SAFETY DATA SHEET - Arco

SAFETY DATA SHEETEU regulation 1907/2006/EEC - (REACH)Page: 1 of 5Print Date: 08/07/20081. IDENTIFICATION OF SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKINGPRODUCT NAME:HEAVY DUTY ADHESIVEUSE:Open system operated by non trained consumer.APPLICATION CONDITIONS: Non Chlorinated AdhesiveSUPPLIER:Arco LimitedP.O. Box 21Waverly StreetHull, HU1 2SJ : United KingdomEmail: sales@arco.co.uk2. HAZARDS IDENTIFICATIONMOST IMPORTANT HAZARDS:SPECIFIC HAZARDS:Harmful to the aquatic environment, irritating to skin and eyes.Extremely flammable, Vapours may cause drowsiness or dizziness, Repeatedexposure may cause skin dryness or cracking3. COMPOSITION/INFORMATION ON INGREDIENTSIDENTIFICATION OF THE PREPARATIONA mixture of resins, organic solvents and organic gases.CHEMICAL NAME CAS-No EC-No CLASS WEIGHT REGISTRATION-NoPropan-2-one 67-64-1 200-662-2 R11, R36, R66, R67 15-40% -Naphtha (petroleum) 64742-49-0 265-151-9 F; R11 Xi; R38 N; 15-40% -hydrotreated lightR51/53, R65, R67Butane 106-97-8 203-448-7 F+; R12 10-30% -Propane 74-98-6 200-827-9 F+; R12 10-30% -Contains no known PBT’s or vPvB’s4. FIRST AID MEASURESGENERAL ADVICE:INHALATION:SKIN CONTACT:EYE CONTACT:INGESTION:In all cases of doubt, or when symptoms persist, seek medical attention. Never giveanything by mouth to an unconscious person.Remove to fresh air, keep the patient warm and at rest. If breathing is irregular orstopped, administer artificial respiration. Give nothing by mouth. If unconscious, placein recovery position and seek medical advice.Remove contaminated clothing immediately and wash affected skin with soap and water.DO NOT use solvents or thinners as skin cleaning agents.Contact lenses should be removed. Promptly wash eyes with lots of water while liftingthe eyelids. Continue to rinse for at least 15 minutes and get medical attention.If swallowed, seek medical advice immediately and show this container or label. Do notinduce vomiting.5. FIRE-FIGHTING MEASURES

SAFETY DATA SHEETEU regulation 1907/2006/EEC - (REACH)Page: 2 of 5Print Date: 08/07/2008SUITABLE EXTINGUSING MEDIA:EXTINGUISING MEDIA WHICH MUSTNOT BE USED FOR SAFETY REASONS:SPECIFIC HAZARDS:SPECIAL PROTECTIVE EQUIPMENTFOR FIREFIGHTERS:Recommended use: Alcohol resistant foam, carbon dioxide (CO2), drypowder, water spray. Do not use water jet. Cool containers with spraywater.Do NOT use high pressure inert gas or water jets.Fire may produce dense black smoke containing hazardous combustionproducts (see heading 10). Decomposition products may be a hazard tohealth. Do not allow run-off from fire fighting to enter drains or watercourses.In the event of fire, wear self contained breathing apparatus.6. ACCIDENTAL RELEASE MEASURESPERSONAL PRECAUTIONS:ENVIRONMENTAL PRECAUTIONS:METHODS FOR CLEANING UP:Remove all sources of ignition. Ensure adequate ventilation. Evacuatepersonnel to safe areas. Avoid breathing vapours. Refer to protectivemeasures listed in sections 7 and 8.DO NOT allow to enter drains or watercourses. If the product enters drainsor sewers, the local water company should be informed immediately. In thecase of contamination of streams, rivers or lakes, inform the relevantenvironment Agency. Vapours are heavier than air and may spread alongfloors. Vapours may form explosive mixture with air.Contain and collect spillage with non-combustible absorbent materials, (e.g.sand, earth, vermiculite, diatomaceous earth) and place in a suitablecontainer for disposal in accordance with the waste regulations (see section13). Clean the spill area preferably with a detergent. Avoid the use ofsolvents.7. HANDLING AND STORAGEHANDLING:GENERAL:STORAGEKeep, the aerosol in a cool, dry place. Exclude sources of heat, sparksand open flame. Do not use sparking tools around aerosols. Avoid skinand eye contact. Avoid inhalation of vapour and spray mist. Forpersonal protection, see section 8. Prevent the creation of flammable prexplosive concentrations of vapour in air and avoid vapourconcentrations higher than the occupational exposure limits. Never applypressure to the aerosol, the aerosol is a pressurised object and mayexplode if pressure is applied.The accumulation of vapours in an enclosed space may result inspontaneous combustion, use only in well ventilated areas. Useresponsibly and in the correct manner. Wear the appropriate personalprotective equipment, as outlined in section 8.Observe label precautions. Store between 5 and 25ºC in a dry, wellventilated place away from sources of heat, ignition and direct sunlight.No smoking. Store separately from oxidising agents and stronglyalkaline and strongly acidic materials.8 . EXPOSURE CONTROLS/ PERSONAL PROTECTION

