Ident-No: HARDENER HV 997 - AMI-CON

SAFETY DATA SHEETaccording to applicable EC directiveIdent-No: HARDENER HV 997Version 6 Print Date 08.05.2009Revision Date 22.03.20091. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THECOMPANY/UNDERTAKINGProduct informationTrade name : HARDENER HV 997Use : Hardener for adhesive systemsCompany: Huntsman Advanced Materials (Europe)BVBAEverslaan 453078 Everberg / BelgiumTelephone : +41619661599Telefax : +41619661589Emergency telephone : +32 35 751 234 (in France ORFILA : +33(0)145425959)numberFor further Product EHS related questions concerning this document or its contents, pleasecontact:E-Mail: global_product_ehs_admat@huntsman.com2. HAZARDS IDENTIFICATIONIrritating to eyes and skin.May cause sensitization by skin contact.3. COMPOSITION/INFORMATION ON INGREDIENTSChemical natureAliphatic polyamine adductpreparationHazardous componentsChemical Name CAS-No. Symbol(s): R-phrase(s) Concentration [%]diethylenetriamine111-40-0 C R21/22 R34 R43 3.00 - 9.00EC-No.: 203-865-4triethylenetetramine 112-24-3 C R21 R34 R43 R52/53 1.00 - 7.00EC-No.: 203-950-64,4'-isopropylidenediphenolEC-No.: 201-245-880-05-7 Xn R37 R41 R43 R62 1.00 - 7.004. FIRST AID MEASURESInhalationEye contactSkin contact: Move to fresh air.Call a physician immediately.: Rinse immediately with plenty of water for at least 15 minutes.If eye irritation persists, consult a specialist.: Wash off with soap and plenty of water.If skin irritation persists, call a physician.1/6

SAFETY DATA SHEETaccording to applicable EC directiveIdent-No: HARDENER HV 997Version 6 Print Date 08.05.2009Revision Date 22.03.2009Ingestion: Do not induce vomiting.Immediately give plenty of water (if possible charcoal slurry).Obtain medical attention.5. FIRE-FIGHTING MEASURESSuitable extinguishingmediaExtinguishing media whichmust not be used for safetyreasonsSpecific hazards during firefightingSpecial protectiveequipment for fire-fighters: Water spray.Dry powder.Carbon dioxide (CO2).Foam.: High volume water jet.: Burning produces obnoxious and toxic fumes.Carbon oxides.: Wear self-contained breathing apparatus and protective suit.6. ACCIDENTAL RELEASE MEASURESPersonal precautionsEnvironmental precautionsMethods for cleaning up: Do not breathe vapours/dust.Avoid contact with skin, eyes and clothing.Ensure adequate ventilation.: Do not allow material to contaminate ground water system.: Soak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust).7. HANDLING AND STORAGEHandlingAdvice on safe handling: Provide sufficient air exchange and/or exhaust in work rooms.Handle and open container with care.StorageFurther information onstorage conditionsStorage hazard classHuntsman AdvancedMaterials: Keep away from food, drink and animal feeding stuffs.Keep container tightly closed.Keep at temperatures between 2 and 40°C.: Storage class 12, Liquids, not dangerous2/6

SAFETY DATA SHEETaccording to applicable EC directiveIdent-No: HARDENER HV 997Version 6 Print Date 08.05.2009Revision Date 22.03.20098. EXPOSURE CONTROLS / PERSONAL PROTECTIONComponents with workplace control parametersComponents CAS-No. ControlUpdateBasisparametersdiethylenetriamine 111-40-0 4.3 mg/m3 GB-OES 8HEngineering measuresEnsure adequate ventilation, especially in confined areas.Personal protective equipmentRespiratory protection: In case of insufficient ventilation wear suitable respiratoryequipment.Filter type AX-P2 (organic vapours, particles)Eye protectionHand protectionSkin and body protectionHygiene measuresProtective measures: goggles: Material of gloves for long term application (BTT>480 min):Butyl rubberEthyl Vinyl Alcohol Laminate (EVAL)Material of gloves for short term/splash application (10min

