Manual for Refrigeration Servicing Technicians - UNEP - Division of ...
Manual for Refrigeration Servicing Technicians - UNEP - Division of ...
Manual for Refrigeration Servicing Technicians - UNEP - Division of ...
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2<br />
Refrigerants<br />
Safety characteristics<br />
CHAPITRE 2<br />
PAGE 06<br />
According to various international and national safety standards,<br />
refrigerants may be allocated one <strong>of</strong> six safety classifications<br />
Refrigerant are classified in terms <strong>of</strong> two general safety criteria: toxicity and<br />
flammability.<br />
according to its toxicity and flammability. This classification<br />
consists <strong>of</strong> two alpha-numeric characters (e.g. A2); the capital letter<br />
Toxicity: Both acute (short-term) and chronic (long-term) toxicity corresponds to toxicity and the digit to flammability. The toxicity<br />
are considered as they affect human safety during handling and classification is determined by a refrigerants’ TLV-TWA, such that<br />
servicing with refrigerants, and <strong>for</strong> occupants in refrigerated or air it may be lower toxicity “A” or higher toxicity “B”. There are no<br />
conditioned spaces. The acute-toxicity exposure limit (ATEL) is refrigerants that are non-toxic.<br />
the maximum recommended refrigerant concentration intended to<br />
reduce the risks <strong>of</strong> acute toxicity hazards to humans in the event <strong>of</strong><br />
a refrigerant release. For chronic toxicity, the threshold limit value-<br />
The flammability classification may be no flame propagation “1”,<br />
lower flammability “2” or higher flammability “3”.<br />
time weighted average (TLV-TWA) is the time -weighted average<br />
concentration <strong>for</strong> a normal 8-hour workday<br />
and a 40-hour workweek, to which nearly all<br />
These classifications are shown in this table:<br />
workers may be repeatedly exposed, day after<br />
day, without adverse effect.<br />
LOWER TOXITY HIGHER TOXITY<br />
Flammability: Refrigerant flammability can<br />
A3<br />
affect the safety <strong>of</strong> people and property<br />
mainly during handling and servicing activities,<br />
A2<br />
and it influences the design <strong>of</strong> equipment.<br />
The flammability <strong>of</strong> a refrigerant is judged<br />
A1<br />
according to the lower flammability limit<br />
(LFL), which is the lowest concentration <strong>of</strong><br />
the refrigerant mixed in air, required <strong>for</strong> it to<br />
be able to be ignited. Flammability is also considered according to<br />
the refrigerants’ heat <strong>of</strong> combustion (HOC), which is the amount <strong>of</strong><br />
energy released when it burns.<br />
B3<br />
B2<br />
B1<br />
HIGHER FLAMMABILITY<br />
LOWER FLAMMABILITY<br />
NO - FLAME PROPAGATION<br />
Safety Classifications according to ISO 817, EN 378 and ASHRAE 34<br />
standards<br />
37