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MATERIAL SAFETY DATA SHEETDSCL (Pictograms) DSCL (Classification) Protective ClothingR22- Harmful if swallowed.R52- Harmful to aquatic organisms.Conforms to 93/112/EC and ISO 11014-1IMIDACLOPRID <strong>35%SC</strong>1. Identification of the substance/preparation and of the company/undertakingProduct name : IMIDACLOPRID <strong>35%SC</strong> Supplier : PLAASKEM (Pty) Ltd.14 Field Road,LILIANTONManufacturer : Sharda Worldwide Exports29 th Road, Mumbai, IndiaSynonyms: Insecticide.Emergency telephone number: 011-823-8000 (o/h); 0800 147 112 (a/h)2. Composition / information on ingredientsSubstance/Preparation: PreparationChemical name*<strong>Imidacloprid</strong>CAS No.138261-41-3%35SymbolXnR-PhrasesR22, R52* Occupational Exposure Limit(s), if available, are listed in section 83. Hazards identificationPhysical/chemical hazardsHuman health hazardsEnvironmental hazards:::Not applicable.Harmful in contact if swallowed.Harmful to aquatic organisms.4. First-aid measuresFirst-Aid measuresInhalationIngestionSkin Contact :Eye Contact :: If inhaled, remove to fresh air. If not breathing, give artificial respiration.oxygen. Get medical attention.If breathing is difficult, give: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything bymouth to an unconscious person. If large quantities of this material are swallowed, call aphysician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removingcontaminated clothing and shoes. Cover the irritated skin with an emollient. Wash clothingbefore reuse. Thoroughly clean shoes before reuse. Get medical attention.Check for and remove any contact lenses. In case of contact, immediately flush eyes with plentyof water for at least 15 minutes. WARM water MUST be used. Get medical attention immediately.Effects and symptomsInhalationIngestionSkin Contact:::Harmful in case of inhalation.Harmful in case of ingestion.Harmful in case of skin contactEye ContactAggravating conditions::Harmful in case of eye contact (irritant).Repeated or prolonged exposure is not known to aggravate medical condition.Date of issue : 2010/08/31. Version 1.00 Page: 1/4
IMIDACLOPRID <strong>35%SC</strong>5. Fire-fighting measuresExtinguishing MediaSuitableSpecial fire-fighting procedures::Not applicable.Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and fullturnout gear.6. Accidental release measuresPersonal precautionsEnvironmental Precautionsand Clean-up Methods::Safety glasses. Gloves.Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finishcleaning by spreading water on the contaminated surface and allow to evacuate through thesanitary system.7. Handling and storageHandling : Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact witheyes. Never add water to this product. If ingested, seek medical advice immediately and show thecontainer or the label.StoragePackaging materialsRecommended useEngineering measuresHygiene measures :Occupational Exposure Limits ::Keep container tightly closed. Keep container in a cool, well-ventilated area.: Use original container.8. Exposure controls/personal protectionIngredient Name<strong>Imidacloprid</strong>: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vaporsbelow their respective threshold limit value.Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,using lavatory, and at the end of day.Occupational Exposure LimitsNonePersonal protective equipmentRespiratory systemSkin and bodyHandsEyes::::N/aLab coat.Gloves.Splash goggles.9. Physical and chemical propertiesPhysical state:Color:Odor:Boiling Point:Melting Point:Density:Solubility:Octanol/water partition coefficient :Liquid.White.Slight.The lowest known value is 100°C (212°F) (Water).May start to solidify at 0°C (32°F) based on data for: Water.1.15 g/cm 3Miscible in waterThe product is insoluble in water and oil.pHFlash pointExplosive properties:::7-8.5Not applicable.Risks of explosion of the product in presence of mechanical impact: Not available.Slightly explosive in presence of open flames, sparks and static discharge.Date of issue : 2010/08/31. Version 1.00 Page: 2/4
IMIDACLOPRID <strong>35%SC</strong>10. Stability and reactivityStabilityMaterials to avoid::The product is stable.Slightly reactive to reactive with oxidizing agents.11. Toxicological informationLocal effectsSkin irritation: Slightly harmful in case of skin contact. Noncorrosivefor skin.Sensitization : Non-sensitizer for lungs.Acute toxicityChronic toxicity: Acute oral toxicity (LD50): 768 mg/kg [Rat],: Repeated or prolonged exposure is not known to aggravate medical condition.12. Ecological informationEcotoxicity :N/a13. Disposal considerationsMethods of disposal; Waste ofresidues; Contaminated packaging: Waste must be disposed of in accordance with federal, state and local environmental control regulations.14. Transport informationInternational transport regulationsUN numberLand - Road/RailwayProper shipping nameADR/RID ClassPacking GroupSeaProper shipping nameIMDG ClassPacking GroupAirProper shipping nameUN/ID NumberIATA-DGR ClassInland waterwaysProper shipping nameADNR ClassificationUN/NA (Europe) ADNRPacking Group: NOT REGULATED.::Not dangerous goods::: Not dangerous goods:::Not dangerous goods:::Not dangerous goods::15. Regulatory informationEU RegulationsHazard symbol(s) :Classification:Risk Phrases:Safety Phrases:Contains :HarmfulR22- Harmful if swallowed. R52 – Harmful to aquatic organisms.S2- Keep out of the reach of children.S36/37- Wear suitable protective clothing and gloves.S46- If swallowed, seek medical advice immediately and show this container or label.<strong>Imidacloprid</strong>Date of issue : 2010/08/31. Version 1.00 Page: 3/4
IMIDACLOPRID <strong>35%SC</strong>16. Other informationHISTORYDate of printingDate of issueDate of Previous IssueVersionPrepared by:::::2010/08/311.00Notice to ReaderTo the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiariesassumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be usedwith caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.2010/08/31.1.00Page: 4/4
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