Safety Data Sheet according to (EC) No 1907/2006 - ISO ... - AMI-CON

Safety Data Sheet according to (EC) No 1907/2006 - ISO 11014-1Page 1 of 8DURCISSEURsds no. : 369073V002.0Revision: 27.04.2010printing date: 16.03.2011Trade name:DURCISSEURIntended use:Crosslinker1. Identification of the substance/preparation and of the company/undertakingCompany name:Henkel LimitedTechnologies HouseWood Lane EndHP2 4RQ Hemel HempsteadGreat BritainPhone: +44 (0)1442 278000Fax-no.: +44 (0)1442 278071E-mail address of person responsible for Safety Data Sheet:ua-productsafety.uk@uk.henkel.comEmergency information:24 Hours Emergency Tel: +44 (0)1442 2784972. Hazards identificationR10 Flammable.R20 Harmful by inhalation.R43 May cause sensitisation by skin contact.R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.The product is classified as hazardous within the meaning of the valid (EU) preparation directive.Persons suffering from allergic reactions to isocyanates should avoid contact with the product.Base substances of preparation:organic solventpolymers3. Composition / information on ingredientsDeclaration of ingredients according to (EC) No 1907/2006:

MSDS-No.: 369073V002.0DURCISSEUR Page 2 of 8Hazardous componentsCAS-No.Hexane, 1,6-diisocyanato-,homopolymer28182-81-22-methoxy-1-methylethyl acetate108-65-6Xylene - mixture of isomeres1330-20-7Ethylbenzene100-41-4Hexamethylene diisocyanate822-06-0EINECSELINCScontentClassification> 50 % Xi - Irritant; R43R52/53203-603-9 10 - 25 % R10215-535-7 10 - 25 % Xn - Harmful; R20/21Xi - Irritant; R38R10202-849-4 1 - 5 % F - Highly flammable; R11Xn - Harmful; R20212-485-8 < 0,5 % T - Toxic; R23Xi - Irritant; R36/37/38R42/43For full text of the R-Phrases indicated by codes see section 16 'Other Information'.Substances without classification may have community workplace exposure limits available.4. First aid measuresInhalation:Move to fresh air. If symptoms persist, seek medical advice.Skin contact:Rinse with running water and soap.Seek medical attention from a specialist.Eye contact:Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist.Ingestion:Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.Combustion behaviour:In case of fire toxic gases can be released.Suitable extinguishing media:Carbon dioxide, foam, powderfine water spray5. Fire fighting measuresExtinguishing media which must not be used for safety reasons:High pressure waterjetSpecial protection equipment for firefighters:Wear protective equipment.Wear self-contained breathing apparatus.Additional information:Cool endangered containers with water spray jet.General information:Danger of slipping on spilled product.Personal precautions:Avoid skin and eye contact.See advice in chapter 8Environmental precautions:Do not empty into drains / surface water / ground water.6. Accidental release measures

MSDS-No.: 369073V002.0DURCISSEUR Page 3 of 8Clean-up methods:Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).Dispose of contaminated material as waste according to item 13.Handling:Ensure that workrooms are adequately ventilated.Avoid open flames and sources of ignition.Storage:Ensure good ventilation/extraction.Temperatures between + 5 °C and + 30 °C7. Handling and storage

MSDS-No.: 369073V002.0DURCISSEUR Page 4 of 88. Exposure controls / personal protectionComponents with specific control parameters for workplace:Valid forGreat BritainBasisUK EH40 WELsIngredient ppm mg/m3 Type Category Remarks2-METHOXY-1-METHYLETHYLACETATE108-65-650 275 Time Weighted Average(TWA).ECTLV2-METHOXY-1-METHYLETHYLACETATE108-65-62-METHOXY-1-METHYLETHYLACETATE108-65-61-METHOXYPROPYL ACETATE108-65-61-METHOXYPROPYL ACETATE108-65-61-METHOXYPROPYL ACETATE108-65-6XYLENE, MIXED ISOMERS, PURE1330-20-7XYLENE, MIXED ISOMERS, PURE1330-20-7XYLENE, MIXED ISOMERS, PURE1330-20-7XYLENE, O-, M-, P- OR MIXEDISOMERS1330-20-7XYLENE, O-, M-, P- OR MIXEDISOMERS1330-20-7XYLENE, O-, M-, P- OR MIXEDISOMERS1330-20-7ETHYLBENZENE100-41-4ETHYLBENZENE100-41-4ETHYLBENZENE100-41-4ETHYLBENZENE100-41-4ETHYLBENZENE100-41-4ETHYLBENZENE100-41-4ISOCYANATES, ALL (AS -NCO)822-06-0ISOCYANATES, ALL (AS -NCO)822-06-0ISOCYANATES, ALL (AS -NCO)28182-81-2ISOCYANATES, ALL (AS -NCO)28182-81-2Engineering controls:Ensure good ventilation/extraction.Respiratory protection:if there is atomisation100 550 Short Term ExposureLimit (STEL):Skin designation:100 548 Short Term ExposureLimit (STEL):Skin designation:50 274 Time Weighted Average(TWA).50 221 Time Weighted Average(TWA).100 442 Short Term ExposureLimit (STEL):Skin designation:50 220 Time Weighted Average(TWA).100 441 Short Term ExposureLimit (STEL):Skin designation:125 552 Short Term ExposureLimit (STEL):Skin designation:100 441 Time Weighted Average(TWA).100 442 Time Weighted Average(TWA).200 884 Short Term ExposureLimit (STEL):Skin designation:0,02 Time Weighted Average(TWA).0,07 Short Term ExposureLimit (STEL):0,07 Short Term ExposureLimit (STEL):0,02 Time Weighted Average(TWA).Can be absorbed through theskin.Can be absorbed through theskin.Can be absorbed through theskin.Can be absorbed through theskin.Can be absorbed through theskin.Can be absorbed through theskin.ECTLVECTLVEH40 WELEH40 WELEH40 WELECTLVECTLVECTLVEH40 WELEH40 WELEH40 WELEH40 WELEH40 WELEH40 WELECTLVECTLVECTLVEH40 WELEH40 WELEH40 WELEH40 WEL

