Medical Aspects of Chemical Warfare (2008) - The Black Vault

Medical Aspects of Chemical Warfare (2008) - The Black Vault Medical Aspects of Chemical Warfare (2008) - The Black Vault

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History of the Chemical Threatgate summaries and fails to inform both the public andstates parties of the extent of noncompliance. 105Krutzch went on to explain inspection and verificationas described to be unduly influenced through thestate parties’ control of the budget, greatly limiting theability of the technical secretariat to prioritize its missionactivities. By defining, in the budget, the numberof inspections to be held in each schedule category,the technical secretariat had to revisit a schedule 1 siteof minimal concern six times, while large numbers ofchemical production facilities were disproportionallyuninspected. 105Progress Made Toward ComplianceUnless a nation declares its own state of progress inimplementing the CWC, any effort to compile a listingof progress by state party is incomplete because theOPCW generally reports only numbers in aggregateform. Many nations, including smaller ones such asAlbania, have or had modest stockpiles and may dependon foreign assistance for their elimination. 106 TheOPCW scorecard shows the United States and RussianFederation declared an overall total of 64,260 metrictons of agent. The remaining 167 declarations total anadditional 7,055 metric tons of agent 99 (Table 4-6).Chemical DemilitarizationThe CWC does not specify how chemicals are tobe destroyed. 107 It provides language requiring thatdestruction be completed in a safe manner and in compliancewith a state party’s environmental regulations.Both incineration and various chemical eliminationmethods are employed. The CWC requires eliminationof the offending chemical; as long as the reaction productsare not CWC scheduled compounds, the agent isconsidered destroyed. Demilitarization is generally amultistep process. VX nerve agent hydrolysis, for example,yields a mixture of schedule 2 products basednot on toxicity but on the presence of residual phosphonatealkyl groups. Hence this product is subsequentlysubjected to further oxidation or biodegradation. ARussian plan incorporated the unwanted products intoasphalt. Concrete embedding can also be used.US ProgramTable 4-6Chemical Weapons ConventionProgress, FEBRUARY 2008Total weight of declared chemicalagentsTotal number of declared munitions/containersTotal destroyed agentTotal destroyed munitions/containersCWPFs certified as destroyed~ 71,315 metrictons~ 8,679,000 items~ 27,199 metrictons (38%)~ 2,930,000 items(34%)42 of 65 declaredCWPFs certified as converted 19Number of states parties (as of December2007)183Initial declarations received 169Implementing legislation submitted79enacted in all key areasCWPF: chemical weapons production facilityData source: Organisation for the Prohibition of Chemical WeaponsWeb site. Accessed: May 16, 2008. Available at: www.opcw.org/index.html.The Army has been responsible for destroyingleaking or obsolete chemical weapons since it begandeveloping them. In October 1972 Army Materiel Commandheadquarters formalized the mission throughthe creation of a Program Manager for Demilitarizationof Chemical Materiel, headed by Colonel SampsonBass. This office was to plan, direct, and controlthe chemical demilitarization program, includingthe design, development, and acquisition of specialequipment and facilities. Its initial projects includedaddressing leaking munitions and bulk agent at thenine chemical weapons stockpile sites and DugwayProving Ground, Utah, in addition to chemical remediationefforts at Rocky Mountain Arsenal, Colorado,and finishing biological warfare agent disposal effortsat Fort Detrick, Maryland. Between 1969 and 1985 theArmy destroyed nearly 15 million lb of chemical agentsthrough neutralization and incineration technologiesat Rocky Mountain Arsenal alone.The duties and scope of disposal operations eventuallyprompted Army leadership to propose that aformal agency take responsibility for chemical demilitarization,which had grown to include developingdisposal technologies, building permanent facilities,coordinating with interagency government offices,and running disposal operations. The US Army Toxicand Hazardous Materials Agency began operationsin 1978. One of its first major efforts was to build theUS Army Chemical Agent Materiel Disposal Systemat Tooele Army Depot, Utah, as a test facility to developproven industrial and military processes andequipment and to demonstrate their applicability tolarge-scale demilitarization facilities. The test facility141

