SAFETY DATA SHEET (91/155/EWG) - DeguDent

SAFETY DATA SHEETTriad DuaLineMaterial no.Specification 143882VA-Nr(91/155/EWG)Version2.0 / GBRevision date 17.11.2004Print Date 22.06.2009Page 1 / 61. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKINGProduct informationTrade name: Triad DuaLineCompany: DeguDent GmbHPostfach 1364D-63403 HanauTelephone : +49 (0)6181/59-5767Telefax : +49 (0)6181/59-5879Emergency telephone number : +49 (0)180 / 23 24-555Use of the Substance /Preparation: For dental use only.2. COMPOSITION/INFORMATION ON INGREDIENTSChemical natureThe preparation contains:Polyacrylate-CopolymerPigmentsinitiatorsstabilisersDibenzoylperoxideInformation on ingredients / Hazardous components• 7,7,9 (or7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diaza-hexadecane-1,16-diyl-bismethacrylate >60%CAS-No. 72869-86-4 EC-No. 276-957-5R52/53• Silicon dioxide, chemically prepared < 10%CAS-No. 7631-86-9 EC-No. 231-545-4See chapter 16 for text of risk phrases3. HAZARDS IDENTIFICATIONHarmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.4. FIRST AID MEASURESInhalationBring affected person outside and ensure that he/she is comfortable.SDB(P18/001) / 17.11.2004 13:09

SAFETY DATA SHEETTriad DuaLineMaterial no.Specification 143882VA-Nr(91/155/EWG)Version2.0 / GBRevision date 17.11.2004Print Date 22.06.2009Page 2 / 6Skin contactWash off immediately with soap and plenty of water.Remove contaminated or saturated clothing immediately and dispose off safely.If skin irritation persists, call a physician.Eye contactRinse thoroughly with plenty of water keeping eyelid open.If eye irritation persists, consult a specialist.IngestionCall a physician immediately.5. FIRE-FIGHTING MEASURESSuitable extinguishing mediawater spray, mist, carbon dioxide (CO2), quenching powderExtinguishing media which must not be used for safety reasonshigh volume water jetSpecial protective equipment for fire-fightersEmploy protective equipment commonly used in the event of fire.In the event of fire, wear self-contained breathing apparatus.6. ACCIDENTAL RELEASE MEASURESPersonal precautionsHandle in accordance with good industrial hygiene and safety practices.Environmental precautionsPrevent penetration into soil, stretches of water and drainage systems.Methods for cleaning upUse mechanical handling equipment.7. HANDLING AND STORAGEHandlingSafe handling adviceNo eating, drinking, smoking, or snuffing tobacco at work.Handle in accordance with good industrial hygiene and safety practices.Advice on protection against fire and explosionKeep away from sources of ignition - No smoking.In case of fire cool containers or take them to a safe place.StorageRequirements for storage areas and containersStore in the original receptacle, keeping this tightly sealed, under cool and dry conditions.8. EXPOSURE CONTROLS / PERSONAL PROTECTIONComponents with workplace control parametersSDB(P18/001) / 17.11.2004 13:09

SAFETY DATA SHEETTriad DuaLineMaterial no.Specification 143882VA-Nr(91/155/EWG)Version2.0 / GBRevision date 17.11.2004Print Date 22.06.2009Page 3 / 6• Silicon dioxide, chemically preparedCAS-No. 7631-86-9 EC-No. 231-545-4Control parameters 6 mg/m3 Time Weighted Average (TWA):(EH40OES)type of exposition Total inhalable dust.Control parameters 2.4 mg/m3 Time Weighted Average (TWA):(EH40OES)type of exposition Respirable dust.Control parameters 4 mg/m3 Time Weighted Average (TWA):(EH40(UK))type of exposition Respirable dust.Control parameters 10 mg/m3 Time Weighted Average (TWA):(EH40(UK))type of exposition Total inhalable dust.Personal protective equipmentHand protectionprotective glovesSuitability for specific workplaces should be clarified with protective glove manufacturers.Eye protectionsafety glassesHygiene measuresWash hands before breaks and at the end of workday.No eating, drinking, smoking, or snuffing tobacco at work.9. PHYSICAL AND CHEMICAL PROPERTIESAppearanceFormColourOdourSafety datapHpasteaccording to the colorationcharacteristicn.a.Flash point > 150 °CAutoinflammabilityExplosivenessDensityWater solubilityViscosity, dynamicnot spontaneously flammablenot explosivenot determinedinsolubleviscous10. STABILITY AND REACTIVITYSDB(P18/001) / 17.11.2004 13:09

SAFETY DATA SHEETTriad DuaLineMaterial no.Specification 143882VA-NrConditions to avoidMaterials to avoidHazardous decomposition productsHazardous reactions(91/155/EWG)Version2.0 / GBRevision date 17.11.2004Print Date 22.06.2009Page 4 / 6Avoid light effect heat sources of ignition.radical generating substancesNone knownpolymerization11. TOXICOLOGICAL INFORMATIONAcute oral toxicitySkin irritationEye irritationLD50 Rat: > 5000 mg/kgMethod: OECD Test Guideline 401related to substance: 7,7,9 (or7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diaza-hexadecane-1,16-diyl-bismethacrylateRabbit / 4 hnot irritatingMethod: OECD Test Guideline 404related to substance: 7,7,9 (or7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diaza-hexadecane-1,16-diyl-bismethacrylateRabbitnot irritatingMethod: OECD Test Guideline 405related to substance: 7,7,9 (or7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diaza-hexadecane-1,16-diyl-bismethacrylate12. ECOLOGICAL INFORMATIONElimination information (persistence and degradability)Behaviour in environmental compartmentsEcotoxicity effectsToxicity to fishToxicity to daphniaLC50 (Brachydanio rerio): 10000 mg/l / 96 hMethod: OECD 203related to substance: Silicon dioxide, chemically preparedEC50 Daphnia magna: 10000 mg/lMethod: OECD 202related to substance: Silicon dioxide, chemically preparedFurther information on ecologyFurther InformationPrevent penetration into soil, stretches of water and drainage systems.SDB(P18/001) / 17.11.2004 13:09

SAFETY DATA SHEETTriad DuaLineMaterial no.Specification 143882VA-Nr(91/155/EWG)Version2.0 / GBRevision date 17.11.2004Print Date 22.06.2009Page 5 / 613. DISPOSAL CONSIDERATIONSProductDisposal according to local authority regulations.Uncleaned packagingDisposal according to local authority regulations.14. TRANSPORT INFORMATIONTransport/further informationNot classified as dangerous in the meaning of transport regulations.15. REGULATORY INFORMATIONLabelling according to EC Directiveshazard-defining component(s)• 7,7,9 (or7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diaza-hexadecane-1,16-diyl-bismethacrylateR-phrase(s) R52/53 Harmful to aquatic organisms, may cause long-termadverse effects in the aquatic environment.S-phrase(s) S61 Avoid release to the environment. Refer to specialinstructions/safety data sheets.National legislation16. OTHER INFORMATIONRisk phrase (R phrase) texts• 7,7,9 (or7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diaza-hexadecane-1,16-diyl-bismethacrylateR52/53 Harmful to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.Further informationChanges since the last version are highlighted in the margin. This version replaces all previousversions.The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and is notto be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.SDB(P18/001) / 17.11.2004 13:09

SAFETY DATA SHEETTriad DuaLineMaterial no.Specification 143882VA-Nr(91/155/EWG)Version2.0 / GBRevision date 17.11.2004Print Date 22.06.2009Page 6 / 6SDB(P18/001) / 17.11.2004 13:09