Foraperle 225 - MSDS - DuPont

Material Safety Data SheetForaperle ® 225Version 2.1Revision Date 01/17/2012 Ref. 130000005008This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatoryrequirements in other countries.SECTION 1. PRODUCT AND COMPANY IDENTIFICATIONProduct name : Foraperle ® 225MSDS Number : 130000005008Product Use : Leather finishing, Stain and soil repellentManufacturer : DuPont1007 Market StreetWilmington, DE 19898Product Information : 1-800-441-7515 (outside the U.S. 1-302-774-1000)Medical Emergency : 1-800-441-3637 (outside the U.S. 1-302-774-1139)Transport Emergency : CHEMTREC: 1-800-424-9300 (outside the U.S. 1-703-527-3887)Other information : professional useSECTION 2. HAZARDS IDENTIFICATIONEmergency OverviewInhalation of decomposition products in high concentration may cause shortness of breath (lung oedema).Inhalation of aerosol or fine spray mist may cause serious respiratory problems.Potential Health EffectsSkin : May cause skin irritation. May cause:, Discomfort, itching, redness, orswelling..Eyes : May cause eye irritation. May cause:, tearing, Redness, Discomfort.Inhalation : Inhalation of decomposition products in high concentration may causeshortness of breath (lung oedema). Inhalation of aerosol or fine spray mistmay cause serious respiratory problems.Ingestion : May cause: narcosis1 / 9

Material Safety Data SheetForaperle ® 225Version 2.1Revision Date 01/17/2012 Ref. 130000005008Repeated exposure : Adverse effects from repeated ingestion may include:, Kidney effects,Adverse effects from repeated inhalation may include:, Respiratory tractirritation, Liver effectsTarget Organs : Liver, Kidney, Respiratory Tract, Stomach, Central nervous systemCarcinogenicityNone of the components present in this material at concentrations equal to or greater than 0.1% are listed byIARC, NTP, or OSHA, as a carcinogen.SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTSComponent CAS-No. Concentrationn-Butyl acetate 123-86-4 70 - 80 %Partially Fluorinated Acrylic Copolymer 20 - 30 %SECTION 4. FIRST AID MEASURESSkin contact: Wash off immediately with soap and plenty of water while removing allcontaminated clothes and shoes.Eye contactInhalationIngestionGeneral advice: Immediately flush eyes for at least 15 minutes. Get medical attention.: Move to fresh air. Oxygen or artificial respiration if needed. Symptoms may bedelayed. Call a physician immediately.: Call a physician or poison control centre immediately. If swallowed, DO NOTinduce vomiting unless directed to do so by medical personnel. Never giveanything by mouth to an unconscious person.: When symptoms persist or in all cases of doubt seek medical advice.2 / 9

Material Safety Data SheetForaperle ® 225Version 2.1Revision Date 01/17/2012 Ref. 130000005008SECTION 5. FIREFIGHTING MEASURESFlammable PropertiesFlash point: 28 °C (82 °F) closed cupLower explosion limitUpper explosion limitFire and Explosion HazardSuitable extinguishing mediaFirefighting Instructions: 1.7 vol%: 7.6 vol%: Flammable liquidHazardous decomposition products formed under fire conditions. Hazardouscombustion products Hydrogen fluoride Carbon dioxide (CO2) Carbonmonoxide Other hazardous decomposition products may be formed.: Foam, Dry chemical, Carbon dioxide (CO2): Wear self contained breathing apparatus for fire fighting if necessary.Evacuate personnel to safe areas. Cool containers / tanks with water spray.Do not allow run-off from fire fighting to enter drains or water courses.SECTION 6. ACCIDENTAL RELEASE MEASURESNOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with cleanup.Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up.Safeguards (Personnel)Spill CleanupAccidental Release Measures: Evacuate personnel to safe areas. Use personal protective equipment.Ventilate the area.: Remove all sources of ignition. Use only non-sparking tools. Dam up. Soakup with inert absorbent material (e.g. sand, silica gel, acid binder, universalbinder, sawdust). Pick up and transfer to properly labelled containers.: Do not discharge to streams, ponds, lakes or sewers. Avoid subsoilpenetration.SECTION 7. HANDLING AND STORAGE3 / 9

Material Safety Data SheetForaperle ® 225Version 2.1Revision Date 01/17/2012 Ref. 130000005008Handling (Personnel)Handling (Physical Aspects)Storage: Do not use sparking tools. Ground containers when transferring material.Avoid formation of respirable particles. Do not breathe vapours or spray mist.Avoid contact with skin, eyes and clothing.Wash hands before breaks and immediately after handling the product. Washcontaminated clothing before re-use.: Vapours may form explosive mixtures with air. Keep away from open flames,hot surfaces and sources of ignition. To avoid thermal decomposition, do notoverheat. Thermal decomposition can lead to release of irritating gases andvapours.: Keep containers tightly closed in a dry, cool and well-ventilated place.Store in accordance with National Fire Protection Associationrecommendations.SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEngineering controlsPersonal protective equipmentRespiratory protectionHand protectionEye protectionSkin and body protection: Use of non-sparking and explosion-proof equipment may be necessarydepending on type of operation. Use only in area provided with appropriateexhaust ventilation. Use appropriate workplace ventilation to remove fumesthat may be released on heating. Use an airless flow type of spray applicator.Keep spraying pressure below 60 psi.: In case of mist, spray or aerosol exposure wear suitable personal respiratoryprotection and protective suit.: Additional protection: Impervious gloves: Wear safety glasses or coverall chemical splash goggles.: Where there is potential for skin contact, have available and wear asappropriate, impervious gloves, apron, pants, jacket, hood and boots.Exposure GuidelinesExposure Limit Valuesn-Butyl acetatePEL: (OSHA) 150 ppm 710 mg/m3 8 hr. TWATLV (ACGIH) 150 ppm TWA4 / 9

