JP-K67 - Hitachi America, Ltd.

M A T E R I A L S A F E T Y D A T A S H E E TJ P - K 6 7 u P r i n t i n g I n kT H I S M A T E R I A L S A F E T Y D A T A S H E E T C O N F O R M S T O T H E R E Q U I R E M E N T S O F A N S I Z 4 0 0 . 1 .T H I S M S D S C O M P L I E S W I T H 2 9 C F R 1 9 1 0 . 1 2 0 0 ( O S H A H A Z A R D C O M M U N I C A T I O N S T A N D A R D ) .I M P O R T A N T : R E A D T H I S M S D S B E F O R E H A N D L I N G O R D I S P O S I N G O F T H I S P R O D U C T .SECTION I – PRODUCT & COMPANY IDENTIFICATIONMANUFACTURER / DISTRIBUTORPRODUCT NAMEMATERIAL USESPRODUCT CODEHitachi America, Ltd50 Prospect AvenueTarrytown, NY 10591JP-K67 u Printing InkIndustrial coding applications; Ink Jet PrintersN/ANON-EMERGENCY PHONE 914-524-6685EMERGENCY PHONE CHEMTREC (800) 424-9300SECTION II – COMPOSITION / INFORMATION ON INGREDIENTSINGREDIENTCAS#PERCENT RANGE(%)2-Butanone 78-93-3 55-65Methanol 67-56-1 10-20Chrome III -Complex Dye 72812-34-1 5-10SECTION III - HAZARDS IDENTIFICATIONHAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS)HEALTH 2 FLAMMABILITY 3 REACTIVITY 0PERSONALPROTECTIONBNOTICE: THESE RATINGS ARE FOR GENERAL RAPID INTERPRETATION. THE END-USER IS RESPONSIBLE FOR DETERMINING THE PROPER PROTECTIVE PROCEDURES.EMERGENCYOVERVIEWWarning! Flammable Liquid and Vapor. Skin, Eye and Mucous Membrane Irritant. Do not use near fire or flame. May be fatal or causeblindness if swallowed. Avoid contact with skin, eyes and mucous membranes. If skin contact occurs, wash skin with mild soap and water. Ifsplashed in eyes, flush with water. If inhaled, remove to fresh air. In medical emergency contact Poison Control Center (USA 800.222.1222).Read MSDS before using.F - Highly FlammableT - ToxicSECTION IV - FIRST AID MEASURESRISK STATEMENTSR11 Highly FlammableR23/24/25 Toxic by inhalation, in contact with skin and if swallowedR36 Irritating to eyes, respiratory system and skinR66 Inhalation of vapors can provoke sleepiness and dizzinessSAFETY STATEMENTSS2 Keep away from children.S7 Keep container tightly closedS16 Keep away from sources of ignition - No Smoking!S25 Avoid contact with eyesS36/37 Wear suitable protective clothing and glovesS45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)ORAL INGESTIONEYE CONTACTSKIN CONTACTINHALATIONDo not induce vomiting unless directed to do so by medical personnel. Seek immediate medical attention.Flush with water for 15 minutes and seek medical attention.Wash with soap and water. Wash contaminated clothing before reuse. Seek immediate medical attention.Remove to fresh air, if not breathing, give artificial respiration and seek medical attention.SECTION V - FIREFIGHTING MEASURESEXTINGUISHING MEDIAAlcohol Resistant foam or dry chemicalPage 1 of 4

