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Rare Earth Elements: A Review of Production, Processing ...

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<strong>Rare</strong> <strong>Earth</strong> <strong>Elements</strong> <strong>Review</strong> Section 5 – <strong>Rare</strong> <strong>Earth</strong> Element Recovery/Alternative Material Use<br />

Engineering discovered how to recover significant quantities <strong>of</strong> REOs present in titanium dioxide<br />

mineral. While the original benefits <strong>of</strong> this technology were thought to be that it could improve<br />

purity, eliminate hazardous wastes, and cut costs and CO2 emissions, the team also discovered<br />

that they could extract significant quantities <strong>of</strong> REM oxides as co-products <strong>of</strong> the refining<br />

process. Current recovery rates <strong>of</strong> oxides <strong>of</strong> neodymium, cerium, and lanthanum vary between 60<br />

percent and 80 percent and are thought to be able to be increased in the future (University <strong>of</strong><br />

Leeds, 2009).<br />

5.3 Commercial REE-Recycling Applications<br />

<strong>Review</strong> <strong>of</strong> the literature indicates that the number <strong>of</strong> commercial REE-recycling operations is limited, but<br />

that is likely to change in the near future due to the number <strong>of</strong> operations under development and the<br />

amount <strong>of</strong> research that is ongoing. Table 5-1 provides a summary <strong>of</strong> commercial, or soon-to-becommercial,<br />

operations by selected companies and includes the information that is known on the target<br />

item to be recycled, the materials being recovered, the technology to be used, the anticipated time frame<br />

until commercial application; notes with respect to cost or environmental benefits; and the source <strong>of</strong><br />

information. Consistent with the information reported here, the literature indicates that the focus <strong>of</strong> REErecycling<br />

research and commercialization efforts has been on magnets, batteries, lighting and<br />

luminescence, and catalysts (Schuler et al., 2011). It should be noted that in many cases, the companies<br />

that are in the process <strong>of</strong> developing or deploying recycling technologies have not published reports or<br />

papers with the details <strong>of</strong> their individual processes, as these are generally a competitive advantage and<br />

considered proprietary.<br />

Company<br />

Table 5-1. Recycling Operations, Technologies Utilized, Current Status, and Benefits<br />

Target<br />

Feedstock/<br />

Element<br />

Hitachi <strong>Rare</strong> earth<br />

magnets from<br />

air conditioner<br />

compressors<br />

and hard disk<br />

drives<br />

Toyota Hybrid car<br />

batteries<br />

Technology<br />

to Be Used<br />

Automated<br />

separation<br />

process and<br />

dry extraction<br />

process<br />

Anticipated Time to<br />

Commercialization<br />

Anticipates recycling<br />

will meet 10% <strong>of</strong> its<br />

need by 2013 when<br />

facility goes online<br />

Benefits (Cost and<br />

Environmental) Source<br />

Dry extraction<br />

method that allows<br />

processing without<br />

acids; resulting waste<br />

water problem.<br />

Automated<br />

separation process is<br />

faster than manual.<br />

Cost savings<br />

anticipated.<br />

Unknown Ongoing Main driver is supply<br />

concerns<br />

http://www.hitachi.<br />

com/New/cnews/1<br />

01206.pdf<br />

http://shanghaiscr<br />

ap.com/?p=5654<br />

Japan’s Air conditioners Plans to 2011 No information http://www.matter<br />

Shin-Etsu recycle readily available. network.com/2011<br />

Chemical recovered<br />

/3/new-push­<br />

REEs into<br />

recycle-rare<br />

magnets<br />

earth.cfm<br />

Showa Dysprosium and No Estimated output <strong>of</strong> No information http://www.bloomb<br />

Denko KK didymium (a information 800 tons from readily available. erg.com/news/201<br />

mixture <strong>of</strong> readily recycling facility<br />

0-12-08/hitachi­<br />

praseodymium available.<br />

recycles-rare<br />

and<br />

earth-as-china<br />

neodymium)<br />

crimpssupply.html<br />

5-8

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