2308 MERGAL K2N (English) SDS EU Contextual V3.1.3 2nd ATP ...

Conforms to 91/155/EEC - 2001/58/EC - EuropeSAFETY DATA SHEETMERGAL K2N1.Identification of the substance/preparation and of the company/undertakingProduct nameEmergency telephone number: MERGAL K2NManufacturer: TROY CHEMICAL EUROPE BVUiverlaan 12ePO Box 1323145 XN MaassluisThe NetherlandsPhone: + 31 (0) 10 592-7494Fax: +31 (0) 10 592-8877Supplier: TROY CHEMICAL COMPANY BVUiverlaan 12ePO Box 1323145 XN MaassluisThe NetherlandsPhone: + 31 (0) 10 592-7494Fax: +31 (0) 10 592-8877: +32 (0) 14 58 45 45Application: : Sanitizing solution, biocidal wash.2.Composition / information on ingredientsSubstance/Preparation:PreparationChemical name*CAS No. % EC Number ClassificationN-Decyl-n,n- dimethyl-1- decanaminiumchloride 7173-51-5 7-10 230-525-2 Xn; R22C; R34(Ethylenedioxy) dimethanol 3586-55-8 7-10 222-720-6 Xn; R22Isopropyl alcohol 67-63-0 3-5 200-661-7 F; R11Xi; R36R67See Section 16 for the full text of the R Phrases declared above* Occupational Exposure Limit(s), if available, are listed in section 83.Hazards identificationThe preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.ClassificationEffects and symptoms:R10C; R34Skin Contact : Corrosive to skin on contact.Eye ContactAggravating conditions::Hazardous in case of eye contact (corrosive).Repeated or prolonged exposure is not known to aggravate medical condition.4.First-aid measuresFirst-Aid measuresInhalation :Ingestion:Skin Contact:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention immediately.Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosentight clothing such as a collar, tie, belt or waistband.In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removingcontaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.Date of issue : April 23, 2003. Page: 1/5

MERGAL K2NEye Contact :Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for atleast 15 minutes. Cold water may be used. Get medical attention immediately.5.Fire-fighting measuresExtinguishing MediaSuitableHazardous thermal (de)compositionproductsSpecial fire-fighting proceduresProtection of fire-fighters::::SMALL FIRE: Use DRY chemical powder.LARGE FIRE: Use alcohol foam, water spray or fog. Cool containing vessels with water jet in order to preventpressure build-up, autoignition or explosion.These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), halogenated compounds,hydrogen chloride.Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.Be sure to use an approved/certified respirator or equivalent.6. Accidental release measuresPersonal precautionsEnvironmental Precautions andClean-up Methods::Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self-contained breathing apparatus should beused to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult aspecialist BEFORE handling this product.Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basementsor confined areas; dike if needed.Note: See section 8 for personal protective equipment and section 13 for waste disposal.7.Handling and storageHandlingStoragePackaging materialsRecommended use:::Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all equipmentcontaining material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with eyes. Ifingested, seek medical advice immediately and show the container or the label.Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep containertightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).Use original container.8. Exposure controls/personal protectionEngineering measuresHygiene measuresIngredient Name::Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors belowtheir respective occupational exposure limits. Ensure that eyewash stations and safety showers are proximal tothe work-station location.Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, usinglavatory, and at the end of day.Occupational Exposure LimitsIsopropyl alcohol ACGIH (United States, 1994).STEL: 500 mg/m 3TWA: 400 mg/m 3Recommended monitoringproceduresPersonal protective equipmentRespiratory systemSkin and bodyHandsEyes:::::Not determined.Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate.Lab coat.Gloves.Splash goggles.9.Physical and chemical propertiesPhysical stateColorOdorpHBoiling PointMelting PointFlash point:::::::Liquid.Clear. Colorless to light yellow.Slight.3 to 6 [Acidic.]100°C (212°F)Not determined.CLOSED CUP: 52°C (125.6°F).Date of issue : April 23, 2003. Page: 2/5

