Problems 9335. Is it possible for a spectrum from an x-ray tube toshow the continuous spectrum of x-rays without thepresence of the characteristic x-rays?6. Suppose that the electron in the hydrogen atomobeyed classical mechanics rather than quantummechanics. Why should such a hypothetical atomemit a continuous spectrum rather than the observedline spectrum?7. When a hologram is produced, the system (includinglight source, object, beam splitter, and so on)must be held motionless within a quarter of thelight’s wavelength. Why?8. If matter has a wave nature, why is it not observablein our daily experience?9. Discuss some consequences of the exclusion principle.10. Can the electron in the ground state of hydrogenabsorb a photon of energy less than 13.6 eV? Can itabsorb a photon of energy greater than 13.6 eV?Explain.11. Why do lithium, potassium, and sodium exhibit similarchemical properties?12. List some ways in which quantum mechanics alteredour view of the atom pictured by the Bohr theory.13. It is easy to understand how two electrons (one withspin up, one with spin down) can fill the 1s shell for ahelium atom. How is it possible that eight more electronscan fit into the 2s, 2p level to complete the1s2s 2 2p 6 shell for a neon atom?14. The ionization energies for Li, Na, K, Rb, and Csare 5.390, 5.138, 4.339, 4.176, and 3.893 eV, respectively.Explain why these values are to be expectedin terms of the atomic structures.15. Why is stimulated emission so important in the operationof a laser?16. The Bohr theory of the hydrogen atom is basedupon several assumptions. Discuss these assumptionsand their significance. Do any of them contradictclassical physics?17. Explain why, in the Bohr model, the total energy ofthe hydrogen atom is negative.18. Consider the quantum numbers n, , m , and m s .(a) Which of these are integers and which are fractional?(b) Which are always positive and which canbe negative? (c) If n 2, what is the largest value of? (d) If 1, what are the possible values of m ?19. Photon A is emitted when an electron in a hydrogenatom drops from the n 3 level to the n 2 level.Photon B is emitted when an electron in a hydrogenatom drops from the n 4 level to the n 2 level.(a) In which case is the wavelength of the emittedphoton greater? (b) In which case is the energy ofthe emitted photon greater?PROBLEMS1, 2, 3 = straightforward, intermediate, challenging = full solution available in Student Solutions Manual/Study Guide= coached problem with hints available at www.cp7e.com = biomedical applicationSection 28.1 Early Models of the AtomSection 28.2 Atomic Spectra1. Use Equation 28.1 to calculate the wavelengthof the first three lines in the Balmer series for hydrogen.2. Show that the wavelengths for the Balmer series satisfythe equation 364.5n2n 2 4 nmwhere n 3, 4, 5, . . .3. The “size” of the atom in Rutherford’s model isabout 1.0 10 10 m. (a) Determine the attractiveelectrostatic force between an electron and a protonseparated by this distance. (b) Determine (in eV)the electrostatic potential energy of the atom.4. The “size” of the nucleus in Rutherford’s model ofthe atom is about 1.0 fm 1.0 10 15 m. (a) Determinethe repulsive electrostatic force betweentwo protons separated by this distance. (b) Determine(in MeV) the electrostatic potential energyof the pair of protons.5.The “size” of the atom in Rutherford’smodel is about 1.0 10 10 m. (a) Determinethe speed of an electron moving about the protonusing the attractive electrostatic force between anelectron and a proton separated by this distance.(b) Does this speed suggest that Einsteinian relativitymust be considered in studying the atom?(c) Compute the de Broglie wavelength of the electronas it moves about the proton. (d) Does thiswavelength suggest that wave effects, such as diffractionand interference, must be considered in studyingthe atom?
