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Multiple choice question

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If �H f ° = 3400 cal/mol, then calculate standard free energy for ozone<br />

formation at 298 K<br />

iz'u&40 cQZ ds fi?kyus dh 25°C ij xyu ,UFksYih 6.97 KJ mol –1 gS rFkk xyu dh<br />

,UVªkWih 25.4 J mol –1 K –1 gSA eqDr ÅtkZ ifjorZu dh x.kuk dhft;s\ ;g<br />

fu/kkZfjr Hkh dhft;s fd bl rki ij cQZ Lor% fi?kyuh pkfg;s vFkok ugha\<br />

The enthalpy of fusion for ice at 25°C is 6.97 KJ mol –1 and entropy of fusion<br />

is 25.4 J mol –1 K –1 Calculate the value of free energy change? Also decide<br />

whether ice should melt or not automatically at this temperature?<br />

iz'u&41 400 K ij fuEu jklk;fud vfHkfØ;k ds fy;s lkE; fLFkjkad (K) dh x.kuk<br />

dhft;s\ (�H° = 80 KJ mol –1 rFkk �S° = 120 JK –1 mol –1 )<br />

2NOCl 2NO + Cl (g) (g) 2(g)<br />

For the following chemical reaction calculate value for chemical equilibrium<br />

constant (K) at 400K (�H° = 80 KJ mol –1and<br />

�S° = 120 JK–1 mol –1 )<br />

iz'u&42 jklk;fud vfHkfØ;k x y ds fy;s ekud ,UVªkWih ifjorZu dh x.kuk<br />

dhft;s] ;fn 298 K ij �H° = 28.4 KJ rFkk K = 1.8 x 10 –7 fn;k x;k gksA<br />

If �H° = 28.4 KJ and K = 1.8 x 10 –7 is given then for a chemical reaction<br />

x y calculate standard entropy change?<br />

iz'u&43 fuEu vfHkfØ;k ds fy;s vfHkdkjdksa ds ,d&,d eksy }kjk vfHkfØ;k 27°C ij<br />

vkjEHk djkbZ xbZA tc vfHkfØ;k ds vfHkdkjdksa dsk 2@3 Hkkx iz;qDr gks x;k<br />

rc tkdj lkE; dh fLFkfr igq¡phA vfHkfØ;k %&<br />

CH 3 COOH (l) + C 2 H 5 OH (l) CH 3 COOC 2 H 5(l) + H 2 O (l) ,<br />

ds fy;s eqDr ÅtkZ ifjorZu Kkr dhft;s\<br />

For the reaction :–<br />

CH 3 COOH (l) + C 2 H 5 OH (l) CH 3 COOC 2 H 5(l) + H 2 O (l) ,<br />

initially at 27°C one geam mol of each reactant was taken to start the reaction,<br />

41

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