safety data sheet (pdf format) - Equip-Test

NECURON K2Safety Data Sheet1. Identification of the substance / preparation and ofthe company / undertakingProduct detailsTrade name:Manufacturer:Distributor:NECURON ® K2NECUMER-PRODUCT GmbHEQUIP-TEST COMPANYTel: +36-29/550-940www.equip-test.com2. Hazards identificationHazard description:Xn HarmfulInformation concerning particular hazards for human and environment:R 20 Harmful by inhalation.R 36/37/38 Irrigation to eyes, respiratory system and skin.R 42/43 May cause sensitisation by inhalation and skin contact.Contains isocyanates. See information supplied by the manufacturer.GHS label elementshealth hazard Danger3.4/1 - May cause allergy or asthma symptoms or breathing difficultiesif inhaled.3.2/2 - Causes skin irritation.3.3/2A - Causes serious eye irritation.3.4/1 - May cause an allergic skin reaction.exlamation mark Warning3.1/4 - Harmful if inhaled.3.8/3 - May cause respiratory irritation.Prevention:Avoid breathing dust/fume/gas/mist/vapours/spray.Wash thoroughly after handling.Use only outdoors or in a well-ventilated area.Contaminated work clothing should be allowe out of the workplace.Wear protective gloves/protective clothing/eye protection/face protection.In case of inadequate ventilation wear respiratory protection..Response:IF ON SKIN: Wash with plenty of soap and water.IF INHALED: Remove victim to fresh air and keep at rest in a positioncomfortable for breathing.IF INHALED: If breathing is difficult, remove victim to fresh air and keep at restin a position comfprtable for breathing.

NECURON K2Safety Data SheetIF IN EYES: Rinse cautiously with water for several minutes. Removes contactlenses, if present and easy to do. Continues rinsing.Call a POISON CENTER or doctor/physician if you feel unwell.Specific treatment (see in this label).If skin irritation occurs: Get medical advice/attention.If skin irritation or rash occurs: Get medical advice/attention.Id eye irritation persists: Get medical advice/attention.Id experiencing respiratory symptoms: Call a POISON CENTER ordoctor/physician.Take off contaminated clothing and wash before reuse.Wash contaminated clothing before reuse.Storage:Store in a well-ventilated place. Keep container tightly closed.Store locked up.Disposal:Dispose of contents/container in accordance withlocal/regional/national/international regulations.3. Composition/information on ingredientsChemical characterizationDangerous components:CAS NO. Description Index R-phrases %101-68-8 diphenylmethane-4-4'-diisocyanate 25-50%Xn, Xi; R 20-35/37/38-42/43Danger: health hazard 3.4.R/1, 3.2/2, 3.3/2A, 3.4.S/1Warning: exclamation mark 3.1.I/4, 3.8/34. First-aid measuresGeneralinformation:Symptoms of poisoning may even occur after several hours; therefore medicalobservation for at least 48 hours after the accident.After inhalation: supply fresh air and to be sure call for a doctor.After skin contact:Treat affected skin with cotton wool or cellulose. Then wash and rinsethoroughly with water and a mild cleaning agent.If skin irritation continues, consult a doctor.After eye contact: Rinse opened eye for several minutes under runningwater. Then consult a doctor.After swallowing: Do not induce vomiting; call for medical help immediately.

NECURON K2Safety Data Sheet5. Fire-fighting measuresSuitable extinguishing agents: Use fire extinguishing methods suitable tosutounding conditions.Special hazards caused by the substance, its products of combustionor resulting gases:In case of fire, the following can be released:IsocyanatesNitrogen oxidesTraces:Hydrogen cyanide (HCN)Protective equipment: Wear self-contained respiratory protective device.6. Accidental release measuresPerson-related safety precautions:Use respiratory protective device against the effects of fumes/dust/aerosol.Measures for environmental protection:Prevent seepage into sewage system, workpits and cellars.Do not allow to enter sewers/surface or ground water.Measures for cleaning/collecting:Absorb with liguid-bindign material (sand, diatomite, acid binders, universalbinders, sawdust).Disponse contaminated material as waste according to item 13.Ensure adequate ventilation.7. Handling and storageHandling:Information for safe handling: Ensure good ventilation/exhaustion at the workplace.Information about fire - and explosion protection: No special measures required.Storage:Requirements to be met by storerooms and receptacles:Keep container tightly closed.Further information about storeage conditions: Keep receptacle tightly sealed.8. Exposure controls/personal protectionAdditional information about design of technical facilities: No furtherdata; see item 7.

