List of used abbreviations - RosDok - Universität Rostock
List of used abbreviations - RosDok - Universität Rostock
List of used abbreviations - RosDok - Universität Rostock
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Scheme 5. Possible explanation for the regioselective formation <strong>of</strong> 5e<br />
Treatment <strong>of</strong> 2-(arylthio)benzoates 5b,c,e,f,g,i,j with concentrated sulfuric acid<br />
resulted in an intramolecular Friedel-Crafts cyclization to give the thioxanthones 6a-g<br />
in excellent yields (Scheme 6, Table 2). The structures <strong>of</strong> all products were<br />
elucidated by spectroscopic methods. The structure <strong>of</strong> 6f was independently<br />
confirmed by X-ray crystal structure analysis (Figure 1).<br />
R 1<br />
Me<br />
S<br />
O<br />
R 2<br />
OMe<br />
i<br />
20<br />
R 1<br />
Me<br />
S<br />
R 3<br />
R 3<br />
5b,c,e,f,g,i,j 6a-g<br />
Scheme 6. Synthesis <strong>of</strong> 6a-g. Conditions: i, conc H2SO4 20 °C, 2 h<br />
R 2<br />
O