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Condensed-Matter Physics: Inscrutably alluring to ... - Tarun Chitra

Condensed-Matter Physics: Inscrutably alluring to ... - Tarun Chitra

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What is <strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>?<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong><strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong> is the study of matter that is in thecondensed phase — <strong>Matter</strong> which is not gaseous.


What is <strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>?<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong><strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong> is the study of matter that is in thecondensed phase — <strong>Matter</strong> which is not gaseous.One can define a gaseeous phase in many ways, with a simpleway being defined by the container that a gas is kept in. A gascan theoretically expand <strong>to</strong> an arbitrarily large volume.


QM, for the win<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>With the advent of Quantum Mechanics in the 1920s, theoristsbegan <strong>to</strong> tackle the physics of solids with their newfangled <strong>to</strong>olsTheory of solids was ’finalized’ by physicists such as Felix Blochand Léon Brillouin. Enrico Fermi made important contribution<strong>to</strong> the theory of Fermionic gasesLiquid state, other phases of nature left out from this early-20thcentury boom in solid-state physics1978: APS changes the name of ’Solid-State <strong>Physics</strong>’ <strong>to</strong>’<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>’


Active Areas of Research in <strong>Condensed</strong>-<strong>Matter</strong>(C-M)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


Active Areas of Research in <strong>Condensed</strong>-<strong>Matter</strong>(C-M)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Superfluidity and SupersoliditySuperconductivity


Active Areas of Research in <strong>Condensed</strong>-<strong>Matter</strong>(C-M)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Superfluidity and SupersoliditySuperconductivityProtein <strong>Physics</strong>Supercooled Liquids


So. . . How does one formulate problems in C-M?<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong><strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong> involves the study of systems withlots of particles. Forget the three-body problem — consider the10 22 -body problem


So. . . How does one formulate problems in C-M?<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong><strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong> involves the study of systems withlots of particles. Forget the three-body problem — consider the10 22 -body problemSolid-state systems: Mathematically ’easy’ because solids have adefinite, static a<strong>to</strong>m density that they can be approximated by alattice. Lattice discretizes phase space and real space, enforcesperiodicity conditions.


So. . . How does one formulate problems in C-M?<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong><strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong> involves the study of systems withlots of particles. Forget the three-body problem — consider the10 22 -body problemSolid-state systems: Mathematically ’easy’ because solids have adefinite, static a<strong>to</strong>m density that they can be approximated by alattice. Lattice discretizes phase space and real space, enforcesperiodicity conditions.The liquid phase and various non-classical phases tend <strong>to</strong> bemuch more difficult <strong>to</strong> study – cannot force a lattice structureon a liquid and various non-classical phases need not behomogeneous.


All hope is not lost!<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Even without a nice a<strong>to</strong>mic-level description of all liquids, scientistshave been fairly adept at studying liquids macroscopic since the timeof the Bernoullis. Two key ingredients <strong>to</strong> studying liquids:


All hope is not lost!<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Even without a nice a<strong>to</strong>mic-level description of all liquids, scientistshave been fairly adept at studying liquids macroscopic since the timeof the Bernoullis. Two key ingredients <strong>to</strong> studying liquids:1 Approximate liquids as a ’limiting’ phase of solids and/or gases.Classical fluid dynamics: a liquid is a solid that ’deforms’ easilyEarly QM: Fermi liquids are ideal Fermi gases (e.g n-bodysystems with a non-interacting, SO(3)-invariant potentials)which are perturbed by an attractive interacting potential.


