Hydrometallurgical process for extraction of metals...
Hydrometallurgical process for extraction of metals...
Hydrometallurgical process for extraction of metals...
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Kamberović et al- <strong>Hydrometallurgical</strong> <strong>process</strong> <strong>for</strong> <strong>extraction</strong> <strong>of</strong> <strong>metals</strong>... 237<br />
Table 3. Chemical composition <strong>of</strong> WPCBs each fraction in wt.%<br />
mm Cu Zn Ni Fe Pb<br />
5.000 11.06 1.89 1.79 5.99 0.89<br />
2.500 30.50 2.25 1.93 0.18 0.71<br />
2.000 30.24 2.28 1.21 2.28 1.53<br />
1.800 24.14 2.04 0.29 0.13 0.78<br />
1.250 35.31 1.73 1.07 1.20 3.85<br />
1.000 33.38 2.23 0.36 1.22 7.15<br />
0.800 27.62 2.21 0.61 0.51 5.91<br />
0.630 28.99 1.68 0.59 0.88 3.56<br />
0.500 40.42 1.81 0.61 1.45 3.44<br />
0.400 40.16 1.24 0.97 1.30 3.50<br />
0.315 23.17 1.27 0.61 1.68 3.76<br />
0.250 14.44 1.18 0.31 1.77 2.09<br />
0.100 7.87 1.31 0.20 2.36 1.50<br />
-0.100 6.32 2.89 0.58 5.22 2.12<br />
Fraction +5mm contained ~6% <strong>of</strong> Fe, which means that magnetic separation was<br />
not efficient enough <strong>for</strong> this size <strong>of</strong> particles.<br />
XRF spectrometry was used <strong>for</strong> direct analysis <strong>of</strong> granulated PCBs samples.<br />
Characteristic parts like contacts, solders and composites were analysed. XRF analysis<br />
was per<strong>for</strong>med on Skyray EDX 3000. Measurement spots labeled lom-1 to 4 are<br />
presented at Figure 2 and results in Table 4.<br />
Figure 2. Measurement spots <strong>for</strong> XRF analysis