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Safety Data SheetCS: 1.7.2Page: 1of4Infosafe No 3NU1U Issue Date : July 2014 ISSUED by CRPCAREProduct Name Simagranz Herbicide1. IdentificationGHS ProductIdentifierProduct CodeProduct TypeCompany NameAddressTelephone/FaxNumberEmergency phonenumberRecommended use ofthe chemical andrestrictions on useOther Information2. Hazard IdentificationGHS classification ofthesubstance/mixtureSignal Word (s)Hazard Statement (s)GeneralPrecautionaryStatement (s)Pictogram (s)Simagranz HerbicideClassified as hazardous0750Group C HerbicideCrop Care Australasia Pty Ltd (ABN 53 061 362 347)Unit 17/16 Metroplex Avenue MurarrieQueensland 4172 AustraliaTel: +61 7 3909 2000Fax: +61 7 3909 20101800 033 498 (24hr Australia)For the control of weeds in a range of horticultual and broadacre crops,forestry and in non-crop situations as per the Directions for Use table on thelabel.This Safety Data Sheet describes, to the best of our knowledge, the propertiesof the concentrated product. The physical properties and some of theassessments do not apply to the properties of the product once it has beendiluted for application. Acute health effects of the diluted product arelikely to be much less severe.CA2 Carcinogenicity: Category 2ED1 Eye Damage/Irritation: Category 1SC-2 Skin Corrosion/Irritation: Category 2DANGERH351 Suspected of causing cancer.H318 Causes serious eye damage.H315 Causes skin irritation.P101 If medical advice is needed, have product container or label at hand.P102 Keep out of reach of children.P103 Read label before use.Corrosion, Health hazardPrecautionarystatement –PreventionPrecautionarystatement –ResponseOther InformationP202 Do not handle until all safety precautions have been read and understood.P280 Wear protective gloves, clothing, eye and face protection.P264 Wash hands and exposed skin thoroughly after handling.P308+P313 IF exposed or concerned: Get medical advice/attention.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing.P310 Immediately call a POISON CENTER or doctor/physician.P302+P352 IF ON SKIN: Wash with plenty of soap and water.P332+P313 If skin irritation occurs: Get medical advice/attention.P362 Take off contaminated clothing and wash before reuse.Poisons Schedule - Not Scheduled3. Composition/information on ingredientsChemicalSolidCharacterizationIngredientsName CAS ProportionSimazine 122-34-9 900 g/kgTalc 14807-96-6

Safety Data SheetCS: 1.7.2Page: 3of4Infosafe No 3NU1U Issue Date : July 2014 ISSUED by CRPCAREProduct Name Simagranz HerbicideHygiene MeasuresRequirementsConcerning SpecialTrainingClassified as hazardousRe-entry period: Do not enter treated area until spray has dried.After use and before eating, drinking or smoking, wash hands, arms and facethoroughly with soap and water.After each day's use, wash contaminated clothing and safety equipment.Check State or Territory regulations that require people who use pesticides intheir job or business to have training in the application of the materials.9. Physical and chemical propertiesFormSolidAppearance Light tan granular powderOdourOdourlessMelting Point 225 - 227°C for simazine technicalSolubility in Water Solubility of simazine technical is 0.062 g/L @ 25°CVapour Pressure 0.00081 mPa for simazine technicalPartition Coefficient: LogP 2.3 (25°C) for simazine technicaln-octanol/waterFlammabilityCombustibleDanger of dust explosion.10. Stability and reactivitySubject to hydrolysis and sublimation at high temperatures.Chemical StabilityPossibility ofhazardous reactionsHazardousPolymerizationThis product contains a high proportion of an organic solid. Largeaccumulations of dust and fines associated with industrial processing of bulkmaterial may be a dust explosion hazard.Hazardous polymerisation is not possible.11. Toxicological InformationAcute Toxicity - Oral LD50 (rat) >5,000 mg/kg for simazineAcute Toxicity - LC50 (rat) (4hr) >5.5 mg/l for simazineInhalationIngestionThe concentrate is of low toxicity if swallowed.InhalationInhalation of dust may result in respiratory irritation.SkinNot a likely route