All hope is not lost!<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Even without a nice a<strong>to</strong>mic-level description of all liquids, scientistshave been fairly adept at studying liquids macroscopic since the timeof the Bernoullis. Two key ingredients <strong>to</strong> studying liquids:1 Approximate liquids as a ’limiting’ phase of solids and/or gases.Classical fluid dynamics: a liquid is a solid that ’deforms’ easilyEarly QM: Fermi liquids are ideal Fermi gases (e.g n-bodysystems with a non-interacting, SO(3)-invariant potentials)which are perturbed by an attractive interacting potential.2 Elucidate the symmetry-breaking that takes place in a liquid. Thetheory of solids is particularly nice because the system has quite a bi<strong>to</strong>f symmetry; if we can figure out which symmetries of a solid stillapply <strong>to</strong> liquids, then we can ’naturally’ write down a Lagrangian fora liquid system


Basic Mathematical Framework: Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematiciansLet’s become a lot more formal with the definitions of the pastfew slides. 1<strong>Tarun</strong> <strong>Chitra</strong>1 There are far more general definitions of a lattice such as:’Any discrete subgroup Γ of a Lie Group G such that G/Γ has finite Haar measure’


Basic Mathematical Framework: Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Let’s become a lot more formal with the definitions of the pastfew slides. 1DefinitionAn lattice L in R n is a set of Z-translates of a basis {⃗e i } n i=1 . That is,L = {∑ ni=1 a ∣i⃗e i ai ∈ Z}. A cell is any Z n -translate of theparallelpiped spanned by {⃗e i } n i=1 (the unit cell)1 There are far more general definitions of a lattice such as:’Any discrete subgroup Γ of a Lie Group G such that G/Γ has finite Haar measure’


Basic Mathematical Framework: Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Let’s become a lot more formal with the definitions of the pastfew slides. 1DefinitionAn lattice L in R n is a set of Z-translates of a basis {⃗e i } n i=1 . That is,L = {∑ ni=1 a ∣i⃗e i ai ∈ Z}. A cell is any Z n -translate of theparallelpiped spanned by {⃗e i } n i=1 (the unit cell)In solid-state physics, we assume that virtually all systems canlocally be described by a lattice. By construction, a latticeadmits a free, transitive Z n -action which means that one needonly study physics in the unit cell Span(⃗e 1 , . . . ,⃗e n ) and then usethe Z n -action <strong>to</strong> translate the dynamics <strong>to</strong> any other cell. Thisis analogous <strong>to</strong> the setup for the NT algorithm that An<strong>to</strong>n relieson.1 There are far more general definitions of a lattice such as:’Any discrete subgroup Γ of a Lie Group G such that G/Γ has finite Haar measure’


Basic Mathematical Framework: Symmetries<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


Basic Mathematical Framework: Symmetries<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematiciansSo what is a symmetry? To answer that we need <strong>to</strong> recall a bi<strong>to</strong>f classical mechanics<strong>Tarun</strong> <strong>Chitra</strong>


Basic Mathematical Framework: Symmetries<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>So what is a symmetry? To answer that we need <strong>to</strong> recall a bi<strong>to</strong>f classical mechanicsLet’s recall that informal statement of Hamil<strong>to</strong>n’s Principle ofLeast Action: ’Particles are lazy, they want <strong>to</strong> take the shortestpossible path while expending the least energy’


Basic Mathematical Framework: Symmetries<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>So what is a symmetry? To answer that we need <strong>to</strong> recall a bi<strong>to</strong>f classical mechanicsLet’s recall that informal statement of Hamil<strong>to</strong>n’s Principle ofLeast Action: ’Particles are lazy, they want <strong>to</strong> take the shortestpossible path while expending the least energy’How do we formalize this? One way is <strong>to</strong> use a Lagrangian.


Basic Mathematical Framework: Symmetries<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>So what is a symmetry? To answer that we need <strong>to</strong> recall a bi<strong>to</strong>f classical mechanicsLet’s recall that informal statement of Hamil<strong>to</strong>n’s Principle ofLeast Action: ’Particles are lazy, they want <strong>to</strong> take the shortestpossible path while expending the least energy’How do we formalize this? One way is <strong>to</strong> use a Lagrangian.Physically, a Lagrangian L is fairly simple <strong>to</strong> define:L = ∑ {Kinetic Energy Terms} − ∑ {Potential Energy Terms}