NECURON K2Safety Data SheetIngredients with limit values that require monitoring at the workplace:CAS No. Designation of material % Type Value Unit101-68-8 diphenylmethane-4,4'-diisocyanate3WEL (Great Britain) Short-term value: 0,07 mg/m3Long-term value: 0,02 mg/mSen; as -NCO3AWG (Germany)0,05 mg/m1;=2=(I); DFG, 11, 12, Sa3PEL (USA)Short-term value: C 0,2 mg/m , C 0,02 ppm3REL (USA)Short-term value: C 0,2* mg/m , C 0,02* ppm3Long-term value: 0,05 mg/m , 0,005 ppm*10-minTLV (USA)30,051 mg/m , 0,005 ppmAdditional information: The lists valid during the making were used as basis.Personal protective equipment:General protective and hygienic measures:Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothingWash hands before breaks and at the and of work.Avoid contact with the eyes and skin.Respiratory protection?Use suitable respiratory protective device only when aerosol or mist is formed.Filter A/P2 (EN 141)Protection of hands: Protective glovesMaterials of glovesButly rubber - BR (0.5 mm)Fluorocarbon rubber (Viton) - FCM (0.4 mm)Nitrile rubber - NBR (0.35 mm)Natural rubber - NR (0.5 mm)Chloroprene rubber - CR (0.5 mm)PVC gloves (0.5 mm)Eye protection: Tightly sealed goggles9. Physical and chemical propertiesGeneral InformationForm: FluidColour: Light yellowOdour: Weak, characteristicChange in conditionBoiling poitn/Boiling range: 208°CFlash point: 212°C

NECURON K2Safety Data SheetIgnition temperature: 520°CDanger of explosion: Product does not present an explosion hazard.Vapour pressure at 20°C:

NECURON K2Safety Data Sheetdisposal facility operator and the pertinent authories and adhering to thenecessary technical regulations.European waste catalogue08 04 09 waste adhesives and sealants contacting organic solvents or otherdangerous substances08 05 01 waste isocyanatesUncleaned packing:Recommendation:Empty contaminated packagings thoroughly. They may be recycled afterthorough and proper cleaning.14. Transport informationLand transport ADR/RID (cross-border)ADR/RID class: -Maritime transport IMDG:IMDG Class: No dangerous goodMarine pollutant: NoAir transport ICAO-TI and IATA-DGR:ICAO/IATA Class: No dangerous goodUN „Model Regulation“: -15. Regulatory informationLabelling according to EU guidelines:The product has been classified and marked in accordance with EU Directives/ Ordinance on Hazardous Materials.Code letter and hazard designation of product:Xn HarmfulHazar-determining components of labelling:diphenylmethane-4,4'-diisocyanateRisk phrases:20 Harmful by inhalation.36/37/38 Irritating to eyes, respiratory system and skin.42/43 May cause sensitisation by inhalation and skin contact.Safety phrases:2 Keep out of the reach of children.23 Do not breathe vapour/aerosol.36/37 Wear suitable protective cloting and gloves.45 In case of accident or if you feel unwell, seek medical advice immediately(show the label where possible).

NECURON K2Safety Data SheetSpecial labeling of certain preparations:Contains isocyanates. See information supplied by the manufacturer.National regulations:(D) Water hazr class: Water hazards class 1 (Self-assessment): slightlyhazardous for water.(EU) VOC - Volatile Organic Compounds (Directive 13/1999/EC)VOC - portion [mass-%]: 0 %16. Other informationThis information is based on our present knowledge. However, this shall not,constitute a guarantee for anyspecific product features and shall not establish a legally valid contractualrelationship.Relevant R-phrases20 Harmful by inhalation.36/37/38 Irritating to eyes, respiratory system ans skin.42/43 May cause sensitisation by inhalation and skin contact.Contact: GünterAbbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route(European Agreement concering the InternationalCarriage of Dangerous Goods by Road)RID: Réglement international conernant le transport des marchandises dangereusespar chemin de fer (Regulations Concerning theInternational Transport of Dangerous Goods by Rail)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationIATA-DGR: Dangerous Goods Regulations by the „International Air Transport Association“(IATA)ICAO: International Civil Aviation OrganizationICAO-TI: Technical Insturction by the „International Civil Aviation Organization“ (ICAO)GHS: Globally Harmonized System of Classification and Labelling of ChemicalsCAS: Chemical Abstracts Service (division of the American Chemical Society)MAL-Code: Måleteknisk Arbejdshygiejnisk Luftbehov (Regultaion for the labelingconcerning inhalation hazards, Denmark)