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45. Toluene reacts with Cl 2 in the presence of light togive -(A) Benzyl chloride (B) Benzoyl chloride(C) p-chlorotoluene (D) o- chlorotoluene46. Which compound is formed when excess of KCN isadded to an aqueous solution of copper sulphate(A) Cu (CN) 2 (B) K 2 [Ca(CN) 4 ](C) K [Cu(CN) 2 ] (D) K 3 [Cu(CN) 4 ]47. The Blue Print Process involves the use of-(A) Indigo dyes (B) Iron compound(C) Vat dyes (D) some other compounds48. The ionic radii of N 3– , O 2– , F – and Na + follow theorder-(A) N 3– > O 2– > F – > Na + (B) N 3– > Na + > O 2– > F –(C) Na + > O 2– > N 3– > F – (D) O 2– > F – > Na + > N 3–49. Reactionxy 2 xy + y(g) (g) (g)Initial pressure of xy 2 is 600 mm Hg & total pressureat equilibrium is 800 mm Hg. Kp of reaction is -(A) 50 (B) 100 (C) 166.6 (D) 40050. Cell: Zn|Zn +2 || Cu +2 | CuIf the correct reactions of Zn +2 & Cu +2 ions aredoubled, the emf of the cells:(A) doubled (B) halved(C) same(D) zero51. What is the pH of buffer solution containing 12gCH 3 COOH & 16.4g CH 3 COONa in 500ml ofsolution (Ka for CH 3 COOH = 1.8×10 –5 ).(A) 4.7447 (B) 4.4774(C) 4.4477(D) None52. How many moles of ferrous oxalate are completelyoxidized by 1 mole KMnO 4 in acidic medium-(A) 3/5 (B) 5/3(C) 1/5 (D) 553. In an irreversible process taking place at constant-T& P and which only pressure-volume work is beingdone, than (dG) and (dS), satisfy the criteria-(A) (dS) V, E > 0, (dG) T,P < 0(B) (dS) V, E = 0, (dG) T,P = 0(C) (dS) V, E = 0, (dG) T,P > 0(D) (dS) V, E < 0, (dG) T,P < 054. 3,3-dimethylbutan-2-ol, on reaction with Conc.H 2 SO 4 at 443K will give…… as major product-(A) 3,3-dimethyl but-1-ene(B) 2,3-dimethyl but-2-ene(C) 2,2-dimethyl but-2-ene(D) 2,2-dimethyl-1- butene55. Select the true statement about benzene fromamongst the following-(A) Because unsaturation benzene easily undergoesaddition reaction(B) There are two types of C-C bonds in benzenemolecule(C) There is a cyclic delocalisation of π es – inbenzene(D) Monosubstitution of benzene group gives threeisomeric substances56.(A)(C)OHZndustH CCl3⎯⎯⎯→B⎯⎯− ⎯⎯ →K4⎯ alk.KMnOAlCl3⎯⎯ ⎯⎯ →D. Identity ‘D’ ?CH 3CHO(B)(D)COOH57. In Lassaigne’s test, the organic compound isfirst fused with sodium metal. The sodiummetal is used because(A) The melting point of sodium metal is low(B) Sodium metal reacts with elements presentin organic compounds to form inorganiccompounds(C) All sodium salts are soluble in water(D) All the above58. Concentrated hydrochloric acid when kept in open airsometimes produces a cloud at white fumes theexplanation for it is that-(A) Oxygen in air reacts with the emitted HCl gas toform a cloud of chlorine gas(B) Strong affinity of HCl gas for moisture in airresults in forming of droplets of liquid solutionwhich appears like a cloudy smoke(C) Due to strong affinity for water concentratedhydrochloric acid pulls moisture of air towardsitself. This moisture forms droplets of water andhence the cloud.(D) Concentrated hydrochloric acid emits stronglysmelling HCl gas all the time59. Consider the following complex[Co(NH 3 ) 5 CO 3 ]ClO 4The coordination number, oxidation number, numberof d-electrons and number of unpaired electrons onthe metal respectively-(A) 6, 3, 6, 0 (B) 7, 2, 7, 1(C) 7, 1, 6, 4 (D) 6, 2, 7, 3XtraEdge for IIT-JEE 73APRIL 2010

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