Basic Mathematical Framework: Symmetries<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>So what is a symmetry? To answer that we need <strong>to</strong> recall a bi<strong>to</strong>f classical mechanicsLet’s recall that informal statement of Hamil<strong>to</strong>n’s Principle ofLeast Action: ’Particles are lazy, they want <strong>to</strong> take the shortestpossible path while expending the least energy’How do we formalize this? One way is <strong>to</strong> use a Lagrangian.Physically, a Lagrangian L is fairly simple <strong>to</strong> define:L = ∑ {Kinetic Energy Terms} − ∑ {Potential Energy Terms}We need <strong>to</strong> define the arguments of a Lagrangian: Particle’spath x(t), velocity ẋ(t) and possibly an explicit dependence ontime t and further spatial and time derivatives


Basic Mathematical Framework: Symmetries<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>So what is a symmetry? To answer that we need <strong>to</strong> recall a bi<strong>to</strong>f classical mechanicsLet’s recall that informal statement of Hamil<strong>to</strong>n’s Principle ofLeast Action: ’Particles are lazy, they want <strong>to</strong> take the shortestpossible path while expending the least energy’How do we formalize this? One way is <strong>to</strong> use a Lagrangian.Physically, a Lagrangian L is fairly simple <strong>to</strong> define:L = ∑ {Kinetic Energy Terms} − ∑ {Potential Energy Terms}We need <strong>to</strong> define the arguments of a Lagrangian: Particle’spath x(t), velocity ẋ(t) and possibly an explicit dependence ontime t and further spatial and time derivativesFormal definition: A Lagrangian is a C ∞ map between ann-manifold M and a target manifold T (usually R, C, H or C 2n orthe cotangent bundle of any symplectic manifold)


’Physicists can’t get enough action’ — TBK<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


’Physicists can’t get enough action’ — TBK<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>So now we need some way <strong>to</strong> define ’the shortest possible paththat costs the least energy’ in a way that is manifestlycompatible with New<strong>to</strong>n’s Laws


’Physicists can’t get enough action’ — TBK<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>So now we need some way <strong>to</strong> define ’the shortest possible paththat costs the least energy’ in a way that is manifestlycompatible with New<strong>to</strong>n’s LawsIntroducing the action S. Mathematically, the action is definedas S = ∫ R L(x(t), ∂ αx(t), ∂ α ∂ α x(t), . . . , t)dt


’Physicists can’t get enough action’ — TBK<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>So now we need some way <strong>to</strong> define ’the shortest possible paththat costs the least energy’ in a way that is manifestlycompatible with New<strong>to</strong>n’s LawsIntroducing the action S. Mathematically, the action is definedas S = ∫ R L(x(t), ∂ αx(t), ∂ α ∂ α x(t), . . . , t)dtHamil<strong>to</strong>n and Lagrange showed (in different ways) that byminimizing the Lagrangian with respect <strong>to</strong> its arguments, onecould obtain a particle’s path x(t) and velocity ẋ(t) that isconsistent with what one would expect from New<strong>to</strong>nianmechanics. This makes life a lot easier, because for a lot ofproblems it is much easier <strong>to</strong> ’guess’ kinetic and potentialenergies as opposed <strong>to</strong> computing all forces


Actions and Symmetry<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


Actions and Symmetry<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematiciansAction: S[x(t), ẋ(t), t].<strong>Tarun</strong> <strong>Chitra</strong>


Actions and Symmetry<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Action: S[x(t), ẋ(t), t].Since x(t), ẋ(t) ∈ R 3 , any group that acts freely/transitively on R 3can act on the trajec<strong>to</strong>ries (pointwise). Representation of G:Λ : G → Aut(R 3 ). G generates a symmetry of S if:S[x(t), ẋ(t), t] = S[Λ(g)x(t), Λ(g)ẋ(t), t]∀g ∈ G


