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Max-Born-Institut Berlin (MBI)

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Fig. 3<br />

A sketch of an optical interferometer. An optical<br />

beam is split at a beam splitter and the<br />

two parts of the beam follow different optical<br />

paths. In the overlap region the beams interfere.<br />

The interference pattern contains information<br />

that will allow us to reconstruct both<br />

Fig. 4<br />

A time line showing the duration of the shortest optical<br />

pulses that could be produced. You will see that we<br />

have just crossed the attosecond threshold. The period<br />

of the Bohr orbit for valence electrons in atoms and<br />

molecules is ~ 100 attoseconds. Pulses shorter than ~<br />

100 attoseconds allow us to “freeze” electron motion.<br />

A related set of images occupied the front cover of the October 19 th edition of Scientific American<br />

in 1878. If we could make similar images of molecules as they undergo chemical reactions,<br />

then we could “watch” chemical processes as they unfold, just as Muyerbridge’s photos<br />

allowed him to watch the real motion of the horse.<br />

You, the reader, may say that <strong>Max</strong> <strong>Born</strong> would have objected. “Quantum Mechanics” he might say,<br />

“showed that it is impossible to obtain sharp images” and he would be correct. The image that we<br />

obtain is the image of a wave. However, anyone who visits a wave pool and or sits on a beach<br />

watching ocean waves break on the shore, knows that images of waves are also arresting.<br />

One last thing before I begin to discuss how attosecond images can be recorded. <strong>Max</strong> <strong>Born</strong><br />

wrote a very famous textbook on optics that is still used today [3]. He would have told you that<br />

we often use an interferometer to characterize light waves. Figure 3 is a sketch of an optical<br />

interferometer. Light entering from the bottom of the figure encounters a beam splitter (which<br />

is really a mirror that partially transmits light). Some of the light beam passes through the mirror,<br />

and some reflects from it. The part that reflects is directed back and overlaps the part that<br />

passed through. As the light beams intersect, the light waves interfere with each other. By measuring<br />

the interference pattern, we can determine everything about the light waves in each<br />

beam – their spatial pattern, their frequency, etc. It is as if we could see the individual waves<br />

in each light beam. I will now show you how to make an electron interferometer in a single<br />

molecule [4].<br />

When setting out to make an electron interferometer that can image the molecule’s electron,<br />

you will immediately be confronted by three challenges: First, “how can we split the molecule’s<br />

electron?” I will show you that it can be done with an intense laser pulse. Second, “how<br />

can we make the electron return to interfere with itself?” I will also show you that this happens<br />

naturally when an intense laser pulse splits the electron. And finally, “how can we see the<br />

interference if it occurs?” That brings me back to the title of my talk “attosecond imaging.” I<br />

will show you that the attosecond optical pulses or trains of optical pulses are produced by this<br />

interference, and therefore measuring the attosecond pulses is equivalent to measuring the<br />

interference.<br />

The ability to generate attosecond pulses is the culmination of 40 years of development of<br />

short-pulse laser science and technology. Lasers were achieved experimentally in 1960. In my<br />

opinion, the laser was one of the major developments of the second half of the 20 th century.<br />

And just like quantum mechanics before it, laser science built on pre-existing science – in this<br />

case optics and quantum mechanics. Furthermore, just as quantum mechanics transformed the<br />

science that followed, lasers are now transforming experimental science.<br />

Attosecond Pulses<br />

<strong>Max</strong> <strong>Born</strong> • Paul Corkum 35

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