Vydate L msds english.pdf - Bartlett.ca

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046This SDS adheres to the standards and regulatory requirements of Canada and may not meet the regulatory requirementsin other countries.SECTION 1. PRODUCT AND COMPANY IDENTIFICATIONProduct name : DuPont Vydate ® L Insecticide/NematicideTradename/Synonym : DPX-D1410 24LVydate ® 24LVydate ® L (Green or Blue)B10049186OXAMYL: [Methyl N'N'-dimethyl-N-[(methylcarbamoyl)oxy]-1-thiooxamimidate]MSDS Number : 130000000046Product Use : Insecticide, NematicideManufacturer : E.I. du Pont Canada CompanyP.O. Box 2200, StreetsvilleMississauga, ONL5M 2H3CanadaProduct Information : 1-800-387-2122Medical Emergency : 1-800-441-3637 (24 hours)SECTION 2. HAZARDS IDENTIFICATIONEmergency OverviewDANGER! POISON!Fatal if swallowed. May be fatal if inhaled. Do not breathe vapours or spray mist. Causes moderate eyeirritation. Avoid contact with skin, eyes and clothing.This product is toxic to: Aquatic organisms This product is extremely toxic to: Birds MammalsWarning symptoms:Poisoning produces effects associated with anticholinesterase activity which may include:Weakness Blurred vision, Breathing difficulties, Nausea, Headache, Abdominal pain, discomfort in the chest,constriction of pupils, slow pulse, sweating, muscle twitchingPotential Health Effects1 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046This section includes potential acute adverse effects which could occur if this material is not used according tothe label.SkinOxamyl : Abnormal cholinesterase levels Symptoms and signs include headache,dizziness, fatigue, muscular weakness, drowsiness and in extreme cases,loss of consciousness., Nausea, Abdominal pain, Abnormal tearing,Abnormal salivation, constriction of pupils, blurred vision, muscle twitching,Convulsions, Respiratory effects.Methanol : Toxic in contact with skin.Causes damage to the kidneys/ liver/ eyes/ brain/ respiratory system/central nervous system in contact with skin. Impairment of vision,Blindness.May cause skin irritation.May cause: Discomfort, itching, redness, or swelling.EyesOxamyl : Abnormal cholinesterase levels Abnormal tearing, constriction of pupils,Blurred vision.acute lethal effectsMethanol : May cause eye irritation.May cause: Tearing, redness, or discomfort.InhalationOxamyl : Abnormal cholinesterase levels Symptoms and signs include headache,dizziness, fatigue, muscular weakness, drowsiness and in extreme cases,loss of consciousness., Nausea, Abdominal pain, Abnormal tearing,Abnormal salivation, constriction of pupils, Blurred vision, muscle twitching,Convulsions, Respiratory effects.Methanol : Toxic by inhalation.Causes damage to the kidneys/ liver/ eyes/ brain/ respiratory system/central nervous system if inhaled. Impairment of vision, Blindness.IngestionOxamyl : Abnormal cholinesterase levels Symptoms and signs include headache,dizziness, fatigue, muscular weakness, drowsiness and in extreme cases,loss of consciousness., Nausea, Abdominal pain, Abnormal tearing,Abnormal salivation, constriction of pupils, Blurred vision, muscle twitching,Convulsions, Respiratory effects.2 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046Methanol : Toxic if swallowed.Causes damage to the kidneys/ liver/ eyes/ brain/ digestive system/ centralnervous system if swallowed. Impairment of vision, Blindness.Target OrganOxamyl : Central nervous systemMethanol : Central nervous system EyesCarcinogenicityNone of the components present in this material at concentrations equal to or greater than 0.1% are listed byIARC, NTP, or OSHA, as a carcinogen.SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTSComponent CAS-No. ConcentrationOxamyl 23135-22-0 24 %Other Ingredients 76 %Includes percentages of the following:Methanol 67-56-1 35 - 45 %SECTION 4. FIRST AID MEASURES3 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046Skin contactEye contactInhalationIngestionGeneral adviceNotes to physician: Take off all contaminated clothing immediately. Rinse skin immediately withplenty of water for 15-20 