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Nr.2 - ALPA - Albanian Papers

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Imeri et al.Which means that for the capacity of 102 t/hr ofthe rotary kiln, has been produced less1358.78 m 3 NCO 2 / hr.Or for 1t dry ore has been produced less CO 2 :1358.78 m 3 NCO 2 /78.06 t DO = 17.41 m 3 NCO 2 / tDO.3. TREATMENT OF NICKEL OXIDE ORES INELECTRIC FURNACECaCO 3 → CaO + CO 210110 kg CaCO 3 /hr x 40% = 4044 kg CaCO 3 /hr x44/100 = 1779.36 kg C0 2 /hr,or 1779.36 kgCO 2 /hr x 22,4/44 = 905.856m 3 NCO 2 /hr.Which means that for the capacity of 102 t/hr ofthe rotary kiln inside the electrical furnace hasbeen produced less 905. 856 m 3 N CO 2 / hr.For 1t dry ore has been produced less CO 2 :905.856 m 3 NCO 2 / 78.06 t DO = 11.605 m 3 NCO 2 / tDO.Chemical composition of electric furnace slagwith increasing of Fe total by 3.89 % is given intable 4, while with less Fe total by 3.89 % is given intable 5.Ni % SiO2 % Fe % FeO% CaO % MgO % Al 2 O 3 %0,09 60.96 12.09 15.60 2.75 18.43 2,23Table 4. Chemical composition of electric furnace slag with increasing quantity by 3.89 % F totalNi % SiO2 % Fe % FeO% CaO % MgO %0,09 64.19 8.2 10.58 2.89 19.4Table 5. Chemical composition of electric furnace slag with less of 3.89 %Fe total4. RESULTS AND DISCUSSIONIncreased quantity of Fe total /t DO:0.038t Fe total /t DO.Decreasing quantity ofCO 2 in rotary kiln gases: 17.41 m 3 NCO 2 /t DO.Decreasing quantity ofCO 2 in electric furnaces gases: 11.605 m 3 NCO 2 /tDO.Increased quantity ofNi:0.0011t Ni/t DO.Increased quantity of Fe total in electric furnaceslag: 3.89 % Fe total.Decreasing of production cost:80 US $/ t Ni.From three components diagram (fig.1) we cancompare the liquid temperature of electricfurnace slag for 2 examples, depending fromchemical composition of slagChemical composition of main components ofelectric furnace slaga). Slag with albanian ores:SiO 2 = 60.96 %;MgO + CaO = 18.43 + 2.75 = 21.18 %;FeO = 15.60 %;FeO+ MgO + CaO = 36.78 %.Tl ≈ 1630 ° Cb). Slag with out albanians ores:SiO 2 = 64.19 %MgO + CaO = 19.4 + 2.89 = 22.29 %;FeO = 10.58 %;FeO + MgO + CaO = 32.87 %.Tl ≈ 1690 ° C.In rotary kiln is improved roasting process ofcalcine and is reduced quantity of sticking calcinefor 50 – 60 %. Is increased quantity and quality ofcalcine, producing more calcine, withtemperature around 700 C, rate of pre-reduction40% and is reduced sufficiently consumption ofmazut up to 42 kg mazut/t calcine ( July 2010)..Total elimination of CaCO 3 in metallurgicalprocess , has been increased capacity of rotaryAKTET Vol. IV, Nr 2, 2011 263

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