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Manual for Refrigeration Servicing Technicians - UNEP - Division of ...

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2<br />

Refrigerants<br />

Safety characteristics<br />

CHAPITRE 2<br />

PAGE 06<br />

According to various international and national safety standards,<br />

refrigerants may be allocated one <strong>of</strong> six safety classifications<br />

Refrigerant are classified in terms <strong>of</strong> two general safety criteria: toxicity and<br />

flammability.<br />

according to its toxicity and flammability. This classification<br />

consists <strong>of</strong> two alpha-numeric characters (e.g. A2); the capital letter<br />

Toxicity: Both acute (short-term) and chronic (long-term) toxicity corresponds to toxicity and the digit to flammability. The toxicity<br />

are considered as they affect human safety during handling and classification is determined by a refrigerants’ TLV-TWA, such that<br />

servicing with refrigerants, and <strong>for</strong> occupants in refrigerated or air it may be lower toxicity “A” or higher toxicity “B”. There are no<br />

conditioned spaces. The acute-toxicity exposure limit (ATEL) is refrigerants that are non-toxic.<br />

the maximum recommended refrigerant concentration intended to<br />

reduce the risks <strong>of</strong> acute toxicity hazards to humans in the event <strong>of</strong><br />

a refrigerant release. For chronic toxicity, the threshold limit value-<br />

The flammability classification may be no flame propagation “1”,<br />

lower flammability “2” or higher flammability “3”.<br />

time weighted average (TLV-TWA) is the time -weighted average<br />

concentration <strong>for</strong> a normal 8-hour workday<br />

and a 40-hour workweek, to which nearly all<br />

These classifications are shown in this table:<br />

workers may be repeatedly exposed, day after<br />

day, without adverse effect.<br />

LOWER TOXITY HIGHER TOXITY<br />

Flammability: Refrigerant flammability can<br />

A3<br />

affect the safety <strong>of</strong> people and property<br />

mainly during handling and servicing activities,<br />

A2<br />

and it influences the design <strong>of</strong> equipment.<br />

The flammability <strong>of</strong> a refrigerant is judged<br />

A1<br />

according to the lower flammability limit<br />

(LFL), which is the lowest concentration <strong>of</strong><br />

the refrigerant mixed in air, required <strong>for</strong> it to<br />

be able to be ignited. Flammability is also considered according to<br />

the refrigerants’ heat <strong>of</strong> combustion (HOC), which is the amount <strong>of</strong><br />

energy released when it burns.<br />

B3<br />

B2<br />

B1<br />

HIGHER FLAMMABILITY<br />

LOWER FLAMMABILITY<br />

NO - FLAME PROPAGATION<br />

Safety Classifications according to ISO 817, EN 378 and ASHRAE 34<br />

standards<br />

37

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