HAZARDOUS COMBUSTIONPRODUCTSFIRE FIGHTING PROCEDURESCarbon Monoxide, Carbon DioxideWear self-contained breathing apparatus with fullfacepiece operated in the positive pressure demand mode.SECTION VI - ACCIDENTAL RELEASE MEASURESKeep away all sources of ignition from spill. If spill is indoors, ventilate areas of spill and soak up the spill with absorbent material. Do not let spilled or leakingmaterial enter watercourse.SECTION VII - HANDLING AND STORAGEHANDLINGSTORAGEAvoid contact with eyes. Wash hands thoroughly with soap and water after handling. Utilize proper grounding with containers of material.Protect from freezing. Overheating may cause container to rupture. Covered storage in a cool, dry place out of direct sunlight ispreferable. Keep container tightly sealed until ready for use. Store away from ignition sources.SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTIONRESPIRATORY PROTECTIONVENTILATIONPROTECTIVE GLOVESEYE PROTECTIONOTHER PROTECTIVEEQUIPMENTOCCUPATIONAL EXPOSURE LIMITS:If workplace exposure limit(s) of product or any other component is exceeded, a NIOSH/OSHA approved respirator is advised. (Seeyour safety equipment supplier for specific details.)Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below PEL/ TLV.Wear chemical resistant gloves. (Consult your safety equipment supplier.)Wear chemical splash goggles in compliance with OSHA regulations. However, OSHA regulations also permit other types of safetyglasses.Wear impervious clothing and boots to prevent prolonged exposure.INGREDIENT ACGIH TLV* OSHA PEL*2-Butanone 200ppm 200ppmMethanol 200ppm 200ppmChrome (III) – Complex Dye Not established Not establishedSECTION IX - PHYSICAL & CHEMICAL PROPERTIESSECTION X - STABILITY & REACIVITYPHYSICAL STATELiquidCOLORBlackODORSolvent odorBOILING RANGE64 - 80º CMELTING RANGENo measurementSPECIFIC GRAVITY (WATER=1) 0.9 (20º C)DENSITY (lbs / gal) 7.4EVAPORATION RATE (N-BUTYL ACETATE=1) -----PERCENT VOLATILE BY VOLUME (%) 81%VAPOR PRESSURE < 9.4kPa (20º C)VAPOR DENSITY (AIR=1)Greater than airFLASH POINT (TCC)-7.0º C (closed cup)AUTO IGNITION TEMPERATURE> 470º CUPPER FLAMMABLE LIMIT (%BY VOL.) 11.5%LOWER FLAMMABLE LIMIT (%BY VOL.) 1.8%,SOLUBILITY IN WATERMiscibleSOLUBILITY IN ORGANIC SOLVENTSMisciblePHNot ApplicableCONDITION OF INSTABILITYCONDITIONS OF REACTIVITYINCOMPATIBILITYHAZARDOUS DECOMPOSITION PRODUCTSEXPLOSION DATA (SENSITIVE TO MECHANICAL IMPACT)EXPLOSION DATA (SENSITIVE TO STATIC DISCHARGE)None KnownNot applicableStrong oxidizing agentsCarbon Monoxide, Carbon DioxideNoYesPage 2 of 4

SECTION XI - TOXICOLOGICAL INFORMATIONINGREDIENTTOXICOLOGICAL INFORMATION**2-Butanone Eye contact (human) 350ppmSkin contact (rabbit) 500mg/24hInhalation TCL0 (human) 100ppm/5minInhalation LCL0 (rat) 2000ppm/4hOral LD50 (rat) 4050mg/kgMethanol Oral LDL0 (human) 340mg/kgLDL0 (mouse) 420mg/kgLDL0 (dog)6300mg/kgLDL0 (monkey) 7000mg/kgLDL0 (rabbit) 4750mg/kgTDL0 (human) 100mg/kgInhalation LC50 (monkey) 1000ppmTCL0 (human) 300ppmSECTION XII - ECOLOGICAL INFORMATIONECOTOXICITYNot AvailableNot AvailableConcentration of lead, mercury, cadmium andhexavalent chromium [Cr(VI)] < 1000ppmNo other ecological information is available for this product.PERSISTANCE / DEGRADABILITYHEAVY METALSSECTION XIII - DISPOSAL CONSIDERATIONSAbsorb in vermiculite, floor absorbent or other non-combustible absorbent material and dispose in licensed facility.regulations.SECTION XIV - TRANSPORT INFORMATIONObserve all federal, state and localSECTION XV - REGULATORY INFORMATIONDOT / TDG UN NUMBER & PROPER SHIPPING NAME UN1210 PRINTING INKDOT / TDG HAZARD CLASS 3DOT / TDG LABELPACKING GROUPFLAMMABLE LIQUIDEMERGENCY RESPONSE GUIDEBOOK NUMBER 129TSCAAll chemicals used are listed on the TSCA Inventory.CERCLAThis material does not meet the definition of a reportable quantity in packages shipped.SARA 313 The following product(s) is (are) listed on SARA 313:2-ButanoneMethanolIICalifornia Prop 65InternationalRegulationsThis product contains the following ingredients that the State of California has found to cause cancer, birth defects,or other reproductive harm, which requires a warning under the statute:NONEThe components of this product are listed on the chemical inventories of the following countries:Australia, Canada, Europe (EINECS), Japan, Korea, United KingdomSECTION XVI - OTHER INFORMATIONISSUE DATE 10/2012REVISION NUMBER 0SUPERCEDES ----Page 3 of 4

PREPARED BYGaran MyersProduct SpecialistDISCLAIMEREvery effort has been made to ensure that the information in this MSDS is accurate and as complete as reasonably possible and of course alldata herein are given in good faith. However, all information is furnished without warranty of any kind, and Hitachi America, Ltd. expresslynegates any warranty of accuracy, expressed or implied; and Hitachi America, Ltd. assumes no responsibility for personal injury or damage toproperty to customers, vendors, or third parties if any information herein proves to be incorrect in any respect. Purchasers are encouraged tomake independent determination of suitability and completeness of information from all sources to assure proper use and compatibility ofproduct.*NIOSH Publication #94-116**Sax’s Dangerous Properties of Industrial Mtls. 10th Ed.Page 4 of 4