of exposure due to the physical nature of the product.EyeMay irritate the eyes.CarcinogenicitySerious eyedamage/irritationSkincorrosion/irritationOther InformationSuspected human carcinogen based on limited evidence from studies on humans orlaboratory animals.This product is a severe eye irritant.The product is a skin irritant.The Australian Acceptable Daily Intake (ADI) for simazine for a human is 0.005mg/kg/day, set for the public for daily, lifetime exposure. This is based onthe NOEL of 0.5 mg/kg/day, the level determined to show no effects during longterm exposure for the most sensitive indicators and the most sensitivespecies. (Ref: Comm. Dept. of Health and Ageing, Office of Chemical Safety,'ADI List', March 2014).12. Ecological informationPersistence and Half life in soil is typically 60 days.degradability (Range 27 - 102 days)Environmental Spray drift should be avoided, read the label for more information.ProtectionAcute Toxicity - Fish The following is data for the active ingredient, simazine.Not toxic to fish. LC50 (96 hr) for bluegill sunfish is 90 mg/l.Print Date: 10/07/2014 CS: 1.7.2

Safety Data SheetCS: 1.7.2Page: 4of4Infosafe No 3NU1U Issue Date : July 2014 ISSUED by CRPCAREProduct Name Simagranz HerbicideAcute Toxicity -DaphniaAcute Toxicity -AlgaeAcute Toxicity -Other OrganismsClassified as hazardousLC50 (48hr) for daphnia is 1.1 mg/l for simazine.EC50 (72hr) for Scenedesmus subspicatus is 0.04 mg/l.The following data is for the active ingredient, simazine.Birds: Not toxic to birds. LD50 for mallard duck is >2,000 mg/kgBees: Not toxic to bees. LD50 97 µg/bee.13. Disposal considerationsProduct Disposal On site disposal of the concentrated product is not acceptable.Ideally, the product should be used for its intended purpose. If there is aneed to dispose of the product, approach local authorities who hold periodiccollections of unwanted chemicals (ChemClear®).Container Disposal Thoroughly wash out the inner and add washings to the spray tank. Dispose ofwashed inner and cardboard box in landfill.If no landfill is available, bury the containers below 500mm in a disposalpit specifically marked and set up for this purpose clear of waterways,desirable vegetation and tree roots.Empty containers and product should not be burnt.14. Transport informationStorage andTransportUN Number (SeaTransport)IMO Class/PackingGroupIMO MarinePollutantIMO ProperShipping NameConsidered non dangerous for road and rail transport (in packaging, includingIBCs not greater than 3000 Lt each) by the Australian Code for the Transportof Dangerous Goods by Road and Rail. Ref: ADG7; SP No. AU01.For bulk shipments as Class 9, use UN 3077, HazChem code 2Z.3077Class 9Marine Pollutant15. Regulatory informationNot ScheduledPoisons SchedulePackaging &LabellingAICS (Australia)16. Other InformationDate of preparationor last revision ofSDSContactPerson/PointRevisionsHighlightedENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(contains Simazine)Not to be used for any purpose or in any manner contrary to the label unlessauthorised under appropriate legislation.READ SAFETY DIRECTIONS BEFORE OPENING OR USINGAll of the components in this product are listed on the Australian Inventoryof Chemical Substances.Revised 10/07/2014.This SDS replaces document dated June 2009.Normal Hours: Mrs Kathleen Marsh Phone: +61 3 9282 1000After Hours: Shift Supervisor Phone: 1800 033 498The SDS was reviewed to include GHS requirements.Various changes were made throughout....End Of MSDS...© Copyright ACOHS Pty LtdCopyright in the source code of the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectualproperty of Acohs Pty Ltd.Copyright in the layout, presentation and appearance of each Infosafe MSDS displayed is the intellectual property of Acohs Pty Ltd.The compilation of MSDS's displayed is the intellectual property of Acohs Pty Ltd.Copying of any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose ofsale or licence or for inclusion as part of a collection of MSDS without the express written consent of Acohs Pty Ltd.Print Date: 10/07/2014 CS: 1.7.2