TH-80u - Hitachi America, Ltd.

M A T E R I A L S A F E T Y D A T A S H E E TT H - 8 0 u M a k e - U p I n kT H I S M A T E R I A L S A F E T Y D A T A S H E E T C O N F O R M S T O T H E R E Q U I R E M E N T S O F A N S I Z 4 0 0 . 1 .H I S M S D S C O M P L I E S W I T H 2 9 C F R 1 9 1 0 . 1 2 0 0 ( O S H A H A Z A R D C O M M U N I C A T I O N S T A N D A R D ) .I M P O R T A N T : R E A D T H I S M S D S B E F O R E H A N D L I N G O R D I S P O S I N G O F T H I S P R O D U C T .T H I SSECTION I – PRODUCT & COMPANY IDENTIFICATIONMANUFACTURER / DISTRIBUTORPRODUCT NAMEMATERIAL USESHitachi America, Ltd50 Prospect AvenueTarrytown, NY 10591TH-80u Make-Up InkPRODUCT CODE X (22, 45, 53) 1275NON-EMERGENCY PHONE 914-524-6685Industrial coding applications; Ink Jet PrintersEMERGENCY PHONE CHEMTREC (800) 424-9300SECTION II – COMPOSITION / INFORMATION ON INGREDIENTSINGREDIENTCAS#PERCENT RANGE(%)Methyl Ethyl Ketone 78-93-3 60 - 100SECTION III - HAZARDS IDENTIFICATIONHAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS)EMERGENCYOVERVIEWEXPOSURE EFFECTS AND RELATED SYMPTOMSMETHYL ETHYL KETONEF - Highly FlammableHEALTH 1 FLAMMABILITY 3 REACTIVITY 0PERSONALPROTECTIONNOTICE: THESE RATINGS ARE FOR GENERAL RAPID INTERPRETATION. THE END-USER IS RESPONSIBLE FOR DETERMINING THE PROPER PROTECTIVE PROCEDURES.Warning! Flammable Liquid and Vapor. Skin, Eye and Mucous Membrane Irritant. Do not use near fire or flame. May be fatal or cause blindness ifswallowed. Avoid contact with skin, eyes and mucous membranes. If skin contact occurs, wash skin with mild soap and water. If splashed in eyes, flush withwater. If inhaled, remove to fresh air. In medical emergency contact Poison Control Center (USA 800.222.1222). Read MSDS before using.Minor embryotoxic/fetotoxic effects have been observed in laboratory rats exposed to methyl ethyl ketone by inhalation at levels greater than 1000 ppm (5times the OSHA-PEL/TWA) for most of the gestation period. Methyl ethyl ketone may potentiate (shorten the time of onset) peripheral neuropathy, butmethyl ethyl ketone, by itself, has not been shown to cause peripheral neuropathy.Xi - IrritantSECTION IV - FIRST AID MEASURESRISK STATEMENTSR11 Highly FlammableR36/37/38 Irritating to eyes, respiratory system and skinR66 Repeated exposure may cause skin dryness or crackingR67 Inhalation of vapors can provoke sleepiness and dizzinessSAFETY STATEMENTSS2 Keep away from children.S7 Keep container tightly closedS16 Keep away from sources of ignition - No Smoking!S25 Avoid contact with eyesS36/37 Wear suitable protective clothing and glovesS45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)BORAL INGESTIONEYE CONTACTSKIN CONTACTINHALATIONDo not induce vomiting unless directed to do so by medical personnel. Seek immediate medical attention.Flush with water for 15 minutes and seek medical attention.Wash with soap and water. Wash contaminated clothing before reuse. Seek immediate medical attention.Remove to fresh air, if not breathing, give artificial respiration and seek medical attention.SECTION V - FIREFIGHTING MEASURESEXTINGUISHING MEDIAHAZARDOUS COMBUSTION PRODUCTSFIRE FIGHTING PROCEDURESAlcohol Resistant foam or dry chemicalCarbon Monoxide, Carbon DioxideWear self-contained breathing apparatus with full facepieceoperated in the positive pressure demand mode.Page 1 of 3

