Rare Earth Elements: A Review of Production, Processing ...
Rare Earth Elements: A Review of Production, Processing ...
Rare Earth Elements: A Review of Production, Processing ...
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<strong>Rare</strong> <strong>Earth</strong> <strong>Elements</strong> <strong>Review</strong> Section 3 – Life-Cycle Stages <strong>of</strong> <strong>Rare</strong> <strong>Earth</strong> <strong>Elements</strong> Mines<br />
building foundations, road beds, retaining structures, or other purposes. Many <strong>of</strong> these reuse strategies<br />
encapsulate waste-rock material, effectively separating it from atmospheric influence that would cause a<br />
release <strong>of</strong> toxic metals, acids, or alkaline waters to the environment.<br />
3.4.1 Soil Storage Piles<br />
The soils removed during the construction-mining stage <strong>of</strong> an aboveground mine site are typically placed<br />
in a storage pile and may be used during restoration at the end <strong>of</strong> the mine’s life. Soils are typically not<br />
considered wastes but can be a potential source <strong>of</strong> pollution if not properly managed, especially for<br />
providing a source <strong>of</strong> sediment in run<strong>of</strong>f. Humus-rich soils may be acidic, and fines that run <strong>of</strong>f to streams<br />
could affect surface water quality. Acidic soils used as cover for metal-bearing rock-waste areas could<br />
encourage metal leaching from the rock.<br />
3.4.2 Overburden<br />
Overburden storage piles <strong>of</strong> sediments and rock materials that do not contain the commodity can include<br />
other metals and constituents that may also be a source <strong>of</strong> pollution and contamination. While relatively<br />
small in comparison to quantities <strong>of</strong> other mining waste, overburden, which is the material removed to<br />
expose the ore during mining, may include unconsolidated materials such as alluvium, colluviums, glacial<br />
deposits, or residuum and be a source <strong>of</strong> sediment or acid-generating minerals; however, the acidity <strong>of</strong><br />
these materials is usually low and they generally do not contain significant concentrations <strong>of</strong> metals.<br />
Overburden usually does not include rock that contains the mineral ore, but it may include the very low<br />
mineralized rock removed from around the ore from hardrock mines. These materials can contain greater<br />
metal concentrations than typically associated with unconsolidated deposits. Without proper management,<br />
erosion <strong>of</strong> the overburden storage piles resulting in sediment loading to streams and surface water can<br />
occur. Ground water may be entrained with the overburden material, which can then leach through to the<br />
base <strong>of</strong> the pile, carrying with it high concentrations <strong>of</strong> metals and other potentially harmful constituents.<br />
Overburden piles can cover hundreds <strong>of</strong> acres and be a prominent feature in the general landscape as they<br />
reach heights extending hundreds <strong>of</strong> feet. Large mines may have multiple overburden storage piles. Large<br />
mine trucks and other vehicles deliver materials to the top <strong>of</strong> the pile and shape the slopes. Fugitive dusts<br />
are a concern from overburden storage piles.<br />
3.4.3 Ore and Subeconomic Ore Storage<br />
Ores may be stockpiled to provide a supply, lasting 6 months or more, <strong>of</strong> ore stock feed for beneficiation<br />
and processing plants. Subeconomic ore is <strong>of</strong>ten stockpiled at the mine site for future exploitation under<br />
the appropriate economic or market demand conditions. These ore stockpiles and subeconomic ore<br />
storage piles can include large areas. Mines may stage ores at multiple sites. Ore stockpiles can represent<br />
a significant source <strong>of</strong> toxic metals. Run<strong>of</strong>f, flooding, or infiltration <strong>of</strong> rainwater, if not captured and<br />
managed, can have significant effects on aquatic habitat. Ground water may be entrained with the ore<br />
material, which can then leach out to the base <strong>of</strong> the pile, carrying with it high concentrations <strong>of</strong> metals<br />
and other potentially harmful constituents. Large mine trucks and other vehicles deliver materials to the<br />
top <strong>of</strong> the pile and shape the slopes. Fugitive dusts containing metals or other harmful constituents from<br />
the ore and subeconomic ore stockpiles, even though not as much <strong>of</strong> a concern as tailings wastes or<br />
conveyances, may still be <strong>of</strong> potential concern depending upon the material stored.<br />
As previously discussed, AMD is uncommon in most REE deposits; however, some potential exists for<br />
low levels <strong>of</strong> acid generation from accessory minor sulfide minerals, especially in low-Ti iron oxide Cu-<br />
U-Au-REE deposits like Pea Ridge (Foose et al., 1995). Carbonatite ores, such as those at the Mountain<br />
Pass mine, may cause elevated pH in streams, depending on the concentration <strong>of</strong> other acid-producing<br />
accessory minerals in the ore-bearing rock and surrounding country rock that can serve to neutralize any<br />
run<strong>of</strong>f. Thorium-rare earth element veins have moderately high sulfur content, but the sulfur is present<br />
chiefly as sulfate in barite. Sulfide mineral content <strong>of</strong> these vein deposits is very low, thus potential for<br />
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