minutes. Call a poison control center or doctor fortreatment advice.: Hold eye open and rinse slowly and gently with water for 15-20 minutes.Remove contact lenses, if present, after the first 5 minutes, then continuerinsing eye. Call a poison control center or doctor for treatment advice.: Remove person to fresh air. If signs/symptoms continue, get medicalattention. Artificial respiration and/or oxygen may be necessary.: If swallowed, call a poison control centre or doctor immediately. If swallowed,drink 1 or 2 glasses of water and try once or twice to induce vomiting bytouching the back of throat with finger. Induce vomiting if person is conscious.Do not give anything by mouth to an unconscious person.: ATROPINE IS AN ANTIDOTE - SEEK MEDICAL ATTENTION AT ONCE INALL CASES OF SUSPECTED POISONINGS.Have the product container or label with you when calling a poison controlcenter or doctor, or going for treatment.For medical emergencies involving this product, call toll free 1-800-441-3637.See Label for Additional Precautions and Directions for Use.: This product is an acetyl cholinesterase inhibiting carbamate insecticide.Morphine therapy is contra-indicated.Administer atropine sulphate as an antidote until complete atropinisation (1.2-2.0 mg i.v. every 10-30 minutes). Artificial respiration and/or oxygen may benecessary. Allow no further exposure to any cholinesterase inhibitor until fullrecovery is assured.SECTION 5. FIREFIGHTING MEASURESFlammable PropertiesFlash point: 23 °C (73 °F) closed cupFire and Explosion Hazard: Vapours may form explosive mixtures with air. Heating can release vapourswhich can be ignited.Suitable extinguishing media: Water spray, Dry chemical, Foam, Carbon dioxide (CO2)4 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046Unsuitable extinguishingmediaFirefighting Instructions: High volume water jet, (contamination risk): In the event of fire, wear self-contained breathing apparatus. Wear fullprotective equipment.Evacuate personnel and keep upwind of fire. Shut off source of fuel, ifpossible and without risk. If area is heavily exposed to fire and if conditionspermit, let fire burn itself out since water may increase the area contaminated.Burning chemicals may produce by-products more toxic than the originalmaterial. Cool tank/container with water spray. Control Runoff.SECTION 6. ACCIDENTAL RELEASE MEASURESNOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with cleanup.Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up.Safeguards (Personnel)Spill CleanupAccidental Release Measures: Evacuate personnel, thoroughly ventilate area, use self-contained breathingapparatus. Use personal protective equipment.: Soak up with sawdust, sand, oil dry or other absorbent material. Shovel orsweep up. Never return to container for reuse. Scoop into bags or boxes withplastic or aluminium shovel. Neutralize with solid sodium hydroxide at a rateof 3 lbs. per gallon spilled.: Prevent material from entering sewers, waterways, or low areas.Never return spills in original containers for re-use. Dispose of in accordancewith local regulations.SECTION 7. HANDLING AND STORAGEHandling (Personnel): Wash hands thoroughly with soap and water after handling and before eating,drinking, chewing gum, using tobacco, or using the toilet. Removeclothing/PPE immediately if material gets inside. Wash thoroughly and put onclean clothing. Remove personal protective equipment immediately afterhandling this product. Wash the outside of gloves before removing. As soonas possible, wash thoroughly and change into clean clothing.5 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046Handling (Physical Aspects)StorageStorage temperature: Flammable. Keep away from heat and sources of ignition. Use only in wellventilatedareas.: Do not contaminate water, other pesticides, fertilizer, food or feed in storage.Store in original container. Not for use or storage in or around the home.Keep out of the reach of children.: > 0 °C (> 32 °F)SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEngineering controlsPersonal protective