DÃ©formation photoinduite dans les films minces contenant des ...

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Contentsix4.2.1.1 Deformation induced in the tip near-field under uniformillumination . . . . . . . . . . . . . . . . . . . . . . . . . 1234.2.1.2 Direct comparison between near-field and far-field deformationeffects . . . . . . . . . . . . . . . . . . . . . . . . 1254.2.1.3 Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . 1294.2.2 Apertureless near-field photomechanical response of hybridmetal/azo-polymer layered structures . . . . . . . . . . . . . . . . 1314.2.2.1 Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . 1334.3 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134pastel-00527388, version 1 - 19 Oct 20105 Nanostructured hybrid systems 1365.1 Gold nanoparticles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1365.1.1 Gold nanoparticles on a non functionalized photochromic surface . 1375.1.2 Particle dispersion and surface functionalization . . . . . . . . . . 1395.2 Hybrid optically nano-structured organized surfaces . . . . . . . . . . . . 1425.2.1 Complex structures . . . . . . . . . . . . . . . . . . . . . . . . . . . 1425.2.1.1 Grid fabrication . . . . . . . . . . . . . . . . . . . . . . . 1425.2.2 Optical pattern tansfer . . . . . . . . . . . . . . . . . . . . . . . . . 1465.3 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147A Electromagnetic field calculations 155A.1 Calculation of the electric field polarization spatial distribution . . . . . . 155A.1.1 s-polarized interfering beams (ϕ 1 = ϕ 2 = 0 ◦ ) . . . . . . . . . . . . 158A.1.2 p-polarized interfering beams (ϕ 1 = ϕ 2 = 90 ◦ ) . . . . . . . . . . . . 159A.1.3 ±45 ◦ polarized interfering beams (ϕ 1 = −ϕ 2 = 45 ◦ ) . . . . . . . . 159B Photoisomerization dynamics 160B.1 Photostationary equilibrium . . . . . . . . . . . . . . . . . . . . . . . . . . 160C Photo-induced mechanical work 163C.1 Deformation energy estimation . . . . . . . . . . . . . . . . . . . . . . . . 163D Photo-induced deformation in PMMA-DR1 165D.1 Polarization effects in PMMA-DR1 at different power densities . . . . . . 165Bibliography 168
Page 1 and 2: Thèse de doctorat de l’Ecole Pol
Page 3 and 4: AcknowledgementsAt the beginning it
Page 5 and 6: vpastel-00527388, version 1 - 19 Oc
Page 7: ContentsAbstractiAcknowledgementsii
Page 11 and 12: List of Figuresxipastel-00527388, v
Page 13 and 14: List of Tables2.1 Sol-gel Si-DR1 pr
Page 15 and 16: L’opera che comunica ha una compl
Page 17 and 18: Introductionpastel-00527388, versio
Page 19 and 20: Introduction 3Subsequently, we use
Page 21 and 22: Introduction 5[7] S. P. Bian, J. M.
Page 23 and 24: Chapter 1pastel-00527388, version 1
Page 25 and 26: Chapter 1. The azobenzene molecules
Page 33 and 34: Bibliography[1] G. S. Hartley. The
Page 39 and 40: Chapter 2Experimental setup and sam
Page 41 and 42: Chapter 2. Experimental setup and s
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Chapter 2. Experimental setup and s
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Absc02AbsChapter 2. Experimental se
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Bibliography[1] Nathalie Landraud.
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Chapter 3. Microscopic mechanisms a
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N.B. I i = E i E i *Chapter 3. Micr
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Chapter 3. Microscopic mechanismsEm
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TOPO0-3sA = h(x brights) ! h(x dark
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Ipara - Iperp/2Chapter 3. Microscop
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Bibliography[1] Almeria Natansohn a
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Chapter 4pastel-00527388, version 1
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Chapter 4. Photomechanical response
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PP-360s-4VChapter 4. Photomechanica
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PP 2VChapter 4. Photomechanical res
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Bibliography[1] Nirmal K. Viswanath
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Chapter 5. Nanostructured hybrid sy
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Conclusions 153timelight ON" # 800
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Appendix AElectromagnetic field cal
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Appendix A 157For i = x, y, z, bein
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Appendix A 159A.1.2 p-polarized int
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Appendix B 161• P is the light po
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Appendix CPhoto-induced mechanical
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Appendix DPhoto-induced deformation
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Appendix D 167S-interf. ONP-interf.
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Bibliography 169[7] S. P. Bian, J.
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Bibliography 171[26] P. Karageorgie
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Bibliography 173on azo-polymer film
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Bibliography 175[63] N. Tabiryan, S
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