SECTION VI - ACCIDENTAL RELEASE MEASURESKeep away all sources of ignition from spill. If spill is indoors, ventilate areas of spill and soak up the spill with absorbent material. Do not let spilled or leakingmaterial enter watercourse.SECTION VII - HANDLING AND STORAGEHANDLINGSTORAGEAvoid contact with eyes. Wash hands thoroughly with soap and water after handling. Utilize proper grounding with containers of material.Protect from freezing. Overheating may cause container to rupture. Covered storage in a cool, dry place out of direct sunlight ispreferable. Keep container tightly sealed until ready for use. Store away from ignition sources.SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTIONRESPIRATORY PROTECTIONVENTILATIONPROTECTIVE GLOVESEYE PROTECTIONOTHER PROTECTIVE EQUIPMENTOCCUPATIONAL EXPOSURE LIMITS:If workplace exposure limit(s) of product or any other component is exceeded, a NIOSH/OSHA approved respirator is advised. (Seeyour safety equipment supplier for specific details.)Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below PEL/ TLV.Wear chemical resistant gloves. (Consult your safety equipment supplier.)Wear chemical splash goggles in compliance with OSHA regulations. However, OSHA regulations also permit other types of safetyglasses.Wear impervious clothing and boots to prevent prolonged exposure.INGREDIENT ACGIH TLV* OSHA PEL*Methyl Ethyl Ketone 200 200SECTION IX - PHYSICAL & CHEMICAL PROPERTIESSECTION X - STABILITY & REACIVITYPHYSICAL STATELiquidCOLORClearODORSolvent odorBOILING RANGE80° CMELTING RANGE- 86° CSPECIFIC GRAVITY (WATER=1) 0.806DENSITY (lbs / gal) 6.72EVAPORATION RATE (N-BUTYL ACETATE=1) ~ 6PERCENT VOLATILE BY VOLUME (%) 100%VAPOR PRESSURE85 mm of Hg @ 20° CVAPOR DENSITY (AIR=1)Greater than airFLASH POINT (TCC)- 4° CAUTO IGNITION TEMPERATURE515° CUPPER FLAMMABLE LIMIT (%BY VOL.) 11.5LOWER FLAMMABLE LIMIT (%BY VOL.) 1.8SOLUBILITY IN WATERMiscibleSOLUBILITY IN ORGANIC SOLVENTSMisciblePHNot ApplicableCONDITION OF INSTABILITYCONDITIONS OF REACTIVITYINCOMPATIBILITYHAZARDOUS DECOMPOSITION PRODUCTSEXPLOSION DATA (SENSITIVE TO MECHANICAL IMPACT)EXPLOSION DATA (SENSITIVE TO STATIC DISCHARGE)None KnownNot applicableStrong oxidizing agentsCarbon Monoxide, Carbon DioxideNoYesSECTION XI - TOXICOLOGICAL INFORMATIONINGREDIENTMethyl Ethyl KetoneTOXICOLOGICAL INFORMATION**LD 50 Oral (rat) - 2737 mg / kgLC 50 Inhalation (rat) - 23,500 mg / m 3 / 8 hrLD 50 Intraperitoneal (rat) - 607 mg / kgLD 50 Skin (rabbit) - 6480 mg / kgLD Lo Intraperitoneal (guinea pig) - 2 g / kgPage 2 of 3

SECTION XII - ECOLOGICAL INFORMATIONECOTOXICITYPERSISTANCE / DEGRADABILITYHEAVY METALSNot AvailableNot AvailableConcentration of lead, mercury, cadmium and hexavalent chromium [Cr(VI)] < 100 ppmNo other ecological information is available for this product.SECTION XIII - DISPOSAL CONSIDERATIONSAbsorb in vermiculite, floor absorbent or other non-combustible absorbent material and dispose in licensed facility. Observe all federal, state and localregulations.SECTION XIV - TRANSPORT INFORMATIONDOT / TDG UN NUMBER & PROPER SHIPPING NAMEUN1210 PRINTING INKDOT / TDG HAZARD CLASS 3DOT / TDG LABELPACKING GROUPSECTION XV - REGULATORY INFORMATIONTSCACERCLAFLAMMABLE LIQUIDEMERGENCY RESPONSE GUIDEBOOK NUMBER 129All chemicals used are listed on the TSCA Inventory.The following product(s) is (are) listed by CERCLA:Methyl Ethyl Ketone (60 - 100%)SARA 313 The following product(s) is (are) listed on SARA 313:California Prop 65InternationalRegulationsSECTION XVI - OTHER INFORMATIONISSUE DATE April 2007REVISION NUMBER 1SUPERCEDESPREPARED BYn/aChris Jordan,Product SpecialistMethyl Ethyl Ketone (60 - 100%)This product contains the following ingredients that the State of California has found to cause cancer, birth defects,or other reproductive harm, which requires a warning under the statute:Toluene (≤ 0.00002%)The components of this product are listed on the chemical inventories of the following countries:Australia, Canada, Europe (EINECS), Japan, Korea, United KingdomIIDISCLAIMEREvery effort has been made to ensure that the information in this MSDS is accurate and as complete as reasonably possible and of course alldata herein are given in good faith. However, all information is furnished without warranty of any kind, and Hitachi America, Ltd. expresslynegates any warranty of accuracy, expressed or implied; and Hitachi America, Ltd. assumes no responsibility for personal injury or damage toproperty to customers, vendors, or third parties if any information herein proves to be incorrect in any respect. Purchasers are encouraged tomake independent determination of suitability and completeness of information from all sources to assure proper use and compatibility ofproduct.*NIOSH Publication #94-116**Sax’s Dangerous Properties of Industrial Mtls. 11th Ed.Page 3 of 3