Actions and Symmetry<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Action: S[x(t), ẋ(t), t].Since x(t), ẋ(t) ∈ R 3 , any group that acts freely/transitively on R 3can act on the trajec<strong>to</strong>ries (pointwise). Representation of G:Λ : G → Aut(R 3 ). G generates a symmetry of S if:S[x(t), ẋ(t), t] = S[Λ(g)x(t), Λ(g)ẋ(t), t]∀g ∈ GMinimizing the action stems from a somewhat empirical consideration— in many classical physical systems, the time expectations ofkinetic and potential energy were approximately equal. That is,E t [T (ẋ)] ≈ E t [V (x, ẋ)]


Noether’s Theorem (<strong>Physics</strong> Version)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


Noether’s Theorem (<strong>Physics</strong> Version)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>What about conservation laws? How do we force Lagrangianmechanics (as vaguely defined) <strong>to</strong> have conservation laws


Noether’s Theorem (<strong>Physics</strong> Version)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>What about conservation laws? How do we force Lagrangianmechanics (as vaguely defined) <strong>to</strong> have conservation lawsNoether’s Theorem (Emmy Noether, 1918): ’For everysymmetry of an action, there exists a conserved quantityassociated <strong>to</strong> the symmetry.’ In classical mechanics this quantityis the conserved momentum:P(x, ẋ) = ∑ i∂L∂ẋ iK i (x))where K i (q) is the linear ’component’ (think Taylor’s theorem)of the symmetry (e.g. Λx = x + ɛK(x))


Example<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Consider (ẋ the Lagrangian for throwing a ball up in the air,L = m 2 2+ ẏ 2 + ż 2) − mgz. This is invariant under translations ofx, y, e.g. x ↦→ x + ɛ, y ↦→ y + ɛ ′ . These two symmetries generate twodifferent conserved momenta (one with K x = 1, K y = K z = 0 and theother with K y = 1:


Example<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Consider (ẋ the Lagrangian for throwing a ball up in the air,L = m 2 2+ ẏ 2 + ż 2) − mgz. This is invariant under translations ofx, y, e.g. x ↦→ x + ɛ, y ↦→ y + ɛ ′ . These two symmetries generate twodifferent conserved momenta (one with K x = 1, K y = K z = 0 and theother with K y = 1:P 1 (x, y, z, ẋ, ẏ, ż) = ∂L∂ẋ K x + ∂L∂ẏ K y + ∂L∂ż K z = mẋ (1)P 2 (x, y, z, ẋ, ẏ, ż) = ∂L∂ẋ K x + ∂L∂ẏ K y + ∂L∂ż K z = mẏ (2)


Noether’s Theorem (Math Version)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


Noether’s Theorem (Math Version)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Hamil<strong>to</strong>nian System (M, ω, H): Symplectic manifold (M, ω)with Hamil<strong>to</strong>nian H ∈ C ∞ (M). Every Hamil<strong>to</strong>nian H gives rise<strong>to</strong> a Hamil<strong>to</strong>nian Vec<strong>to</strong>r Field, X H = ω −1 (dH).


Noether’s Theorem (Math Version)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Hamil<strong>to</strong>nian System (M, ω, H): Symplectic manifold (M, ω)with Hamil<strong>to</strong>nian H ∈ C ∞ (M). Every Hamil<strong>to</strong>nian H gives rise<strong>to</strong> a Hamil<strong>to</strong>nian Vec<strong>to</strong>r Field, X H = ω −1 (dH).Infinitesmal Symmetry: Smooth vec<strong>to</strong>r field V ∈ Γ(M, TM)with flow θ : D → M such that L XH ω = ω, θ ∗ H = H.


Noether’s Theorem (Math Version)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Hamil<strong>to</strong>nian System (M, ω, H): Symplectic manifold (M, ω)with Hamil<strong>to</strong>nian H ∈ C ∞ (M). Every Hamil<strong>to</strong>nian H gives rise<strong>to</strong> a Hamil<strong>to</strong>nian Vec<strong>to</strong>r Field, X H = ω −1 (dH).Infinitesmal Symmetry: Smooth vec<strong>to</strong>r field V ∈ Γ(M, TM)with flow θ : D → M such that L XH ω = ω, θ ∗ H = H.Conserved Quantity: f ∈ C ∞ (M) such that f is constantalong any integral curve (read: trajec<strong>to</strong>ry) of X H . Also definedas f ∈ C ∞ (M) ∋ {H, f } = 0.


