _ Me3SiCl O O Me OMe TiCl 4 TiCl 4 (2 equiv.) CH 2Cl 2 _ 78 20 °C H 2O Scheme 7. Possible mechanism of the formation of 8a _ 23 SPh O Me Me Cl Cl 3TiO Me 8a (48%) F Me OMe _ (Cl3Ti) 2O + TiCl3 SPh O OMe _ Cl The cyclization of 1-trimethylsilyloxy-3-arylthio-1,3-butadienes 3a,d,f,g,i,k,o with 1,1- diacylcyclopropanes 7a-e, in the presence of TiCl4 or TiBr4, afforded the 5-haloethyl- 2-(arylthio)benzoates 8a-x (Scheme 8, Table 3). Products 8b-d,g,i,j,l,o, derived from the unsymmetrical cyclopropanes 7b-d, were formed with very good regioselectivity. This can be explained by regioselective attack of the terminal carbon atom of diene 3 onto the acetyl rather than the less reactive aroyl group of 7b-d.
Page 1 and 2: Synthesis of functionalized 2-(aryl
Page 3 and 4: The ink of the scholar is more holy
Page 5 and 6: Affectionately Dedicated to “All
Page 7 and 8: Table of Contents 03 List of used a
Page 9 and 10: RCM Ring Closing Metathesis TBAI Te
Page 11 and 12: humans: 1) the thiomethyl of methio
Page 13 and 14: Chart 3. Structure of sumatriptan S
Page 15 and 16: disulfide (DADS) and diallyl sulfid
Page 17 and 18: 1. Synthesis of functionalized 2-(a
Page 19 and 20: 3-Arylthio-1-trimethylsilyloxy-1,3-
Page 21 and 22: under kinetic reaction control, by
Page 23 and 24: l a u 4-FC6H4 H Me H 40 m a v 4-FC6
Page 25: Table 2. Synthesis of thioxanthones
Page 29 and 30: Table 3. Synthesis of 8a-x 3 7 8 Ar
Page 31 and 32: Cl + SPh OSiMe 3 3a 9 O OMe O O H i
Page 33 and 34: solution. The use of an excess (1.5
Page 35 and 36: Table 4. Synthesis of 12a-r 3 11 12
Page 37 and 38: 2.3 Conclusion In conclusion, I hav
Page 39 and 40: aromatization). An unseparable 1:2
Page 41 and 42: Table 5. Synthesis of arenes 14a-l
Page 43 and 44: 3.3 Conclusion In conclusion, I hav
Page 45 and 46: Mass Spectroscopy: AMD MS40, AMD 40
Page 47 and 48: 131.0 (ArCH), 132.7, 134.0, 135.9,
Page 49 and 50: (EI, 70 eV): m/z (%): 380 (100), 21
Page 51 and 52: (m), 1490 (m), 1434 (m), 1383 (w),
Page 53 and 54: 15.4, 16.9, 18.9 (CH3), 28.3 (CH2),
Page 55 and 56: (C). IR (neat): ν̃ = 2945 (w), 29
Page 57 and 58: 948 (w) 853 (m), 803 (m), 751 (m),
Page 59 and 60: 135.4, 139.2, 143.8, 146.5, 182.2 (
Page 61 and 62: Me S O Me Ph Br Methyl 4-methyl-5-(
Page 63 and 64: 35 Cl, 37 Cl, 61), 430 (M + , 35 Cl
Page 65 and 66: ArH). 13 C NMR (62 MHz, CDCl3): δ
Page 67 and 68: Me S O Me Me Methyl 4,6-dimethyl-5-
Page 69 and 70: S Methyl 4-methyl-5-(2-bromoethyl)-
Page 71 and 72: (CH2CH3), 33.3 (CH2), 40.1 (CH2), 5
Page 73 and 74: Me 3,4-Dimethyl-2-phenylsulfanyl-be
Page 75 and 76: Me 3,4-Dimethyl-2-(p-tolylsulfanyl)
Page 77 and 78:
OCH3), 7.08-7.17 (m, 7H, Ar); 13 C
Page 79 and 80:
(w), 750 (s), 732 (s), 688 (s), 650
Page 81 and 82:
35 Cl 35 Cl, 100), 359 (26), 357 (3
Page 83 and 84:
2924 (w), 2853 (w), 1728 (s), 1712
Page 85 and 86:
Me 3-Hydroxy-5-(4-methylphenylsulfa
Page 87 and 88:
Et 3-Hydroxy-5-(4-ethylphenylsulfan
Page 89 and 90:
(13), 264 (13), 262 (36) ,260 (12),
Page 91 and 92:
MS (EI, 70 eV): m/z (%) = 337 (16),
Page 93 and 94:
OH O 5'-Hydroxy-[1,1';3',1'']terphe
Page 95 and 96:
Refrences 1. Handbook of Chemistry
Page 97 and 98:
20. For a review of [3+3] cyclizati
Page 99 and 100:
Nationality Pakistan Place of Birth
Page 101 and 102:
Publications 1. Inam Iqbal, Muhamma
Page 103 and 104:
Tetrahedron 2007, 63, 12562-12575.
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List of used abbreviations - RosDok - Universität Rostock

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