FOG Analysis with the FOG Analysis with the InfraCal TOG/TPH ...
FOG Analysis with the FOG Analysis with the InfraCal TOG/TPH ... FOG Analysis with the FOG Analysis with the InfraCal TOG/TPH ...
FOG Analysis with the InfraCalTOG/TPH Analyzerswww.WilksIR.com
- Page 2 and 3: Fats, Oils and Grease (FOG)New FOG
- Page 4 and 5: Important for FOG ProgramsLocate&Mo
- Page 6 and 7: Monitoring Using an Offsite Lab=Del
- Page 8 and 9: Non Compliance The sooner the indus
- Page 10 and 11: FOG Analysis with the InfraCalTOG/T
- Page 12 and 13: Spectrum of a hydrocarbon (red)Over
- Page 14 and 15: Two different models availabledepen
- Page 16 and 17: The Measurement of Oil usingHexaneM
- Page 18 and 19: Infrared light (source) is focused
- Page 20 and 21: At each reflection, the infrared li
- Page 22 and 23: A higher oil and grease concentrati
- Page 24 and 25: Preset timer allowshexane to evapor
- Page 26 and 27: Measurement Range Hexane extraction
- Page 28 and 29: The Measurement of Oil usingS-316 o
- Page 30 and 31: ASTM Method D 7066-0404 Uses a tran
- Page 32 and 33: The infrared light is focused on to
- Page 34 and 35: Cuvette is placed in the analyzerAf
- Page 36 and 37: Repeatability of theS-316 or perc/I
- Page 38 and 39: FOG-Fats, Fats, Oil and Grease Not
- Page 40 and 41: TechnologyInfraredGravimetryGC/FIDU
- Page 42 and 43: Same Samples,Three Different Labora
- Page 44 and 45: Using this simple and quick infrare
<strong>FOG</strong> <strong>Analysis</strong> <strong>with</strong> <strong>the</strong> <strong>InfraCal</strong><strong>TOG</strong>/<strong>TPH</strong> Analyzerswww.WilksIR.com
Fats, Oils and Grease (<strong>FOG</strong>)New <strong>FOG</strong> limits are forcingindustries and regulating agenciesto monitor effluent more frequently
Fats, Oils and Grease (<strong>FOG</strong>)• 23-28% of Sanitary Sewer Overflows(SSOs) are due to Fats, Oils and Grease(<strong>FOG</strong>)• as much as 19 million gallons from 1998 to2001
Important for <strong>FOG</strong> ProgramsLocate&MonitorIndustries and food service establishmentsdumping high levels of <strong>FOG</strong>
Important for <strong>FOG</strong> Programs Set standards for grease traps,interceptors, and separators Monitor for compliance Enforce limits
Monitoring Using an Offsite Lab=Delayed Results
Monitoring Using an Offsite Lab Typical commercial laboratory turn around - twodays to two weeks In-house hexane/gravimetric—several hours Results in <strong>the</strong> discharge of effluent aboveregulatory limit for extended time Add costs in time and dollars
Non Compliance The sooner <strong>the</strong> industry or regulatingagency can detect non compliance The sooner <strong>the</strong> problem can becorrected
What is needed:A quick, accurate and simplefield and/or in-plant analysis
<strong>FOG</strong> <strong>Analysis</strong> <strong>with</strong> <strong>the</strong> <strong>InfraCal</strong><strong>TOG</strong>/<strong>TPH</strong> Analyzer
Basic Measurement ConceptInfrared <strong>Analysis</strong>:Hydrocarbons have a characteristicabsorbance in <strong>the</strong> infrared region:2930 cm- 1 or 3.4 microns
Spectrum of a hydrocarbon (red)Overlaid <strong>with</strong> a 3.4 micron filter (black)
Infrared AbsorbanceThe amount of energy absorbedis proportional to <strong>the</strong> amount ofoil/grease in <strong>the</strong> sample:A higher oil and grease concentrationhas a higher infrared absorbanceA lower oil and grease concentrationhas a lower infrared absorbance
Two different models availabledepending on desired measurementrange and extraction solventModel CVHModel HATR-T2T2
CVHMinimum Detection Limit 2 ppm 8 ppmSolventPerchloroethylene, Freon,S-316HATR-T2hexane, pentane,Vertrel MCAComponent Measured Measures all hydrocarbons Measures hydrocarbons<strong>with</strong> a boiling point higherInstrument Repeatability +/- 1 ppm +/- 2 ppmO<strong>the</strong>rSolvents are heavier thanwater and require a seperatoryfunnel or inverted vial <strong>with</strong> asepta cap to collect a solventsample.than <strong>the</strong> solvent—volatilehydrocarbons will beevaporated along <strong>with</strong> <strong>the</strong>solvent.Solvents are lighter thanwater and solvent samplecan be collected from <strong>the</strong>top of <strong>the</strong> container.
