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Manual for Refrigeration Servicing Technicians - UNEP - Division of ...

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2<br />

Refrigerants<br />

Characteristics<br />

An important characteristic <strong>of</strong> many <strong>of</strong> the synthetic lubricants,<br />

such as POE and PAG oils, is that they are more hygroscopic<br />

than mineral oils as shown in the diagram below. They saturate at<br />

approximately 1000 ppm from atmospheric moisture, compared to<br />

about 100 ppm <strong>for</strong> mineral oils. The POE lubricants are considerably<br />

less hygroscopic than PAG lubricants. This diagram shows lubricant<br />

compatibility <strong>for</strong> some refrigerants.<br />

MOISTURE CONTENT<br />

TIME (HOURS)<br />

Hygroscopy <strong>of</strong> POE and mineral lubricants<br />

PAG<br />

POE<br />

MINERAL<br />

10 000 PPM<br />

1000 PPM<br />

100 PPM<br />

Refrigerant Mineral<br />

Oil (MO)<br />

Alkyl<br />

benzene<br />

(AB)<br />

Appropriate Lubricant<br />

Polyol<br />

Ester<br />

(POE)<br />

Poly alpha<br />

oelfin<br />

(PAO)<br />

Chapter 4 <strong>of</strong> this manual presents in<strong>for</strong>mation about the problems moisture<br />

can create in a system, and how to deal with them.<br />

52<br />

Poly alkyl<br />

glycol<br />

(PAG)<br />

CFC-11 � � � � �<br />

CFC-12 � � � � �<br />

R-502 � � � � �<br />

HCFC-22 � � � � �<br />

HCFC-123 � � � � �<br />

HFC-134a � � � � �<br />

HFC-404A � � � � �<br />

HFC-407C � � � � �<br />

HFC-410A � � � � �<br />

HFC-507A � � � � �<br />

HC-600a � � � � �<br />

HC-290 � � � � �<br />

R-717 (NH 3 ) � � � � �<br />

R-744 (CO 2 ) � � � � �<br />

�: Good Suitability �: Application with limitations �: Not Suitable

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