Noether’s Theorem (Math Version)<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Hamil<strong>to</strong>nian System (M, ω, H): Symplectic manifold (M, ω)with Hamil<strong>to</strong>nian H ∈ C ∞ (M). Every Hamil<strong>to</strong>nian H gives rise<strong>to</strong> a Hamil<strong>to</strong>nian Vec<strong>to</strong>r Field, X H = ω −1 (dH).Infinitesmal Symmetry: Smooth vec<strong>to</strong>r field V ∈ Γ(M, TM)with flow θ : D → M such that L XH ω = ω, θ ∗ H = H.Conserved Quantity: f ∈ C ∞ (M) such that f is constantalong any integral curve (read: trajec<strong>to</strong>ry) of X H . Also definedas f ∈ C ∞ (M) ∋ {H, f } = 0.Theorem(Noether) If f ∈ C ∞ (M) is a conserved quantity, then itsHamil<strong>to</strong>nian vec<strong>to</strong>r field X f is an infinitesmal symmetry. Conversely ifH 1 (M; R) = 0, then every infinitesmal symmetry is the Hamil<strong>to</strong>nianvec<strong>to</strong>r field of a conserved quantity.


Symmetries of Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


Symmetries of Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Set of isometries (distance-preserving) maps = physical intuitionthat rotation/translation of coordinate system shouldn’t affectthe physics. Distance-preservation is req’d <strong>to</strong> ensure that onedoesn’t change an energy functional, as most energy functionalsrequire a metric.


Symmetries of Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Set of isometries (distance-preserving) maps = physical intuitionthat rotation/translation of coordinate system shouldn’t affectthe physics. Distance-preservation is req’d <strong>to</strong> ensure that onedoesn’t change an energy functional, as most energy functionalsrequire a metric.What are the isometries of a cubic unit cell? Hint: It’s not adihedral group, but it decomposes similarly (has a subgroup ofreflections ∼ = Z 2 )


Symmetries of Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Set of isometries (distance-preserving) maps = physical intuitionthat rotation/translation of coordinate system shouldn’t affectthe physics. Distance-preservation is req’d <strong>to</strong> ensure that onedoesn’t change an energy functional, as most energy functionalsrequire a metric.What are the isometries of a cubic unit cell? Hint: It’s not adihedral group, but it decomposes similarly (has a subgroup ofreflections ∼ = Z 2 )Proper Rotations (24): Identity rotations about an axis fromcenter <strong>to</strong> face, rotation about an axis from the center of anedge, <strong>to</strong> an opposite edge, rotation about a body diagonal


Symmetries of Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Set of isometries (distance-preserving) maps = physical intuitionthat rotation/translation of coordinate system shouldn’t affectthe physics. Distance-preservation is req’d <strong>to</strong> ensure that onedoesn’t change an energy functional, as most energy functionalsrequire a metric.What are the isometries of a cubic unit cell? Hint: It’s not adihedral group, but it decomposes similarly (has a subgroup ofreflections ∼ = Z 2 )Proper Rotations (24): Identity rotations about an axis fromcenter <strong>to</strong> face, rotation about an axis from the center of anedge, <strong>to</strong> an opposite edge, rotation about a body diagonalRotation Plus a Reflection (24)


Symmetries of Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Set of isometries (distance-preserving) maps = physical intuitionthat rotation/translation of coordinate system shouldn’t affectthe physics. Distance-preservation is req’d <strong>to</strong> ensure that onedoesn’t change an energy functional, as most energy functionalsrequire a metric.What are the isometries of a cubic unit cell? Hint: It’s not adihedral group, but it decomposes similarly (has a subgroup ofreflections ∼ = Z 2 )Proper Rotations (24): Identity rotations about an axis fromcenter <strong>to</strong> face, rotation about an axis from the center of anedge, <strong>to</strong> an opposite edge, rotation about a body diagonalRotation Plus a Reflection (24)Math: Isometry Group of Cube: BC 3∼ = S4 ⋊ Z 2 is the 3rdCoxeter Group, with Coxeter-Dynkin Diagram, ❡ 4


