Aviblue - Lohmann Animal Health

Conforms to ANSI Z400.1-2004 StandardMaterial Safety Data SheetAviBlue ®1. Product and company identificationProduct name : AviBlue ®Code : 30697Material usesSupplier/ManufacturerValidation date : 11/15/201 0: Other non-specified industry: Intended for the use in stock solutions and drinking-watersystems for animals.: Lohmann Animal Health GmbH & Co. KGHeinz-Lohmann-Straße 427472 Cuxhaven, GermanyTel: +49-4721-747-0Fax: +49-4721-747-554MSDS authored by: KMK Regulatory Services inc.In case of emergency : +49-761-192402. Hazards identificationEmergency overviewPhysical stateColorOdorSignal wordHazard statementsPrecautionary measuresOSHA/HCS statusPotential acute health effectsInhalationIngestionSkinEyesPotential chronic health effectsChronic effectsCarcinogenicityMutagenicityTeratogenicityDevelopmental effectsFertility effectsTarget organs: Solid. [Effervescent granule.]: Blue.: Odorless.: WARNING!: CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. CONTAINSMATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMALDATA. SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSECANCER.: Do not handle until all safety precautions have been read and understood. Obtainspecial instructions before use. Use only with adequate ventilation. Do not eat, drink orsmoke when using this product. Avoid contact with eyes, skin and clothing. Keepcontainer tightly closed. Use personal protective equipment as required. Washthoroughly after handling.: This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).: Severely irritating to the respiratory system. Exposure to decomposition products maycause a health hazard. Serious effects may be delayed following exposure.: No known significant effects or critical hazards.: Severely irritating to the skin.: Irritating to eyes.: Contains material that may cause target organ damage, based on animal data.: Contains material which may cause cancer. Risk of cancer depends on duration andlevel of exposure.: No known significant effects or critical hazards.: No known significant effects or critical hazards.: No known significant effects or critical hazards.: No known significant effects or critical hazards.: Contains material which may cause damage to the following organs: upper respiratorytract.KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services Réglementaires KMK Inc.www.kmkregservices.com1/6

2. Hazards identificationOver-exposure signs/symptomsInhalationIngestionSkinEyesMedical conditionsaggravated by overexposureSee toxicological information (section 11): Adverse symptoms may include the following:respiratory tract irritationcoughing: No specific data.: Adverse symptoms may include the following:irritationredness: Adverse symptoms may include the following:pain or irritationwateringrednessAviBlue ®: Pre-existing disorders involving any target organs mentioned in this MSDS as being atrisk may be aggravated by over-exposure to this product.3. Composition/information on ingredientsName CAS number %Sodium hydrogencarbonate 144-55-8 10 - 30Sodium thiosulphate 7772-98-7 10 - 30Citric acid 77-92-9 5 - 15Polyethylene glycol 25322-68-3 5 - 10Sodium carbonate 497-19-8 1 - 10Hydrogen [4-[4-(diethylamino)-5'-hydroxy-2',4'-disulphonatobenzhydrylidene]cyclohexa-2,5-dien-1-ylidene]diethylammonium, monosodium salt20262-76-4 1 - 5There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, areclassified as hazardous to health or the environment and hence require reporting in this section.4. First aid measuresEye contactSkin contactInhalationIngestionProtection of first-aidersNotes to physician5. Fire-fighting measuresFlammability of the productExtinguishing mediaSuitableNot suitableHazardous decompositionproductsSpecial protectiveequipment for fire-fighters: Immediately flush eyes with plenty of water for at least 20 minutes, occasionally liftingthe upper and lower eyelids. Get medical attention if symptoms occur.: In case of contact, immediately flush skin with plenty of water for at least 20 minutes.: Move exposed person to fresh air.: Wash out mouth with water. Do not induce vomiting unless directed to do so by medicalpersonnel. Never give anything by mouth to an unconscious person. Get medicalattention if symptoms occur.: If it is suspected that fumes are still present, the rescuer should wear an appropriatemask or self-contained breathing apparatus.: No specific treatment. Treat symptomatically.: No specific fire or explosion hazard.: Use an extinguishing agent suitable for the surrounding fire.: None known.: Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxidessulfur oxides: Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services Réglementaires KMK Inc.www.kmkregservices.com2/6