934 Chapter 28 Atomic <strong>Physics</strong>6. In a Rutherford scattering experiment, an -particle(charge 2e) heads directly toward a goldnucleus (charge 79e). The -particle had a kineticenergy of 5.0 MeV when very far ( r : )from the nucleus. Assuming the gold nucleus tobe fixed in space, determine the distance of closestapproach. [Hint: Use conservation of energywith PE k e q 1 q 2 /r.]Section 28.3 The Bohr Theory of Hydrogen7. A hydrogen atom is in its first excited state (n 2).Using the Bohr theory of the atom, calculate (a) theradius of the orbit, (b) the linear momentum of theelectron, (c) the angular momentum of the electron,(d) the kinetic energy, (e) the potential energy,and (f ) the total energy.8. For a hydrogen atom in its ground state, use theBohr model to compute (a) the orbital speed of theelectron, (b) the kinetic energy of the electron, and(c) the electrical potential energy of the atom.9. Show that the speed of the electron in the nth Bohrorbit in hydrogen is given byv n k ee 2n10. A photon is emitted as a hydrogen atom undergoesa transition from the n 6 state to the n 2 state.Calculate (a) the energy, (b) the wavelength, and(c) the frequency of the emitted photon.11. A hydrogen atom emits a photon of wavelength656 nm. From what energy orbit to what lower energyorbit did the electron jump?12. Following are four possible transitions for a hydrogenatomI. n i 2; n f 5 II. n i 5; n f 3III. n i 7; n f 4 IV. n i 4; n f 7(a) Which transition will emit the shortest-wavelengthphoton? (b) For which transition will theatom gain the most energy? (c) For which transition(s)does the atom lose energy?13. What is the energy of a photon that, when absorbedby a hydrogen atom, could cause (a) an electronictransition from the n 3 state to the n 5 stateand (b) an electronic transition from the n 5state to the n 7 state?14. A hydrogen atom initially in its ground state (n 1) absorbs a photon and ends up in the state forwhich n 3. (a) What is the energy of the absorbedphoton? (b) If the atom eventually returnsto the ground state, what photon energies couldthe atom emit?15. Determine both the longest and the shortest wavelengthsin (a) the Lyman series (n f 1) and (b) thePaschen series (n f 3) of hydrogen.16. Show that the speed of the electron in the first(ground-state) Bohr orbit of the hydrogen atom maybe expressed asv (1/137)c.17. A monochromatic beam of light is absorbed by acollection of ground-state hydrogen atoms in such away that six different wavelengths are observedwhen the hydrogen relaxes back to the groundstate. What is the wavelength of the incident beam?18. A particle of charge q and mass m, moving with aconstant speed v, perpendicular to a constant magneticfield, B, follows a circular path. If in this casethe angular momentum about the center of this circleis quantized so that mvr 2n,show that the allowedradii for the particle arer n √2 nqBwhere n 1, 2, 3, . . .19.(a) If an electron makes a transitionfrom the n 4 Bohr orbit to the n 2 orbit,determine the wavelength of the photon created inthe process. (b) Assuming that the atom was initiallyat rest, determine the recoil speed of the hydrogenatom when this photon is emitted.20. Consider a large number of hydrogen atoms, withelectrons all initially in the n 4 state. (a) Howmany different wavelengths would be observed inthe emission spectrum of these atoms? (b) What isthe longest wavelength that could be observed? Towhich series does it belong?21. Analyze the Earth–Sun system by following the Bohrmodel, where the gravitational force between Earth(mass m) and Sun (mass M) replaces the Coulombforce between the electron and proton (so that F GMm/r 2 and PE GMm/r). Show that (a) the totalenergy of the Earth in an orbit of radius r is givenby (a) E GMm/2r, (b) the radius of the nth orbitis given by r n r 0 n 2 , where r 0 2 /GMm 2 2.32 10 138 m, and (c) the energy of the nth orbit is givenby E n E 0 /n 2 , where E 0 G 2 M 2 m 3 /2 2 1.71 10 182 J. (d) Using the Earth–Sun orbit radius ofr 1.49 10 11 m, determine the value of the quan-
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876 Chapter 27 Quantum PhysicsSolve
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30.9 Conservation Laws 989LeptonsLe
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30.12 Quarks 993n pΣ _ Σ 0 Σ + S
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Problems 1005particles fuse to prod
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A.1 MATHEMATICAL NOTATIONMany mathe
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A.3 Algebra A.3by 8, we have8x8 32
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APPENDIX BAn Abbreviated Table of I
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An Abbreviated Table of Isotopes A.
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Some Useful Tables A.15TABLE C.3The
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IndexPage numbers followed by “f
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Current, 568-573, 586direction of,
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Index I.5Fissionnuclear, 973-976, 9
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South poleEarth’s geographic, 626
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CreditsPhotographsThis page constit
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PHYSICAL CONSTANTSQuantity Symbol V