MSDS-No.: 369073V002.0DURCISSEUR Page 5 of 8Hand protection:Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at leastprotection index 2, corresponding to > 30 minutes permeation time as per EN 374): Fluorinated rubber (FKM; >= 0.7 mmthickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutespermeation time as per EN 374): Fluorinated rubber (FKM; >= 0.7 mm thickness) This information is based on literaturereferences and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please notethat in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation timedetermined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tearare noticed then the gloves should be replaced.Eye protection:Tightly fitting safety gogglesSkin protection:Wear suitable protective clothing.9. Physical and chemical propertiesGeneral characteristics:AppearanceOdor:liquidLiquidyellowSolventPhys./chem. properties:Boiling pointFlash pointDensity(20 °C (68 °F))Viscosity (dynamic)(Brookfield; Instrument: RVT; 23 °C (73.4 °F);speed of rotation: 20 min-1)Solubility (qualitative)(Solvent: Water)Explosion limitlower [vol%]upper [vol%]VOC content(1999/13/EC)145 °C (293 °F)38 °C (100.4 °F)1,07 g/cm3150 - 300 mPa.sInsoluble1 %(V)10,8 %(V)25 %Conditions to avoid:No decomposition if used according to specifications.Materials to avoid:Reacts with alcohols and amines.Reacts slowly with water to liberate carbon dioxide gas.Hazardous decomposition products:None if used for intended purpose.10. Stability and reactivity11. Toxicological informationGeneral toxicological information:Persons suffering from allergic reactions to isocyanates should avoid contact with the product.Inhalative toxicity:Harmful by inhalation.May cause headache and dizziness.

MSDS-No.: 369073V002.0DURCISSEUR Page 6 of 8Sensitizing:May cause sensitization by skin contact.12. Ecological informationGeneral ecological information:Do not empty into drains / surface water / ground water.May cause long-term adverse effects in the aquatic environment.Harmful to aquatic organisms.Other remarks:The product contains organic solvents which are insoluble in water. According to the requirements of the ATV regulationsfor the dis charge of wastewater from commercial and industrial plant, organic solvents which are immiscible with water canonly be dis charged to an extent which corresponds to their solubility in water. The local discharge regulations takeprecedence.13. Disposal considerationsProduct disposal:In consultation with the responsible local authority, must be subjected to special treatment.Waste code( ):080111Road transport ADR:14. Transport informationClass: 3Packaging group:IIIClassification code:F1Hazard ident. number: 30UN no.: 1866Label: 3Technical name:RESIN SOLUTIONTunnelcode:(D/E)Additional information:Special provision 640ERailroad transport RID:Class: 3Packaging group:IIIClassification code:F1Hazard ident. number: 30UN no.: 1866Label: 3Technical name:RESIN SOLUTIONTunnelcode:Additional information:Special provision 640EInland water transport ADN:Class: 3Packaging group:IIIClassification code:F1Hazard ident. number:UN no.: 1866Label: 3Technical name:RESIN SOLUTIONAdditional information:Special provision 640EMarine transport IMDG:Class: 3

MSDS-No.: 369073V002.0DURCISSEUR Page 7 of 8Packaging group:IIIUN no.: 1866Label: 3EmS:F-E ,S-ESeawater pollutant: -Proper shipping name:RESIN SOLUTIONAir transport IATA:Class: 3Packaging group:IIIPackaging instructions (passenger) 309Packaging instructions (cargo) 310UN no.: 1866Label: 3Proper shipping name:Resin solutionIndication of danger:Xn - Harmful15. Regulations - classification and identificationRisk phrases:R10 Flammable.R20 Harmful by inhalation.R43 May cause sensitisation by skin contact.R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Safety phrases:S24 Avoid contact with skin.S37 Wear suitable gloves.Additional labeling:Contains isocyanates. See information supplied by the manufacturer.National regulations/information (Great Britain):RemarksControl of Substances Hazardous to Health Regulations (COSHH), and relatedguidance, e.g COSHH Essentials.EH40 Occupational Exposure LimitsChemicals (Hazard Information & Packaging for Supply) Regulations.The Personnel Protective Equipment at Work Regulations.The Carriage of Dangerous Goods by Road Regulations.The Health & Safety at Work Act 1974.(Note: Use latest editions/amendments of above referenced documents.)

MSDS-No.: 369073V002.0DURCISSEUR Page 8 of 816. Other informationThe labelling of the product is indicated in Section 15. The full text of the R-phrases indicted by codes in this safety data sheetare as follows:R10 Flammable.R11 Highly flammable.R20 Harmful by inhalation.R20/21 Harmful by inhalation and in contact with skin.R23 Toxic by inhalation.R36/37/38 Irritating to eyes, respiratory system and skin.R38 Irritating to skin.R42/43 May cause sensitization by inhalation and skin contact.R43 May cause sensitisation by skin contact.R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Further information:This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It isintended to describe our products from the point of view of safety requirements and is not intended to guarantee anyparticular properties.