AviBlue ®6. Accidental release measuresPersonal precautionsEnvironmental precautionsMethods for cleaning upSmall spillLarge spill: Provide adequate ventilation. Put on appropriate personal protective equipment (seeSection 8).: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).: Vacuum or sweep up material and place in a designated, labeled waste container.Dispose of via a licensed waste disposal contractor.: Prevent entry into sewers, water courses, basements or confined areas. Vacuum orsweep up material and place in a designated, labeled waste container. Dispose of via alicensed waste disposal contractor. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.7. Handling and storageHandlingStorage: Put on appropriate personal protective equipment (see Section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking and smoking.Do not get in eyes or on skin or clothing. Do not ingest. Use only with adequateventilation. Wear appropriate respirator when ventilation is inadequate. Emptycontainers retain product residue and can be hazardous.: Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Keep container tightly closed and sealed until readyfor use. Containers that have been opened must be carefully resealed and kept uprightto prevent leakage. Do not store in unlabeled containers. Use appropriate containmentto avoid environmental contamination.8. Exposure controls/personal protectionIngredientExposure limitsPolyethylene glycol AIHA WEEL (United States, 1/2009).TWA: 10 mg/m³ 8 hour(s). Form: AerosolRecommended monitoringproceduresEngineering measuresHygiene measuresPersonal protectionRespiratoryHandsEyesSkin: Personal, workplace atmosphere or biological monitoring may be required to determinethe effectiveness of the ventilation or other control measures and/or the necessity to userespiratory protective equipment.: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits.: Ensure that eyewash stations and safety showers are close to the workstation location.Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.: Not required under normal conditions of use. Respirator selection must be based onknown or anticipated exposure levels, the hazards of the product and the safe workinglimits of the selected respirator. Wear an appropriate NIOSH approved respirator ifconcentration levels exceed the safe exposure limits. Use appropriate NIOSH approveddust respirator if PEL/TLV may be exceeded.: Not required under normal conditions of use. Use gloves appropriate for work or taskbeing performed. Recommended: Natural rubber (latex).: Not required under normal conditions of use. Safety eyewear should be used whenthere is a likelihood of exposure. Recommended: Safety glasses with side shields.: No special protective clothing is required. Personal protective equipment for the bodyshould be selected based on the task being performed and the risks involved and shouldbe approved by a specialist before handling this product. Recommended: Lab coat.KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services Réglementaires KMK Inc.www.kmkregservices.com3/6

8. Exposure controls/personal protectionEnvironmental exposurecontrols9. Physical and chemical propertiesPhysical stateFlash pointColorOdorAviBlue ®: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation.: Solid. [Effervescent granule.]: [Product does not sustain combustion.]: Blue.: Odorless.pH : 7.5 [Conc. (% w/w): 1%]Relative density : 0.810. Stability and reactivityChemical stabilityConditions to avoidIncompatible materialsHazardous decompositionproductsPossibility of hazardousreactions: The product is stable.: Avoid exposure - obtain special instructions before use.: No specific data.11. Toxicological informationAcute toxicity: Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxidessulfur oxides: Under normal conditions of storage and use, hazardous reactions will not occur.Product/ingredient name Result Species Dose ExposureCitric acid LD50 Oral Rat 3 g/kg -Sodium carbonate LD50 Oral Rat 4090 mg/kg -Irritation/CorrosionProduct/ingredient name Result Species Score Exposure ObservationCitric acid Eyes - Severe irritant Rabbit - - -Skin - Mild irritant Rabbit - - -Skin - Moderate irritant Rabbit - - -Sodium carbonate Eyes - Mild irritant Rabbit - - -Eyes - Moderate irritant Rabbit - - -Eyes - Severe irritant Rabbit - - -Skin - Mild irritant Rabbit - - -Polyethylene glycol Eyes - Mild irritant Rabbit - - -Skin - Mild irritant Rabbit - - -12. Ecological informationEcotoxicityAquatic ecotoxicity: No known significant effects or critical hazards.Product/ingredient name Result Species ExposureCitric acid Acute LC50 160000 ug/L Marine water Crustaceans - Carcinus maenas - Adult 48 hoursSodium carbonate Acute EC50 199.82 mg/L Fresh water Daphnia - Ceriodaphnia dubia - Neonate - 48 hours1000000 ug/L Fresh water Fish - Salmo salar - Parr - 8.2 to 11.7 cm -5.1 to 14.1 g96 hoursKMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services Réglementaires KMK Inc.www.kmkregservices.com4/6