Material Safety Data SheetForaperle ® 225Version 2.1Revision Date 01/17/2012 Ref. 130000005008TLV (ACGIH) 200 ppm STEL* AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits whichare lower than the AEL are in effect, such limits shall take precedence.SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESForm: liquidColor: light yellowOdor: ester-likeFreezing point: -18 °C (0 °F)Boiling range: 120 °C (248 °F) at 760 mm Hg% Volatile : 70 - 80 %Vapour Pressure: 8 mm Hg at 20 °C (68 °F)Density: 0.968 g/cm3 at 20 °C (68 °F)Water solubility: insolubleSECTION 10. STABILITY AND REACTIVITYStability: Stable under normal conditions.Conditions to avoidIncompatibilityHazardous decompositionproducts: To avoid thermal decomposition, do not overheat.: strong oxidizers: Incompletely burned carbon products , Carbon dioxide , Carbon monoxide,Hydrofluoric acid...%Other hazardous decomposition products may be formed.SECTION 11. TOXICOLOGICAL INFORMATIONForaperle ® 225Inhalation 4 h ALC : >105.8 mg/m3 , rat, aerosolDifficulty in breathinglung effects5 / 9

Material Safety Data SheetForaperle ® 225Version 2.1Revision Date 01/17/2012 Ref. 130000005008Oral LD50 : > 2,000 mg/kg , ratSkin irritation : slight irritation, rabbitEye irritation : Eye irritation, rabbitSensitisation : Did not cause sensitization on laboratory animals., guinea pign-Butyl acetateDermal LD50 : > 17,652 mg/kg , rabbitRepeated dose toxicity : OralratKidney damageInhalationratRespiratory tract irritation, Reduced body weight gainInhalationrabbitIncreased liver enzyme levels in serumMutagenicity: Evidence suggests this substance does not cause genetic damage inanimals.Reproductive toxicity : No toxicity to reproductionTeratogenicity : Animal testing showed effects on embryo-fetal development at levelsequal to or above those causing maternal toxicity.SECTION 12. ECOLOGICAL INFORMATIONAquatic ToxicityForaperle ® 2256 / 9

Material Safety Data SheetForaperle ® 225Version 2.1Revision Date 01/17/2012 Ref. 13000000500848 h EC50 : Daphnia magna (Water flea) 56 mg/l16 h Growth inhibition : Pseudomonas putida >= 100 mg/ln-Butyl acetate96 h LC50 : Pimephales promelas (fathead minnow) 19 mg/lEnvironmental FateForaperle ® 225Biodegradability : Not readily biodegradable.SECTION 13. DISPOSAL CONSIDERATIONSWaste Disposal: In accordance with local and national regulations.SECTION 14. TRANSPORT INFORMATIONDOT UN number : 1123Proper shipping name : Butyl acetates solutionClass : 3Packing group: IIILabelling No. : 3Reportable Quantity: 5,000 lbs n-Butyl acetateIATA_C UN number : 1123Proper shipping name: Butyl acetates solutionClass : 3Packing group: IIILabelling No. : 3IMDG UN number : 1123Proper shipping name : Butyl acetates solutionClass : 3Packing group: IIILabelling No. : 37 / 9

Material Safety Data SheetForaperle ® 225Version 2.1Revision Date 01/17/2012 Ref. 130000005008SECTION 15. REGULATORY INFORMATIONTSCA Status: On the inventory, or in compliance with the inventorySARA 313 RegulatedChemical(s)Title III hazardclassificationCERCLA ReportableQuantityCalifornia Prop. 65PA Right to KnowRegulated Chemical(s)NJ Right to KnowRegulated Chemical(s): SARA 313: This material does not contain any chemical components withknown CAS numbers that exceed the threshold (De Minimis) reporting levelsestablished by SARA Title III, Section 313.: Acute Health Hazard: YesChronic Health Hazard: NoFire: YesReactivity/Physical hazard: NoPressure: No: 6,689 lbsBased on the percentage composition of this chemical in the product.:n-Butyl acetate: Chemicals known to the State of California to cause cancer, birth defects orany other harm: none known: Substances on the Pennsylvania Hazardous Substances List present ata concentration of 1% or more (0.01% for Special HazardousSubstances): n-Butyl acetate: Substances on the New Jersey Workplace Hazardous Substance Listpresent at a concentration of 1% or more (0.1% for substancesidentified as carcinogens, mutagens or teratogens): n-Butyl acetateSECTION 16. OTHER INFORMATIONHMISHealth : 2Flammability : 3Reactivity/Physical hazard : 0PPE: Personal Protection rating to besupplied by user depending on use8 / 9

Material Safety Data SheetForaperle ® 225Version 2.1Revision Date 01/17/2012 Ref. 130000005008conditions.Foraperle ® and The DuPont Oval Logo ®are registered trademarks or trademarks of E. I. du Pont de Nemours and Company or its affiliates.Contact person: MSDS Coordinator, DuPont Chemicals and Fluoroproducts, Wilmington, DE19898, (800) 441-7515The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief atthe date of its publication. The information given is designed only as a guidance for safe handling, use, processing,storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Theinformation relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process, unless specified in the text.Significant change from previous version is denoted with a double bar.9 / 9