Rare Earth Elements: A Review of Production, Processing ...
Rare Earth Elements: A Review of Production, Processing ...
Rare Earth Elements: A Review of Production, Processing ...
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<strong>Rare</strong> <strong>Earth</strong> <strong>Elements</strong> <strong>Review</strong> Section 5 – <strong>Rare</strong> <strong>Earth</strong> Element Recovery/Alternative Material Use<br />
A recent United Nations (UN) report on recycling rates <strong>of</strong> metals estimates that the end-<strong>of</strong>-life functional<br />
recycling (i.e., recycling in which the physical and chemical properties that made the material desirable in<br />
the first place are retained for subsequent use) for rare earths is less than 1 percent (UNEP, 2011).<br />
Another study estimates that world-wide, only 10 percent to 15 percent <strong>of</strong> personal electronics are being<br />
properly recycled (Dillow, 2011). Of the items that are sent<br />
for recycling, the European Union (EU) estimates that 50<br />
percent <strong>of</strong> the total is illegally exported, potentially ending<br />
up in unregulated recycling operations in Africa or Asia.<br />
These recycling operations frequently result in<br />
environmental damage and worker exposure, as documented<br />
in a separate UNEP report (Schluep et al., 2009) and<br />
discussed further in Section 6.<br />
The increasing prices <strong>of</strong> REEs (as well as other recyclable<br />
metals), along with the knowledge <strong>of</strong> the quantities available<br />
in discards and the increased worldwide demand, have led to<br />
the concept <strong>of</strong> “urban mining.” Urban mining is defined as<br />
the recovery <strong>of</strong> elements and compounds from waste<br />
materials and products. Consumer electronics are<br />
increasingly becoming subject to urban mining practices—<br />
and with over 6.5 million metric tons <strong>of</strong> personal computers,<br />
computer monitors and peripherals, televisions, and mobile<br />
“If the United States committed itself to<br />
meeting its critical materials needs in large<br />
part through recycling, there is no nation<br />
on earth that could match American<br />
resources. The United States has the<br />
largest "above-ground" mines <strong>of</strong> critical<br />
materials in the world, in the sense that<br />
this country's supply <strong>of</strong> industrial scrap and<br />
end-<strong>of</strong>-life automobiles, electronics, and<br />
electronic appliances - whether they are in<br />
wreckers' yards, land-fills, or Americans'<br />
basements and attics - can't be matched<br />
by any other nation. In essence, these<br />
"above-ground mines" make the United<br />
States the Saudi Arabia <strong>of</strong> critical<br />
materials. A well-developed recycling<br />
system could tap these mines for U.S.<br />
critical materials security without limit.”<br />
Waste Management World, 2011<br />
devices being generated in 2007 in the United States, Europe, China, and India—the supply available for<br />
“mining,” or recycling, is large and increasing (ICF International, 2011). A short introductory video on<br />
urban mining, with a focus on efforts in Japan, is available on the Internet<br />
(http://english.ntdtv.com/ntdtv_en/ns_<strong>of</strong>fbeat/2010-10-19/822469802087.html).<br />
Some small electronics such as cell phones reach their end <strong>of</strong> life after a few years, while many <strong>of</strong> the<br />
products that contain larger amounts <strong>of</strong> REEs have useful lives <strong>of</strong> well over one decade. The recycling <strong>of</strong><br />
the REEs contained within products will occur many years in the future and is not a short-term solution to<br />
the current demand. Another factor that will impact one <strong>of</strong> the recycling drivers is that as additional REE<br />
mines begin operation outside <strong>of</strong> China, global production will increase, costs may decrease, and the<br />
urgency behind the push to recycle may be reduced.<br />
5.2 Recycle <strong>Processing</strong> Steps<br />
The recycling process for post-consumer, end-<strong>of</strong>-life products typically involves four key steps, as<br />
illustrated by Figure 5-1: (1) collection; (2) dismantling; (3) separation (preprocessing); and<br />
(4) processing.<br />
As previously noted, a 2011 status report (UNEP, 2011) states that the end-<strong>of</strong>-life recycling rates, defined<br />
as the “percentage <strong>of</strong> a metal in discards that is actually recycled,” for REEs is less than 1 percent. As<br />
cited by Meyer and Bras (2011), the consumer products with the most rare earth recycling potential are<br />
the ones that contain high levels <strong>of</strong> rare earths and an established collection or recycling infrastructure,<br />
such as fluorescent lamps, magnets, car batteries, and catalytic converters. Three factors noted as<br />
contributing to the effectives <strong>of</strong> recycling efforts are the following (UNEP, 2011):<br />
1. Economics – The value <strong>of</strong> the materials to be recycled must be greater than the cost <strong>of</strong> recycling.<br />
In situations where this is not the case, laws and incentives can be effective in increasing<br />
recycling rates.<br />
5-3