12.07.2015 Views

II Alkanes, Alkenes, and Alkynes

II Alkanes, Alkenes, and Alkynes

II Alkanes, Alkenes, and Alkynes

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Conformational Isomers: Isomers that differ as a result of the degree ofrotation around a carbon-carbon single bondLet us take Ethane as an example to describe alkane conformation:Conformation or orientations of alkanes can be expressed using several differentmethods:A) Sawshorse Diagram: A way of representing conformational isomers withstick drawingsB) Newman Projection: A way of representing conformational isomers usingan end-on projection of a carbon-carbon bondEclipsed: Conformation around a carbon-carbon single bond in which attachedatoms are as close together as possibleStaggered: Conformation around a carbon-carbon single bond in which attachedatoms are as far apart as possibleTorsional or Dihedral Angle: Angle between the bonds in the Newman Projection4

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