HM 1400 TRX Total Mercury Analyser - Webshop, Gas Analysis ...

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14. Appendix Extracts from safety data sheetscarbides, halogen oxides.Dangerous products of decomposition: The following can result in the event offire: Mercury vapours.Toxicological informationAcute toxicityAdditional toxicological information: After skin contact: Risk of skin sensitisation.Other information: In the event of intoxication, Hg compounds act as cell andprotoplasmic poisons.Symptoms of poisoning: acute: eye contact results in severe lesions. Afterswallowing and inhalation of dusts, the mucous membranes in thegastrointestinal and respiratory tract are damaged (metallic taste, nausea,vomiting, abdominal pain, bloody diarrhoea, intestinal corrosion, glotticoedema, aspiration pneumonia); reduction in blood pressure, cardiacdisrhythmia, circulatory collapse and kidney failure; chronic: Inflammation ofthe oral cavity with loss of teeth and mercury edge. Main manifestationsappear in the CNS (speech, vision, hearing, sensitivity disorders, amnesia,irritability, hallucinations, delirium, among other things).Disposal informationChemicals must be disposed of in compliance with the pertinent national regulations.Transport informationRID/ADR: UN 2809 MERCURY, 8, IIIIMDG code: UN 2809 MERCURY, 8, IIIEmS: F-A S-BThe transport regulations are cited in accordance with the internationalregulations and in the form in which they are applied in Germany. Possibledeviations in other countries are not taken into account.Regulations1. IdentificationEC number: 231-106-7Symbols:T ToxicN Hazardous to the environmentR phrases: 23-33-50/53Toxic if inhaled. Risk of cumulative effects.Very toxic for water organisms, can have long term harmful effects in water courses.S phrases: 7-45-60-61Keep container tightly closed. In case of accident or feeling unwell, consult adoctor immediately (produce "Mercury" safety data sheet if possible). This substanceand its container are to be disposed of as hazardous waste. Avoid release intothe environment. Refer to special instructions/consult safety data sheet.2. National regulationsWater hazard class: 3Storage class VCI:6.1 BBG-Chemie data sheet:M024 Mercury and its compoundsM050 Handling hazardous substancesHazardous Incident Ordinance no.: 29aEmployment restrictions:Comply with employment restrictions forjuveniles in accordance with § 22 JArbSchGComply with restrictions for pregnant andnursing women in accordance with §§ 4 and5 MuSchRiV96 HM 1400 TRX
14. Appendix Extracts from safety data sheets14.5 Extract from safety data sheet for hydrochloric acidPlease note the reference to the extracts from safety data sheets used here on page 90!Manufacturer:variousTotal formula:HClPotential dangers: Causes chemical burns. Irritates therespiratory organs. Risk of pulmonaryoedemaChemicals in principle give rise to particular dangers. Therefore, they mustalways be handled with the necessary care by appropriately trained personnel.First-aid measures:Eye contact: Rinse with plenty of water, keeping eyelid open (min. 10 min.),consult eye specialist immediately.Skin contact: Wash off with plenty of soap and water. Remove contaminatedclothing immediately.Ingestion: If conscious drink plenty of water, do not induce vomiting. Consult adoctor immediately.Inhalation: Remove casualty to fresh air and keep at rest.Fire-fighting measures:Suitable extinguishing agents: Water mist, foam, carbon dioxide, dry powder.Particular dangers: Particular hazard from the substance, its combustionproducts or resulting gases. In the event of fire, the following can be released:Hydrogen chloride ( HCl )Special protective gear during fire-fighting: Only remain in danger area withrespiratory equipment independent of ambient air.Measures in case of accidental release:Personal precautions: Remove persons to safety. Ensure supply of fresh air inclosed roomsEnvironmental protection measures: Do not allow substance to enter sewagesystem or waterways.Cleaning/pick-up method: Pick up with liquid-binding material (e.g. sand,kieselgur, universal binder). Neutralise with lime. Forward for disposal in wellsealed containers.Handling:Extraction.Only use acid-proof equipment.Storage:Notes on storage with other substances: Do not store together with strongoxidants.Tightly closed, in a well ventilated location. Storage class: 8L Causticsubstances, liquidPersonal protective equipmentGeneral protective measures: Do not inhale vapours.Respiratory protection: necessary (full mask).Hand protection for full or splash contact: Protective rubber glovesEye protection: necessary (see respiratory protection). Safety goggles mustalways be worn when handling chemicals.Body protection: Suitable protective clothing (acid-proof in this case) mustalways be worn when handling chemicals.Safety and hygiene measures: Wash hands before breaks and at the end ofwork. Change contaminated clothing immediately and wash thoroughly beforere-using. The use of protective skin ointment is recommended for preventiveskin protection.Stability and reactivityHM 1400 TRX 97
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