Medical Aspects of Chemical Warfarewas the primary tool for evaluating technologies andprocesses to destroy chemical munitions and agentsbetween 1979 and 1986. Based on extensive testing andevaluation, the Army decided that a reverse-assemblyapproach to disassembling the munitions, followed byincineration and treatment of off-gases by a pollutionabatement system, should be used for constructing apilot disposal facility at Johnston Island in the PacificOcean.In the 1980s Congress tied the binary program tothe chemical demilitarization program by languagethat directed the Army to destroy an equal amountof unitary weapons as they built the new binaryweapons. 108 In 1985 Congress authorized the Army toexecute the binary weapons production with a numberof constraints, one of them being the elimination of theexisting chemical agents and munitions by September1994. This language also authorized the creation of anew Army management organization, headed by ageneral officer, to execute the disposal mission. 30,38 Asa result, the Army’s Program Manager for ChemicalMunitions (Demilitarization and Binary) was establishedat Aberdeen Proving Ground on May 1, 1986.In 1987 the binary munitions project split off, and in1988, the office was renamed the “Program Managerfor Chemical Demilitarization.”The US Army Chemical Materials Agency, whichassumed the responsibilities of the Program Managerfor Chemical Demilitarization in 2003, employsmanual and robotic technologies to carry out eitherhigh-temperature incineration or chemical elimination.Several of the agency’s facilities use high-temperatureincineration for agent, explosive, and propellantcomponents. Prototype studies were conducted atJohnston Island (1990–1993), and the technology wasthen transferred to the Tooele, Utah, facility, whichcommenced operation in 1996. Public unease withincinerator-based technologies resulted in the creationof the Assembled Chemical Weapons AlternativesProgram in 1997. Under this DoD program, the PuebloChemical Depot in Colorado will neutralize HD withhot water followed by bacterial elimination of the products.At the Bluegrass Army Depot in Kentucky, agentwill be hydrolyzed and the hydrolysate subjected tofundamental decomposition under high temperatureand pressure. The Newport Army Depot in Indianabecame fully operational in 2005, hydrolyzing its nerveagent stocks.Nonchemical weapons are typically rendered inoperablethrough mechanical means such as crushing,sawing, or detonation. Contaminated materials areincinerated or chemically decontaminated. The UnitedStates has also developed a portable, flatbed-mountedexplosive destruction system to destroy old, unstablechemical warfare munitions.From a medical perspective, the chemical demilitarizationprogram upholds occupational safety standardsenacted to protect workers and maintains publichealth measures to protect citizens. Both the EnvironmentalProtection Agency (EPA) and the Centers forDisease Control and Prevention (CDC) worked withthe Army surgeon general and the Army Center forHealth Promotion and Preventive Medicine to developworker and public health standards in line with similarOccupational Safety and Health Administration andNational Institute of Occupational Safety and Healthguidance for working with hazardous materials.For personnel working at the stockpile sites anddisposal facilities, the CDC promulgated airborneexposure levels as occupational safety standards forvarious timeframes and purposes. These include thefollowing limits:• Immediately dangerous to life or health: themaximum exposure concentration at whichone could escape within 30 minutes withoutany escape-impairing symptoms or permanentadverse health effects.• Short-term exposure limit: the maximumconcentration at which unprotected chemicalworkers may be exposed for up to 15 minutes.• Worker population limit: the maximum allowableconcentration at which unprotectedchemical workers may be exposed for an8-hour workday and 40-hour workweek over30 years.• General population limit: the maximumconcentration at which the general populationmay be exposed continuously, based onexposure 24 hour per day, 7 days per week,over a 70-year lifetime. 109In addition to protecting civilians and militaryemployees on post, the Army’s chemical demilitarizationprogram supports the development and implementationof medical emergency response protocolsfor any chemical accidents or incidents that involvean off-post exposure hazard. The Chemical StockpileEmergency Preparedness Program, established in1988, has funded both on-post and off-post efforts toensure that state and local emergency responders canreact to chemical accidents or incidents, protecting thepublic living around the stockpile sites. The medicalagencies at those sites work to prepare emergencymedical technicians and hospitals to receive and treatpotentially exposed civilians by providing advice onthe procurement of personal protective equipment,142

