SAFETY DATA SHEET according to Regulation (EC) No ... - AMI-CON

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27Specific target organtoxicity - single exposureCategory 3H336Classification according to EU Directives 67/548/EEC or 1999/45/ECEU. Directive 67/548/EEC or 1999/45/ECHazard symbolsHighly flammable (F)Irritant (Xi)Risk phrasesR11R36R66R672.2. Label elementsLabelling according to Regulation (EC) No 1272/2008Hazard symbols :Signal word : DangerHazard statements : H225 Highly flammable liquid and vapour.H319Causes serious eye irritation.H336May cause drowsiness or dizziness.Precautionary statementsPrevention : P210 Keep away from heat/sparks/openflames/hot surfaces. - No smoking.P280Wear protective gloves/ protective clothing/eye protection/ face protection.Response : P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Takeoff immediately all contaminated clothing.Rinse skin with water/ shower.P305 + P351 + P338 IF IN EYES: Rinse cautiously withwater for several minutes. Remove contactR4422 2/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27P337 + P313lenses, if present and easy to do. Continuerinsing.If eye irritation persists: Get medical advice/attention.Storage : P403 + P235 Store in a well-ventilated place. Keep cool.Additional Labelling:EUH066 Repeated exposure may cause skin dryness or cracking.EUH210 Safety data sheet available on request.Hazardous components which must be listed on the label:• acetone2.3. Other hazards3. Composition/information on ingredients3.1. SubstancesChemical Name Identification Number: Amount [%]acetoneIndex-No. : 606-001-00-8CAS-No. : 67-64-1EC-No. : 200-662-2>= 99.64. First aid measures4.1 Description of first aid measuresGeneral adviceIf inhaled: Remove from exposure, lie down. Take off all contaminatedclothing immediately.: Remove to fresh air. If breathing is irregular or stopped,administer artificial respiration. If unconscious place inrecovery position and seek medical advice.R4422 3/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27In case of skin contactIn case of eye contactIf swallowed: Wash off immediately with soap and plenty of water.: Rinse immediately with plenty of water, also under the eyelids,for at least 5 minutes. Consult an eye specialist immediately.Go to an ophthalmic hospital if possible.: Clean mouth with water and drink afterwards plenty of water.Never give anything by mouth to an unconscious person. Ifswallowed, do not induce vomiting - seek medical advice. If aperson vomits when lying on his back, place him in therecovery position.4.2 Most important symptoms and effects, both acute and delayed4.3 Indication of immediate medical attention and special treatment needed5. Fire-fighting measures5.1. Extinguishing mediaSuitable extinguishingmedia: Use water spray, alcohol-resistant foam, dry chemical orcarbon dioxide.Unsuitable extinguishing : High volume water jetmedia5.2. Special hazards arising from the substance or mixtureSpecific hazards during firefighting: Vapours are heavier than air and may spread along floors.Vapours may form explosive mixtures with air.Flash back possible over considerable distance.In case of fire hazardous decomposition products may beproduced such as:Carbon monoxideCarbon dioxide (CO2)5.3. Advice for firefightersSpecial protectiveequipment for fire-fightersFurther information: In the event of fire, wear self-contained breathing apparatus.Wear appropriate body protection (full protective suit): Cool closed containers exposed to fire with water spray.Heating will cause a pressure rise - with risk of bursting.Collect contaminated fire extinguishing water separately. ThisR4422 4/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27must not be discharged into drains.6. Accidental release measures6.1 Personal precautions, protective equipment and emergency proceduresPersonal precautions: Use personal protective equipment. Keep away unprotectedpersons. Provide adequate ventilation. Keep away from heatand sources of ignition. Avoid contact with skin and eyes. Donot breathe vapours or spray mist. For personal protection seesection 8.6.2 Environmental precautionsEnvironmental precautions: Do not flush into surface water or sanitary sewer system.Avoid subsoil penetration. If the product contaminates riversand lakes or drains inform respective authorities.6.3 Methods and materials for containment and cleaning upMethods and materials forcontainment and cleaningupFurther information: Contain spillage, and then collect with non-combustibleabsorbent material, (e.g. sand, earth, diatomaceous earth,vermiculite) and place in container for disposal according tolocal / national regulations (see section 13).: Treat recovered material as described in the section "Disposalconsiderations".6.4 Reference to other sections7. Handling and storage7.1 Precautions for safe handlingR4422 5/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27Advice on safe handlingHygiene measures: Keep container tightly closed. Ensure adequate