MERGAL K2NAutoignition temperature:Explosive properties:Lower explosion limit:Oxidizing Properties :Vapor PressureDensitySolubility:::Viscosity:Vapor Density:Evaporation rate (butyl acetate = 1) :The lowest known value is 399°C (750.2°F) (Isopropyl alcohol).Not applicable.The greatest known range is LOWER: 2% UPPER: 12% (Isopropyl alcohol)Not available.Not determined.1.04 to 1.06 g/cm 3 (20°C / 68°F)Easily soluble in cold water, hot water.Dynamic: The highest known value is 2.43 cP (Isopropyl alcohol)The highest known value is 2.07 (Air = 1) (Isopropyl alcohol).The highest known value is 1.5 (Isopropyl alcohol) Weighted average: 0.42compared to (n-BUTYLACETATE=1)10.Stability and reactivityStabilityHazardous Decomposition Products11.Acute toxicityLocal effectsSpecific effectsToxicological informationIngredient NameDidecyl dimethyl ammonium chlorideSkin irritationEye irritationChronic toxicity12.ISOPROPYL ALCOHOLCarcinogenic EffectsMutagenic EffectsDevelopmental and TeratogenicEffectsEcotoxicity DataEcological information::::::::The product is stable.These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), halogenated compounds,hydrogen chloride.Test Result Route SpeciesLD50LD50LD50200 to 2000 mg/kg268 mg/kg3342 mg/kgOralOralDermalRatMouseRatLD505045 mg/kg OralRatLD506410 mg/kg OralRabbitLD503600 mg/kg OralMouseLD5012800 mg/kg DermalRabbitLDLo1537 mg/kg OralDogLDLo5272 mg/kg OralmanLDLo3570 mg/kg OralHuman/30 minLC5016000 ppm (8 INHALATION Rathours)Hazardous in case of skin contact (corrosive).Hazardous in case of eye contact (corrosive).Repeated or prolonged exposure is not known to aggravate medical condition.Classified None. by NIOSH [Isopropyl alcohol]. Classified 3 (Not classifiable for human.) by IARC [Isopropylalcohol].Classified None. for human [Isopropyl alcohol].Ingredient NameSpecies Period ResultDidecyl dimethyl ammonium chloride Trout 96 hours 2 mg/l13.Disposal considerationsMethods of disposal ; Waste ofresidues ; Contaminated packaging:Waste must be disposed of in accordance with federal, state and local environmental control regulations.Waste Classification:European Waste Catalogue (EWC) :Hazardous Waste :Not applicable.070499The classification of the product may meet the criteria for a hazardous wasteDate of issue : April 23, 2003. Page: 3/5

MERGAL K2N14. Transport informationInternational transport regulationsUN number Proper shipping nameUN2924 Flammable liquid, corrosive, n.o.s. (Contains: Isopropyl alcohol, Quarternary ammonium compound)RegulatoryInformationClassPackingGroupLabelAdditional informationADR/RID Class3 FCIIILimited QuantityLQ7TRANSPORT EMERGENCYCARD (Road)3830GFC-IIIIMDG Class 3 IIIEmergency Schedules (EmS)F-E, S-C3IATA-DGR Class3III-315.Regulatory informationEU RegulationsHazard symbol(s):Risk PhrasesSafety PhrasesContainsProduct UseGermany Hazard class forwater::::CorrosiveR10- Flammable.R34- Causes burns.S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).N-Decyl-n,n- dimethyl-1- decanaminiumchloride 230-525-2Industrial applications.: 2 (Annex 4 VwVwS)Date of issue : April 23, 2003. Page: 4/5

MERGAL K2N16.Other informationFull text of R-Phrases with no.appearing in Section 2 - EuropeText of classifications appearing inSection 2 - EuropeHISTORYDate of printingDate of issueDate of Previous IssueVersionPrepared by:::::::R11- Highly flammable.R22- Harmful if swallowed.R34- Causes burns.R36- Irritating to eyes.R67- Vapors may cause drowsiness and dizziness.F - Highly flammableC - CorrosiveXn - HarmfulXi - IrritantJune 19, 2003.April 23, 2003.No Previous Validation.No Previous Validation.No Previous Validation.No Previous Validation.2Notice to ReaderClassification and labeling have been performed according to EU directives 1999/45/EC and 2001/58/EC, including amendments and the intended use.To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumesany liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used withcaution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.Version 2Page: 5/5