SAFETY DATA SHEETEU regulation 1907/2006/EEC - (REACH)Page: 3 of 5Print Date: 08/07/2008CHEMICAL NAME:Long Term RefNaphtha (petroleum) hydrotreated light 200ppm SUP1000mgm-38hr TWA (1) 15min (2) Type (4)(3) RefPropan-2-one 1810mgm -3 3620mgm -3 WEL SUP(1) Long term exposure limits – 8hr time weighted average(2) ‘SUP’ Suppliers reccomendationENGINEERING MEASURES:Provide adequate ventilation. All PPE used to control exposure to hazardoussubstances must be selected to meet the requirements of the COSHHregulations.PERSONAL PROTECTION EQUIPMENT:RESPIRATORY PROTECTION:HAND PROTECTION:EYE PROTECTION:SKIN & BODY PROTECTION:If exposure to hazardous substances identified cannot be controlled by theprovision of local exhaust ventilation and good general extraction, suitablerespiratory protective equipment should be worn.When skin exposure may occur, advice should be sought from glovesuppliers on appropriate types and usage times for this product. Theinstructions and information provided by the glove supplier on use, storage,maintenance and replacement must be followed. Barrier creams may help toprotect exposed areas of skin, but are not substitutes for full physicalprotection. They should not be applied once exposure has occurred.Eye protection designed to protect against liquid splashes should be worn.Grossly contaminated clothing should be removed and the skin washed withsoap and water or a proprietary skin cleaner.9. PHYSICAL AND CHEMICAL PROPERTIESFORM:FLASHPOINT:COLOUR:ODOUR:AerosolNot known for blendBrownNaphtha10. STABILITY AND REACTIVITYSTABILITY:CONDITIONS TO AVOID:MATERIALS TO AVOID:HAZARDOUS DECOMPOSTION PRODUCTS:Stable under the recommended storage and handling conditions(see section 7).Applying heat or pressure to the aerosol may result in explosionand fire. Naked flames, smoking, wet and damp storageconditions and mishandling may also result in explosion and fire.Keep away from oxidising agents, strongly alkaline and stronglyacidic materials in order to avoid exothermic reactions.In a fire, hazardous decomposition products such as smoke,carbon monoxide, carbon dioxide and oxides of nitrogen may beproduced.11. TOXICOLOGICAL INFORMATIONACUTE TOXICITY:Gas or vapour is harmful on prolonged contact or in high concentration. This chemical

SAFETY DATA SHEETEU regulation 1907/2006/EEC - (REACH)Page: 4 of 5Print Date: 08/07/2008LOCAL EFFECTS:SENSITIZATION:CHRONIC TOXICITY:LONG TERM TOXICITY:can be hazardous when inhaled and/or touched. Irritant of eyes and mucous membranes.Narcotic effect. CNS depressant. Acute eczematous dermatitis, contact type erythema,oedema, papules, vesicles, bullae, crusts, desquamation.Hazardous in case of skin contact, irritant.Repeated exposure may cause chronic eye irritation. May cause chemical eye burns.Swallowing concentrated chemical may cause severe internal injury, unconsciousness,and death.Contains no known category 1 or 2 carcinogens, mutagens or reproductive toxicants12. ECOLOGICAL INFORMATIONMOBILITY:PERSISTENCE AND DEGRADABILITY:BIOACCUMULATION:ECOTOXICITY EFFECTS:ENDOCRINE DISRUPTING POTENTIAL:Insoluble in water; will float on water. The majority of this productwill evaporate within a day from water or soil surfaces leaving achemical that will bind to particulate matter to form sediments.The majority of this product is inherently biodegradable, oxidisingrapidly by photochemical reactions in air. The remaining chemicalsdegrade in soil abiotically to form smaller molecules, which are eitherbiodegraded in soil or volatised into the air.This product has the potential to bioaccumulate.This product is classified as harmful to aquatic organisms and maycourse long term adverse effects in the aquatic environment.Contains no known substances that require a chemical safety report13. DISPOSAL CONSIDERATIONSWASTE FROM RESIDUES / UNUSED PRODUCTS:CONTAMINATED PACKAGING:Do not allow to enter drains or water courses or dispose ofwhere ground or surface waters may be affected.Wastes, including emptied aerosols, are controlled wastesand should be disposed of in accordance with regulationsmade under the Control of Pollution Act and theEnvironmental Protection Act. Using the informationprovided in this safety data sheet, advice should beobtained from the relevant environment agency whether thespecial waste regulations apply.14. TRANSPORT INFORMATIONUN NUMBER: UN1950SHIPPING NAME AerosolsHAZARD CLASS: 2.1 (For Sea Transport). Classification code 5fEmS:F-D, S-UCLASS: 2LABELLING: 2.115. REGULATORY INFORMATIONSYMBOLS:

SAFETY DATA SHEETEU regulation 1907/2006/EEC - (REACH)Page: 5 of 5Print Date: 08/07/2008Extremely Flammable IrritantR-PHRASE(S): R12 Extremely flammableR36/38 Irritating to skin and eyesR52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR66 Repeated exposure may cause skin dryness or crackingR67 Vapours may cause drowsiness and dizzinessS-PHRASE(S): S2 Keep out of the reach of childrenS9 Keep container in a well ventilated placeS16 Keep away from sources of ignition – no smokingS23 Do not breathe gas/fumes/vapour/sprayS24/2 5 Avoid contact with skin and eyesS29/35 Do not empty into drains; dispose of this material and its container in a safe wayS36 Wear suitable protective clothingS46 If swallowed, seek medical advice immediately and show this container or labelS51 Use only in well-ventilated areasNo chemical safety assessments have been carried out for any of the substances used in this preparation.16. OTHER INFORMATIONUSES ADVISED AGAINST:The product should not be used for any other purposes other than its intended use.Handling, storage and conditions to avoid instructions must be followed at all times.The information contained in this safety data sheet is provided in accordance with the requirements of the Chemical(Hazard Information and Packaging) Regulations. The information we have provided is correct to the best of ourknowledge, information and belief at the date of its publication. The information given is designed only as guidance forsafe handling, use, processing, storage, transportation, disposal and release and is not considered a warranty or qualityspecification. The information relates only to the material designated and may not be valid for such material used incombination with any other materials or in any process unless specified in the text.