equipmentRespiratory protectionSkin and body protection: Use only with adequate ventilation. Refer to the product label for additionalEngineering Controls.: Applicators and other handlers must wear: Mixer and loaders must wear: Arespirator with an organic vapor-removing cartridge with a prefilter approvedfor pesticides (NIOSH approval number prefix TC-23C), or a canisterapproved for pesticides (NIOSH approval number prefix TC-14G), or aNIOSH approved respirator with an organic vapor (OV) cartridge or canisterwith any R, P, or HE prefilter.: Mixers, loaders, applicators and other handlers must wear:Coveralls worn over long-sleeved shirt and long pantsChemical-resistant glovesBarrier laminatebutyl-rubberNeoprenePolyvinylchlorideViton ®Chemical resistant footwear plus socksProtective eyewearChemical resistant headgear for overhead exposureChemical-resistant apron when cleaning equipment, mixing or loadingPPE required for early entry to treated areas that is permitted under theWorker Protection Standard and that involves contact with anything that hasbeen treated, such as plants, soil, or water, is:CoverallsChemical resistant gloves made of any waterproof materialShoes plus socks6 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046Protective measures: Discard clothing and other absorbent materials that have been drenched orheavily contaminated with this product. Do not reuse them. Followmanufacturer's instructions for cleaning/maintaining PPE. If no suchinstructions for washables exist, use detergent and hot water. Keep andwash PPE separately from other laundry.Exposure GuidelinesExposure Limit ValuesMethanolTLV (ACGIH) 200 ppm TWASkin designationTLV (ACGIH) 250 ppm STELAEL * (DUPONT) 200 ppm 8 & 12 hr. TWA, SkinSkin designationOxamylAEL * (DUPONT) 0.05 mg/m3 8 & 12 hr. TWAMethanolTLV (ACGIH) 200 ppm TWASkin designationTLV (ACGIH) 250 ppm STELAEL * (DUPONT) 200 ppm 8 & 12 hr. TWA, SkinSkin designationOxamylAEL * (DUPONT) 0.05 mg/m3 8 & 12 hr. TWA7 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046* AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits whichare lower than the AEL are in effect, such limits shall take precedence.SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESForm: liquidColor: green, or, blueOdor: slight, sulphurouspH: 3.6 at 10 g/l 25 °C (77 °F)Oxidising Substance: The product is not oxidizing.Density: 0.97 - 0.98 g/cm3Water solubility: solubleViscosity: 2 - 2.2 mPa.s at 25 °C (77 °F)SECTION 10. STABILITY AND REACTIVITYStability: Stable at normal temperatures and storage conditions.IncompatibilityHazardous decompositionproductsHazardous reactions: Hydrolyses in presence of:Strong acids and strong bases: Decomposition will not occur.: Hazardous polymerization will not occur.SECTION 11. TOXICOLOGICAL INFORMATIONDuPont Vydate ® L Insecticide/NematicideInhalation 4 h LC50 : 0.3 mg/l , ratDermal LD50 : > 5,000 mg/kg , rabbitOral LD50 : 9 mg/kg , female, ratOral LD50 : 10 mg/kg , male, ratSkin irritation : No skin irritation, rabbit8 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046Eye irritation : slight irritation, rabbitSensitisation : Animal test did not cause sensitization by skin contact., guinea pigOxamylEye contact : mortalityRepeated dose toxicity : Oral - feedmultiple species15 dReduced body weight gain, cholinesterase inhibitionCarcinogenicity : Did not show carcinogenic effects in animal experiments.Mutagenicity : Did not cause genetic damage in animals.Tests on bacterial or mammalian cell cultures did not show mutageniceffects.Reproductive toxicity : Animal testing showed effects on reproduction at levels equal to orabove those causing parental toxicity.Teratogenicity : Animal testing showed effects on embryo-fetal development at levelsequal to or above those causing maternal toxicity.MethanolCarcinogenicity : Overall weight of evidence indicates that the substance is notcarcinogenic.Mutagenicity : Overall weight of evidence indicates that the substance is notmutagenic.Did not cause genetic damage in animals.Genetic damage in cultured mammalian