Other types of lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematiciansBut what if they’re not orthonormal? Bieberbach proved whatphysicists already knew: There are only a few types of crystalstructures:<strong>Tarun</strong> <strong>Chitra</strong>


Other types of lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematiciansBut what if they’re not orthonormal? Bieberbach proved whatphysicists already knew: There are only a few types of crystalstructures:<strong>Tarun</strong> <strong>Chitra</strong>


Symmetry-breaking and Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


Symmetry-breaking and Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Intuitively a lattice is ’different’ from an arbitrary particlebecause it is ’rigid’. How can symmetries help us quantify this?


Symmetry-breaking and Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Intuitively a lattice is ’different’ from an arbitrary particlebecause it is ’rigid’. How can symmetries help us quantify this?First things first: What are the set of isometries of a single,thermally-isolated, classical particle that is sitting in a vacuumR n ?Rotations — Represented in n-dimensions by the Lie groupSO(n)Translations — represented by R n , treated as Abelian groupunder addition


Symmetry-breaking and Lattices<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Intuitively a lattice is ’different’ from an arbitrary particlebecause it is ’rigid’. How can symmetries help us quantify this?First things first: What are the set of isometries of a single,thermally-isolated, classical particle that is sitting in a vacuumR n ?Rotations — Represented in n-dimensions by the Lie groupSO(n)Translations — represented by R n , treated as Abelian groupunder additionThese are differentiable symmetries, as the sets of rotations andtranslations turn out <strong>to</strong> be Lie groups and hence smoothmanifolds (so that differentiation can be defined).


The Poincaré Group<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


The Poincaré Group<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>This <strong>to</strong>tal set of symmetries of a free particle is known as thePoincaré Group P(R n ). However, note that P(R 3 ) ≁ = SO(3) × R3and in general, P(R n ) ≁ = SO(n) × R n for n > 1. To see whyconsider two rotations and translations(R, y), (˜R, ỹ), R, ˜R ∈ SO(3), y, ỹ ∈ R 3 . A rotation plustranslation acts on a vec<strong>to</strong>r x ∈ R 3 as (R, y) · x = Rx + y.Hence we have:(R, y) ∗ P (˜R, ỹ) · x = (R, y) · (˜Rx + ỹ)= R ˜Rx + Rỹ + y = (R ˜R, Rỹ + y) · x


The Poincaré Group<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>This <strong>to</strong>tal set of symmetries of a free particle is known as thePoincaré Group P(R n ). However, note that P(R 3 ) ≁ = SO(3) × R3and in general, P(R n ) ≁ = SO(n) × R n for n > 1. To see whyconsider two rotations and translations(R, y), (˜R, ỹ), R, ˜R ∈ SO(3), y, ỹ ∈ R 3 . A rotation plustranslation acts on a vec<strong>to</strong>r x ∈ R 3 as (R, y) · x = Rx + y.Hence we have:(R, y) ∗ P (˜R, ỹ) · x = (R, y) · (˜Rx + ỹ)= R ˜Rx + Rỹ + y = (R ˜R, Rỹ + y) · xHence we have P(R 3 ) ∼ = R 3 ⋊ ϕ SO(3) where ⋊ ϕ is thesemi-direct product with respect <strong>to</strong> ϕ : SO(3) → Aut(R 3 )defined as ϕ(R)(y) = Ry


Symmetry-Breaking<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


Symmetry-Breaking<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Now we can define symmetry-breaking: When dynamics force aphysical system <strong>to</strong> have a smaller group (subgroup) of the staticsymmetries.