The Measurement of Oil usingHexaneModel HATR-T2T2
The hexane evaporates leaving anoil film on <strong>the</strong> crystalOil FilmSourceATR crystalA = log (I r / I a )Filters(I r / I a )DualDetector
Infrared light (source) is focused on <strong>the</strong>end of <strong>the</strong> crystalOil FilmSourceATR CrystalA = log (I r / I a )Filters (I r / I a)DualDetector
The infrared light reflects off<strong>the</strong> surface of <strong>the</strong> crystalOil FilmSourceATR CrystalA = log (I r / I a )Filters (I r / I a )DualDetector
At each reflection, <strong>the</strong> infrared lightpenetrates into <strong>the</strong> oil film and is absorbedby <strong>the</strong> oil at 2930cm-1Infrared lightSampleOil Film
The infrared light is focused on toa detector containing a2930cm-1 filterOil FilmSourceATR crystalFilters (I r / I a ) DualA = log (I r / I ) a Detector
A higher oil and grease concentrationhas a higher infrared absorbanceA lower oil and grease concentrationhas a lower infrared absorbance
Hexane Extraction –Model HATR-T2T2 Acidify sample to pH of 2 Add 10 ml solvent to 100mlsample (10 to 1 ratio) Shake for 2 minutes Hexane separates totop
Preset timer allowshexane to evaporate After timercountdown and 15second run time Value is displayed
<strong>Analysis</strong> ProcedureThe whole analysis, from samplecollection to final result, takes under 15minutesAn operator <strong>with</strong> minimal training cando <strong>the</strong> analysis
Measurement Range Hexane extraction: 10- 300 ppm** <strong>the</strong> upper limit can be extended by dilution
Repeatability of <strong>the</strong> Hexane/InfraredMethodRepeated runs on same sample: + 01Independent applications of sample: + 02Independently prepared samples: +03** Repeatability is dependent on how carefully <strong>the</strong>analyst does <strong>the</strong> extraction
The Measurement of Oil usingS-316 or PerchloroethyleneModel CVH
ASTM Infrared Oil and Grease Method toreplace Freon/IR MethodASTM Method D7066-04: 04:Standard Test Method for dimer/trimerofchlorotrifluoroethylene (S-316)Recoverable Oil and Grease and NonpolarMaterial by Infrared Determination
ASTM Method D 7066-0404 Uses a transmission cell – Model CVH Measures volatile constituents
The Measurement of IR Absorption ofan Oil Sample <strong>with</strong> a CuvetteSampleFilters (I R / I A )SourceDetectorsA = log I R / I AInfraRed light passes through <strong>the</strong> cuvettefilled <strong>with</strong> solvent from <strong>the</strong> sample extract
The infrared light is focused on toa detector containing a2930cm - 1 filterSampleFilters (I R / I A )SourceDetectorsA = log I R / I AThe amount of IR energy absorbed by <strong>the</strong>sample correlates to <strong>the</strong> concentration ofoil and grease in <strong>the</strong> sample
Cuvette is filled <strong>with</strong>solvent extract
Cuvette is placed in <strong>the</strong> analyzerAfter 30 seconds,<strong>FOG</strong> value is displayed
Measurement Range S-316 or Perchloroethylene: 2 -300ppm** <strong>the</strong> upper limit can be extended by dilution
Repeatability of <strong>the</strong>S-316 or perc/Infrared MethodRepeated runs on same sample: + 01Independent applications of sample: + 01Independently prepared samples: +02** Repeatability is dependent on how carefully <strong>the</strong>analyst does <strong>the</strong> extraction
Comparing Different AnalyticalProcedures
<strong>FOG</strong>-Fats, Fats, Oil and Grease Not a unique chemical entity A mixture of chemical species that varyfrom source to source It is defined by <strong>the</strong> analytical procedure,ie: infrared, gravimetric, GC/FID
Comparing Different Analytical Infrared GravimetricProcedures Gas Chromatograph/FlameIonization Detector (GC/FID) Ultra VioletEach method measures different physicalproperties
TechnologyInfraredGravimetryGC/FIDUltra VioletWhat isMeasuredAll analytes removed from<strong>the</strong> samples by <strong>the</strong>extraction solvent thatcontain a C-H stretchingabsorption.All analytes removed from<strong>the</strong> sample by <strong>the</strong> extractionsolvent that are notvolatilized.All analytes removed from<strong>the</strong> sample by <strong>the</strong> extractionsolvent that can bechromatographed and thatrespond to <strong>the</strong> detector.Aromatics onlyWhat is NotMeasuredVery polar organicsVolatilesVery polar or involatilecompounds dependingon choice of column,temperature program,time, etc.Aliphahtics
Comparison of Hexane/Infrared andMeat Packing PlantHexane/GravimetricInfraredGravimetricSample 1 67 ppm 70 ppmSample 2 1990 2020After Grease Trap at a RestaurantSample 1 423 415Sample 2 332 300Sample 3 103 130Sample 4 157 170Sample 5 67 74
Same Samples,Three Different Laboratories<strong>InfraCal</strong>Wilks<strong>InfraCal</strong> Lab 1 Lab 2 Lab 3Customer51 49 67 23 5162 61 74 43 4771 -- 76 70 4963 53 66 55 403 1 14 7
Using this simple and quick infrared procedure,operators of a pretreatment system can: Quickly and easily assess <strong>the</strong>ir system’sefficiency Take samples before and after treatment Change <strong>the</strong>ir system’s parameters andimmediately test <strong>the</strong> results of <strong>the</strong>ir changes See how <strong>the</strong>ir system functions under heavyloads Avoid discharging effluent that is above <strong>the</strong>regulatory limit
Using this simple and quick infrared procedure,regulators can: Quickly and easily test industrial wastewater Immediately catch discharges above regulatorylimit Reduce <strong>the</strong> number of samples sent to alaboratory Avoid effluent that is above <strong>the</strong> regulatory limit
<strong>FOG</strong> <strong>Analysis</strong> <strong>with</strong> <strong>the</strong> <strong>InfraCal</strong><strong>TOG</strong>/<strong>TPH</strong> Analyzerswww.WilksIR.comFor questions or more information:info@WilksIR.com203-855-9136