cells was observed in somelaboratory tests but not in others.Genetic damage in cultured bacterial cells was observed in somelaboratory tests but not in others.Reproductive toxicity : Evidence suggests the substance is not a reproductive toxin inanimals.Teratogenicity : Evidence suggests the substance is not a developmental toxin inanimals.9 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046SECTION 12. ECOLOGICAL INFORMATIONAquatic ToxicityDuPont Vydate ® L Insecticide/Nematicide96 h LC50 : Oncorhynchus mykiss (rainbow trout) 27 mg/l72 h ErC50 : Selenastrum capricornutum (green algae) 34 mg/l48 h EC50 : Daphnia magna (Water flea) 3 mg/lOxamyl61 d Early Life-Stage : NOEC Oncorhynchus mykiss (rainbow trout) 0.77 mg/l21 d flow-through test : NOEC Daphnia magna (Water flea) 0.0268 mg/lEnvironmental FateMethanolBiodegradability : Readily biodegradable.Bioaccumulation : Bioaccumulation is unlikely.Additional ecological information : Environmental Hazards: Do not apply directly to water, or to areaswhere surface water is present, or to intertidal areas below the meanhigh water mark. Run-off from treated areas may be hazardous toaquatic organisms in neighboring areas. Do not contaminate waterwhen cleaning equipment or disposing of equipment washwaters orrinsate. See product label for additional application instructionsrelating to environmental precautions.SECTION 13. DISPOSAL CONSIDERATIONSWaste Disposal: Do not contaminate water, food or feed by disposal. Pesticide wastes areacutely hazardous. Improper disposal of excess pesticide, spray mixture, orrinsate is a violation of Federal law. If these wastes cannot be disposed of byuse according to label instructions, contact your State Pesticide orEnvironmental Control Agency, or the Hazardous Waste representative at the10 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046nearest EPA Regional Office for guidance.Container Disposal: Container Refilling and Disposal:Refer to the product label for instructions.In the event of a major spill, fire or other emergency, call 1-800-441-3637 dayor night.SECTION 14. TRANSPORT INFORMATIONTDG_ROAD UN number : 2991Proper shipping name: CARBAMATE PESTICIDE, LIQUID, TOXIC,FLAMMABLEClass : 6.1 (3)Packing group: IILabelling No. : 6.1 (3)TDG_RAIL UN number : 2991Proper shipping name: CARBAMATE PESTICIDE, LIQUID, TOXIC,FLAMMABLEClass : 6.1 (3)Packing group: IILabelling No. : 6.1 (3)IATA_C UN number : 2991Proper shipping name: Carbamate pesticide, liquid, toxic, flammable (Methanol,Oxamyl)Class : 6.1 (3)Packing group: IILabelling No. : 6.1 (3)IMDG UN number : 2991Proper shipping name: CARBAMATE PESTICIDE, LIQUID, TOXIC,FLAMMABLE (Methanol, Oxamyl)Class : 6.1 (3)Packing group: IILabelling No. : 6.1 (3)Marine pollutant: yes (Oxamyl)11 / 12

Material Safety Data SheetDuPont Vydate ® L Insecticide/NematicideVersion 2.0Revision Date 06/14/2013 Ref. 130000000046SECTION 15. REGULATORY INFORMATIONEPA Reg. No. : 352-372In the United States this product is regulated by the US EnvironmentalProtection Agency (EPA) under the Federal Insecticide, Fungicide andRodenticide Act (FIFRA). It is a violation of Federal law to use this product ina manner inconsistent with its labeling. Read and follow all label directions.This product is excluded from listing requirements under EPA/TSCA.PCP Registration # : 17995Remarks: Regulated under the Pest Control Products Act - WHMIS exempt.SECTION 16. OTHER INFORMATIONMSDS preparation date : 06/14/2013 Trademark of E.I. du Pont de Nemours and Company.® Registered trademark of E.I. du Pont de Nemours and CompanyContact person : E.I. DuPont Canada Company, Mississauga, Ontario, L5M 2H3The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief atthe date of its publication. The information given is designed only as a guidance for safe handling, use, processing,storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Theinformation relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process, unless specified in the text.Significant change from previous version is denoted with a double bar.12 / 12