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Sensitivity <strong>of</strong> Molecular Vibrations to ΔμSensitivity <strong>of</strong> interval:∂Ω / ΓFOM 1 ≡ × 10∂μ/μ−15( number <strong>of</strong> line widths shifted,in response to Δμ / μ = 10 −15 )Monitoring <strong>the</strong> nth vibrational harmonic oscillator state:E ≈nω∝nnvibμ − 1/2FOM 1Maximize FOM 1 by monitoring:• a high-n level• <strong>of</strong> a tightly bound oscillator—large ω vib• <strong>with</strong> narrow linewidth=12nω vibΓ