ventilation. Usepersonal protective equipment. Avoid contact with the skin andthe eyes. Do not breathe vapours or spray mist. Emergencyeye wash fountains and emergency showers should beavailable in the immediate vicinity.: Keep away from food, drink and animal feedingstuffs. Smoking,eating and drinking should be prohibited in the application area.Wash hands before breaks and at the end of workday. Take offall contaminated clothing immediately. Avoid contact with theskin and the eyes. Do not breathe vapours or spray mist.7.2 Conditions for safe storage, including any incompatibilitiesRequirements for storageareas and containersAdvice on protectionagainst fire and explosion: Keep in an area equipped with solvent resistant flooring.Suitable materials for containers: Mild steel Stainless steel: Combustible liquid Keep away from sources of ignition - Nosmoking. Use only explosion-proof equipment. Vapours areheavier than air and may spread along floors. Vapours mayform explosive mixtures with air. Take measures to prevent thebuild up of electrostatic charge. Use only in an area containingexplosion proof equipment.Further information onstorage conditions: Keep tightly closed in a dry and cool place. Keep away fromdirect sunlight. Keep away from heat. Keep in a well-ventilatedplace.Advice on common storage : Keep away from food, drink and animal feedingstuffs.Incompatible with oxidizing agents.German storage class: 3 Flammable Liquids7.3 Specific end uses8. Exposure controls/personal protection8.1. Control parametersR4422 6/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27acetoneOther OELsCAS-No.67-64-1Regulatory Basis : EU. Indicative Exposure and Directives relating to the protection ofrisks related to work exposure to chemical, physical, and biologicalagents.Regulatory List : EU ELVValue type : Time Weighted Average (TWA):Value : 500 ppmValue : 1,210 mg/m3Remarks : IndicativeRegulatory Basis : UK. EH40 Workplace Exposure Limits (WELs)Regulatory List : EH40 WELValue type : Time Weighted Average (TWA):Value : 500 ppmValue : 1,210 mg/m3Regulatory Basis : UK. EH40 Workplace Exposure Limits (WELs)Regulatory List : EH40 WELValue type : Short Term Exposure Limit (STEL):Value : 1,500 ppmValue : 3,620 mg/m38.2. Exposure controlsEngineering measuresRefer to protective measures listed in sections 7 and 8.Personal protective equipmentRespiratory protectionAdvice : Required, if exposure limit is exceeded (e.g. OEL).In case of insufficient ventilation, wear suitable respiratoryequipment.Breathing apparatus with filter.Recommended Filter type:AXHand protectionR4422 7/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27Advice : The glove material has to be impermeable and resistant to theproduct / the substance / the preparation.Take note of the information given by the producer concerningpermeability and break through times, and of special workplaceconditions (mechanical strain, duration of contact).Protective gloves should be replaced at first signs of wear.Material : butyl-rubberGloves : >= 4 hGlove thickness : 0.5 mmEye protectionAdvice : Tightly fitting safety gogglesSkin and bodyprotectionAdvice : Solvent resistant protective clothingEnvironmental exposure controlsGeneral advice : Do not flush into surface water or sanitary sewer system.Avoid subsoil penetration.If the product contaminates rivers and lakes or drains informrespective authorities.9. Physical and chemical properties9.1. Information on basic physical and chemical propertiesForm: liquidColourOdour: colourless: sweetOdour Threshold :pH :Freezing point : -94.7 °CBoiling point : 55.8 - 56.6 °CFlash point : -18 °Cclosed cupR4422 8/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27Upper explosion limit : 13.0 %(V)Lower explosion limit : 2.1 %(V)Vapour pressure : 247 hPa20 °CRelative vapour density : 2.0812 hPa50 °CDensity : 0.791 g/cm320 °CWater solubility : completely misciblePartition coefficient: n-octanol/water : -0.24(measured)Ignition temperature : 540 °CViscosity, dynamic : 0.33 mPa.s20 °COxidizing properties :9.2 Other information10. Stability and reactivity10.1. Reactivity10.2. Chemical stability10.3. Possibility of hazardous reactions10.4. Conditions to avoidConditions to avoid : Keep away from heat and sources of ignition.10.5. Incompatible materialsMaterials to avoid: strong reducing agentsOxidizing agentsHalogenated compoundsAlkali metalsEthanolamineR4422 9/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27Hydrogen peroxide10.6. Hazardous decomposition productsHazardous decompositionproducts: Under fire conditions:Carbon oxides11. Toxicological information11.1. Information on toxicological effectsAcute toxicityOralacetoneCAS-No.67-64-1Value type : LD50Value : 5,800 mg/kgSpecies : ratInhalationacetoneCAS-No.67-64-1Remarks : Irritating to respiratory system.acetoneCAS-No.67-64-1Value type : LC50Value : ca. 76 mg/lExposure time : 4 hSpecies : ratDermalR4422 10/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27acetoneCAS-No.67-64-1Value type : LD50Value : 20,000 mg/kgSpecies : rabbitIrritationEyesacetoneCAS-No.67-64-1Species : rabbitResult : Irritating to eyes.Remarks : May cause corneal damage.SkinacetoneCAS-No.67-64-1Remarks : Repeated exposure may cause skin dryness or cracking.SensitisationacetoneCAS-No.67-64-1Species : guinea pigResult : not sensitizingExperiences withhuman exposureFurther information: Symptoms of overexposure may be headache, dizziness,tiredness, nausea and vomiting.Chronic exposure may cause dermatitis.Chronic inhalation causes tiredness, headache and rhinitis.12. Ecological informationR4422 11/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/2712.1. ToxicityAcute toxicityFishacetoneCAS-No.67-64-1Species : Oncorhynchus mykissExposure Time : 96 hValue type : LC50Value : 5,540 mg/lSpecies : Lepomis macrochirusExposure Time : 96 hValue type : LC50Value : 8,300 mg/lToxicity to daphnia and other aquatic invertebrates.acetoneCAS-No.67-64-1Species : Daphnia magnaExposure time : 48 hValue type : LC50Value : 12,600 mg/lalgaeacetoneCAS-No.67-64-1Species : Pseudokirchneriella subcapitataExposure time : 48 hValue type : NOECValue : 4,740 mg/lBacteriaR4422 12/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27acetoneCAS-No.67-64-1Species : Pseudomonas putidaExposure time : 16 hValue type : NOECValue : 1,700 mg/l12.2. Persistence and degradabilityPersistence and degradabilityBiodegradabilityacetoneCAS-No.67-64-1Biodegradation : 84 %Exposure time : 20 dRemarks : Readily biodegradable12.3. Bioaccumulative potentialBioaccumulationacetoneCAS-No.67-64-1Bioconcentration factor : < 10(BCF)Remarks : Does not bioaccumulate.12.4. Mobility in soil12.5. Results of PBT and vPvB assessment12.6. Other adverse effectsBiochemical Oxygen Demand (BOD)R4422 13/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27acetoneCAS-No.67-64-1Value : 1,900 mg/gIncubation time : 5 dChemical oxygen demandacetoneCAS-No.67-64-1Value : 2,100 mg/gAdditional ecological informationacetoneCAS-No.67-64-1Remarks : Do not flush into surface water or sanitary sewer system.Avoid subsoil penetration.13. Disposal considerations13.1. Waste treatment methodsProductContaminated packagingEuropean Waste CatalogueNumber: Disposal together with normal waste is not allowed. Specialdisposal required according to local regulations.Do not let product enter drains.Contact waste disposal services.: Empty contaminated packagings thoroughly. They can berecycled after thorough and proper cleaning.Do not burn, or use a cutting torch on, the empty drum.Risk of explosion.: No waste code according to the European Waste Cataloguecan be assigned for this product, as the intended use dictatesthe assignment. The waste code is established in consultationwith the regional waste disposer.R4422 14/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/2714. Transport information14.1. UN number109014.2. UN proper shipping nameADRRIDIMDG: ACETONE: ACETONE: ACETONE14.3. Transport hazard class(es)ADR-Class(Labels; Classification Code; Hazardidentification No; Tunnel restriction code)RID-Class(Labels; Classification Code; Hazardidentification No)IMDG-Class(Labels; EmS):::33; F1; 33; (D/E)33; F1; 3333; F-E, S-D14.4. Packaging groupADRRIDIMDG: II: II: II14.5. Environmental hazardsLabeling according to 5.2.1.8 ADRLabeling according to 5.2.1.8 RIDLabeling according to 5.2.1.6.3 IMDGClassification as environmentally hazardousaccording to 2.9.3 IMDGClassified as “P” according to 2.10 IMDG: no: no: no: no: noR4422 15/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/2714.6. Special precautions for user14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeIMDG: not applicable15. Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureNotification status15.2. Chemical Safety Assessment16. Other informationFull text of R-phrases referred to under sections 2 and 3.R11R36R66R67Highly flammable.Irritating to eyes.Repeated exposure may cause skin dryness or cracking.Vapours may cause drowsiness and dizziness.Full text of H-Statements referred to under sections 2 and 3.H225H319H336Highly flammable liquid and vapour.Causes serious eye irritation.May cause drowsiness or dizziness.Further informationR4422 16/17 EN

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006ACETONEVersion 4.0 Print Date 2010/10/27Revision Date 2010/10/27Other information : The information provided in this Safety Data Sheet is correct toour knowledge at the date of its revision. The information givenonly describes the products with regard to safety arrangementsand is not to be considered as a warranty or qualityspecification and does not constitute a legal relationship.The information contained in this Safety Data Sheet relatesonly to the specific material designated and may not be validfor such material used in combination with any other materialor in any process, unless specified in the text|| Indicates updated section.The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and is notto be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.R4422 17/17 EN