13. Disposal considerationsWaste disposalAviBlue ®: The generation of waste should be avoided or minimized wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Significant quantities of waste product residuesshould not be disposed of via the foul sewer but processed in a suitable effluenttreatment plant. Dispose of surplus and non-recyclable products via a licensed wastedisposal contractor. Disposal of this product, solutions and any by-products should at alltimes comply with the requirements of environmental protection and waste disposallegislation and any regional local authority requirements. Avoid dispersal of spilledmaterial and runoff and contact with soil, waterways, drains and sewers.Disposal should be in accordance with applicable regional, national and local laws and regulations.Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handlinginformation and protection of employees.14. Transport informationDOT/TDG/MXT/IMDG/IATA: Not regulated.15. Regulatory informationHCS ClassificationU.S. Federal regulations: Irritating materialCarcinogenTarget organ effects: United States inventory (TSCA 8b): Not determined.SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Sodium thiosulphate; Citric acid;Sodium carbonateSARA 311/312 MSDS distribution - chemical inventory - hazard identification:Sodium thiosulphate: Immediate (acute) health hazard; Citric acid: Immediate (acute)health hazard; Sodium carbonate: Immediate (acute) health hazard, Delayed (chronic)health hazardClean Air Act Section112(b) Hazardous AirPollutants (HAPs)Clean Air Act Section 602Class I SubstancesClean Air Act Section 602Class II SubstancesDEA List I Chemicals(Precursor Chemicals)DEA List II Chemicals(Essential Chemicals)State regulationsMassachusettsNew YorkNew JerseyPennsylvaniaCanada inventoryInternational regulations: Not listed: Not listed: Not listed: Not listed: Not listed: None of the components are listed.: None of the components are listed.: None of the components are listed.: None of the components are listed.: All components are listed or exempted.KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services Réglementaires KMK Inc.www.kmkregservices.com5/6

AviBlue ®15. Regulatory informationInternational listsChemical WeaponsConvention List Schedule IChemicalsChemical WeaponsConvention List ScheduleII ChemicalsChemical WeaponsConvention List ScheduleIII Chemicals16. Other informationLabel requirementsHazardous MaterialInformation System (U.S.A.): Australia inventory (AICS): Not determined.China inventory (IECSC): All components are listed or exempted.Japan inventory: Not determined.Korea inventory: Not determined.New Zealand Inventory of Chemicals (NZIoC): Not determined.Philippines inventory (PICCS): Not determined.: Not listed: Not listed: Not listed: CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. CONTAINSMATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMALDATA. SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSECANCER.: Health : 2 * Flammability : 0 Physical hazards : 0Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards orrisks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings areto be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®materials may be purchased exclusively from J. J. Keller (800) 327-6868.The customer is responsible for determining the PPE code for this material.National Fire ProtectionAssociation (U.S.A.): Health : 2 Flammability : 0 Instability : 0Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, NationalFire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire ProtectionAssociation, on the referenced subject which is represented only by the standard in its entirety.Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only byproperly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number ofchemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals areclassified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.HistoryDate of issue: 15/11/2010Da te of previous issue : 10/01/2010Vers ion : 3Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of itssubsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services Réglementaires KMK Inc.www.kmkregservices.com6/6