SAFETY DATA SHEETaccording to applicable EC directiveIdent-No: HARDENER HV 997Version 6 Print Date 08.05.2009Revision Date 22.03.2009Thermal decomposition : > 200 °CFlash point : 124 °CMethod: DIN 51584Vapour pressureDensity: approx.4 Paat 20 °C: 0.9 g/cm3at 25 °CWater solubility : at 20 °CNote: practically insolubleMiscibility with water: immiscibleat 20 °C10. STABILITY AND REACTIVITYConditions to avoidMaterials to avoidHazardous decompositionproducts: Note: Take necessary action to avoid static electricitydischarge.: Strong acids and strong bases.Strong oxidizing agents.: Carbon oxides. Burning produces obnoxious and toxic fumes.11. TOXICOLOGICAL INFORMATIONAcute oral toxicityEye irritationSkin irritationSensitization: LD50 ratDose: > 5,000 mg/kg: irritatingrabbit: irritatingrabbitdermal: Causes sensitization.guinea pigdermal12. ECOLOGICAL INFORMATIONElimination information (persistence and degradability)Biodegradability: Result: Not readily biodegradable.Ecotoxicity effects4/6

SAFETY DATA SHEETaccording to applicable EC directiveIdent-No: HARDENER HV 997Version 6 Print Date 08.05.2009Revision Date 22.03.2009Further information on ecology13. DISPOSAL CONSIDERATIONSProduct : Waste Key Number: 070204Must be incinerated, when in compliance with local regulations.Container: Empty containers can be landfilled after cleaning, when incompliance with the Environmental Protection (Duty of Care)Regulations 1991.14. TRANSPORT INFORMATIONLand transportADR:Regulation:RID:Regulation:Not dangerous goodsNot dangerous goodsSea transportIMDG:Regulation:Not dangerous goodsAir transportIATA-DGR:Regulation:Not dangerous goods15. REGULATORY INFORMATIONLabelling according to EEC DirectiveLabelling requiredSymbol(s): : Xi IrritantR-phrase(s) : R36/38 Irritating to eyes and skin.R43May cause sensitization by skin contact.S-phrase(s) : S28 After contact with skin, wash immediatelywith plenty of soap and water.S37/39 Wear suitable gloves and eye/faceprotection.5/6

SAFETY DATA SHEETaccording to applicable EC directiveIdent-No: HARDENER HV 997Version 6 Print Date 08.05.2009Revision Date 22.03.2009Hazardous componentswhich must be listed on thelabel: diethylenetriamineEC-No.: 203-865-4Further information : According to Directive 88/379/EEC, Article 3, Paragraph 3b,classification derived from direct toxicological testing of thepreparation take precedence over classification derived fromusing the conventional (calculation) method.National legislationNotification status: EINECS yes: TSCA yes16. OTHER INFORMATIONList of R-phrases (Section 3)R21Harmful in contact with skin.R21/22 Harmful in contact with skin and if swallowed.R34Causes burns.R37Irritating to respiratory system.R41Risk of serious damage to eyes.R43May cause sensitization by skin contact.R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.R62Possible risk of impaired fertility.The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is the recognisedabbreviation for the Chemicals Hazard Information and Packaging Regulations). This is an additionto the Health and Safety at Work Act 1974.Users of products supplied by Huntsman AdvancedMaterials should take appropriate measures to ensure working practices are in accordance with theControl of Substances Hazardous to Health Regulations (COSHH).All information is based on results gained from experience and tests and is believed to be accuratebut is given without acceptance of liability for loss or damage attributable to reliance thereon asconditions of use lie outside our control. Users should always carry out sufficient tests to establishthe suitability of any products for their intended applications. No statements shall be incorporated inany contract unless expressly agreed in writing nor construed as recommending the use of anyproduct in conflict of any patent. All goods are supplied subject to Huntsman Advanced MaterialsGeneral Conditions of Sale.6/6