<strong>Medical</strong> <strong>Aspects</strong> <strong>of</strong> <strong>Chemical</strong> <strong>Warfare</strong>was the primary tool for evaluating technologies andprocesses to destroy chemical munitions and agentsbetween 1979 and 1986. Based on extensive testing andevaluation, the Army decided that a reverse-assemblyapproach to disassembling the munitions, followed byincineration and treatment <strong>of</strong> <strong>of</strong>f-gases by a pollutionabatement system, should be used for constructing apilot disposal facility at Johnston Island in the PacificOcean.In the 1980s Congress tied the binary program tothe chemical demilitarization program by languagethat directed the Army to destroy an equal amount<strong>of</strong> unitary weapons as they built the new binaryweapons. 108 In 1985 Congress authorized the Army toexecute the binary weapons production with a number<strong>of</strong> constraints, one <strong>of</strong> them being the elimination <strong>of</strong> theexisting chemical agents and munitions by September1994. This language also authorized the creation <strong>of</strong> anew Army management organization, headed by ageneral <strong>of</strong>ficer, to execute the disposal mission. 30,38 Asa result, the Army’s Program Manager for <strong>Chemical</strong>Munitions (Demilitarization and Binary) was establishedat Aberdeen Proving Ground on May 1, 1986.In 1987 the binary munitions project split <strong>of</strong>f, and in1988, the <strong>of</strong>fice was renamed the “Program Managerfor <strong>Chemical</strong> Demilitarization.”<strong>The</strong> US Army <strong>Chemical</strong> Materials Agency, whichassumed the responsibilities <strong>of</strong> the Program Managerfor <strong>Chemical</strong> Demilitarization in 2003, employsmanual and robotic technologies to carry out eitherhigh-temperature incineration or chemical elimination.Several <strong>of</strong> the agency’s facilities use high-temperatureincineration for agent, explosive, and propellantcomponents. Prototype studies were conducted atJohnston Island (1990–1993), and the technology wasthen transferred to the Tooele, Utah, facility, whichcommenced operation in 1996. Public unease withincinerator-based technologies resulted in the creation<strong>of</strong> the Assembled <strong>Chemical</strong> Weapons AlternativesProgram in 1997. Under this DoD program, the Pueblo<strong>Chemical</strong> Depot in Colorado will neutralize HD withhot water followed by bacterial elimination <strong>of</strong> the products.At the Bluegrass Army Depot in Kentucky, agentwill be hydrolyzed and the hydrolysate subjected t<strong>of</strong>undamental decomposition under high temperatureand pressure. <strong>The</strong> Newport Army Depot in Indianabecame fully operational in 2005, hydrolyzing its nerveagent stocks.Nonchemical weapons are typically rendered inoperablethrough mechanical means such as crushing,sawing, or detonation. Contaminated materials areincinerated or chemically decontaminated. <strong>The</strong> UnitedStates has also developed a portable, flatbed-mountedexplosive destruction system to destroy old, unstablechemical warfare munitions.From a medical perspective, the chemical demilitarizationprogram upholds occupational safety standardsenacted to protect workers and maintains publichealth measures to protect citizens. Both the EnvironmentalProtection Agency (EPA) and the Centers forDisease Control and Prevention (CDC) worked withthe Army surgeon general and the Army Center forHealth Promotion and Preventive Medicine to developworker and public health standards in line with similarOccupational Safety and Health Administration andNational Institute <strong>of</strong> Occupational Safety and Healthguidance for working with hazardous materials.For personnel working at the stockpile sites anddisposal facilities, the CDC promulgated airborneexposure levels as occupational safety standards forvarious timeframes and purposes. <strong>The</strong>se include thefollowing limits:• Immediately dangerous to life or health: themaximum exposure concentration at whichone could escape within 30 minutes withoutany escape-impairing symptoms or permanentadverse health effects.• Short-term exposure limit: the maximumconcentration at which unprotected chemicalworkers may be exposed for up to 15 minutes.• Worker population limit: the maximum allowableconcentration at which unprotectedchemical workers may be exposed for an8-hour workday and 40-hour workweek over30 years.• General population limit: the maximumconcentration at which the general populationmay be exposed continuously, based onexposure 24 hour per day, 7 days per week,over a 70-year lifetime. 109In addition to protecting civilians and militaryemployees on post, the Army’s chemical demilitarizationprogram supports the development and implementation<strong>of</strong> medical emergency response protocolsfor any chemical accidents or incidents that involvean <strong>of</strong>f-post exposure hazard. <strong>The</strong> <strong>Chemical</strong> StockpileEmergency Preparedness Program, established in1988, has funded both on-post and <strong>of</strong>f-post efforts toensure that state and local emergency responders canreact to chemical accidents or incidents, protecting thepublic living around the stockpile sites. <strong>The</strong> medicalagencies at those sites work to prepare emergencymedical technicians and hospitals to receive and treatpotentially exposed civilians by providing advice onthe procurement <strong>of</strong> personal protective equipment,142

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