Symmetry-Breaking<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Now we can define symmetry-breaking: When dynamics force aphysical system <strong>to</strong> have a smaller group (subgroup) of the staticsymmetries.Physical system on Lattice: We can think of our system asembedded in R 3 , but with a much smaller symmetry group (e.g.BC 3 ⋊ ϕ Z n )


Symmetry-Breaking<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>Now we can define symmetry-breaking: When dynamics force aphysical system <strong>to</strong> have a smaller group (subgroup) of the staticsymmetries.Physical system on Lattice: We can think of our system asembedded in R 3 , but with a much smaller symmetry group (e.g.BC 3 ⋊ ϕ Z n )Practical Implementation:Start with a Lagrangian with a lot of symmetry L s and solve forthe trajec<strong>to</strong>ry/dynamicsPerturb L s with a non-symmetric Lagrangian, L p by trying <strong>to</strong>compute the dynamics of L = L s + ɛL p, ɛ > 0, ɛ ≪ 1.Likely: You will be unable <strong>to</strong> solve the Euler-Lagrange equationsfor this Lagrangian. Using Taylor’s Theorem repeatedly (and Imean repeatedly) will make the new approximate solution for Ldepend heavily on the solution for L s


Example of Symmetry-Breaking: Superfluidity<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong>


Example of Symmetry-Breaking: Superfluidity<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Physics</strong>: Liquid 3 He has no viscosity (or creep) at T < 3mK. Assuch, there exist at least three phases of matter of 3 He. This isa quantum phenomena, so we need <strong>to</strong> consider spin.<strong>Tarun</strong> <strong>Chitra</strong>


Example of Symmetry-Breaking: Superfluidity<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong><strong>Physics</strong>: Liquid 3 He has no viscosity (or creep) at T < 3mK. Assuch, there exist at least three phases of matter of 3 He. This isa quantum phenomena, so we need <strong>to</strong> consider spin.Symmetry: Local SO(3) × SO(3) × U(1) symmetry [Shouldremind you of the Standard Model, SU(3) × SU(2) × U(1)!!]


Example of Symmetry-Breaking: Superfluidity<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong><strong>Physics</strong>: Liquid 3 He has no viscosity (or creep) at T < 3mK. Assuch, there exist at least three phases of matter of 3 He. This isa quantum phenomena, so we need <strong>to</strong> consider spin.Symmetry: Local SO(3) × SO(3) × U(1) symmetry [Shouldremind you of the Standard Model, SU(3) × SU(2) × U(1)!!]Lagrangian density for Free Energy (Lagrangian of Superfluid3 He, Phys. Rev. B, 37(7), S. Theodorakis):L = k 1 [Ω ∗ µlΩ µl ] + ik 2 [Ω ∗ µlA µl − Ω µl A ∗ µl] + k 3 H µ ɛ µνσ A vi Ω ∗ σir+ k 3 H µ ɛ µνσ A ∗ νiΩ σi − F d − F mag + g S22


Example of Symmetry-Breaking: Superfluidity<strong>Condensed</strong>-<strong>Matter</strong> <strong>Physics</strong>:<strong>Inscrutably</strong><strong>alluring</strong> <strong>to</strong>Physicists,Chemists andevenMathematicians<strong>Tarun</strong> <strong>Chitra</strong><strong>Physics</strong>: Liquid 3 He has no viscosity (or creep) at T < 3mK. Assuch, there exist at least three phases of matter of 3 He. This isa quantum phenomena, so we need <strong>to</strong> consider spin.Symmetry: Local SO(3) × SO(3) × U(1) symmetry [Shouldremind you of the Standard Model, SU(3) × SU(2) × U(1)!!]Lagrangian density for Free Energy (Lagrangian of Superfluid3 He, Phys. Rev. B, 37(7), S. Theodorakis):rL = k 1 [Ω ∗ µlΩ µl ] + ik 2 [Ω ∗ µlA µl − Ω µl A ∗ µl] + k 3 H µ ɛ µνσ A vi Ω ∗ σi+ k 3 H µ ɛ µνσ A ∗ νiΩ σi − F d − F mag + g S22Symmetry-breaking: Contributions from A, Ω are invariant underSO(3) × SO(3) × U(1); F d , F mag are not. They contribute <strong>to</strong> anenergetically unfavorable liquid state at low T

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