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52. G. Vassilikogiannakis, M. Orfanopoulos, Tetrahedron Lett., 39, 8891, (1998) "A Mechanistic ComparisonBetween [2+2] and [4+2] Cycloadditions of Tetracyanoethylene to 2,7-Dimethyl-2,trans-4, 6-octatriene. AVery Remote Secondary Isotope Effect"53. G. Vassilikogiannakis, M. Stratakis, M. Orfanopoulos, C. S. Foote J. Org. Chem. 64, 4130, (1999)"Stereochemistry in the Ene Reactions of Singlet Oxygen and Triazolinediones with Allylic Alcohols. AMechanistic Comparison.54. G. Vassilikogiannakis, M. Orfanopoulos, J. Org. Chem. 64, 3392, (1999)“Regio- and Stereoselectivity of the [2+2] Photocycloaddition of Acyclic Enones to C 60 ”.55. N. Chronakis, M. Orfanopoulos, Org. Lett. 1, 1909, (1999) “ Ene Reaction of Arylallyl Alkenes with C 60 . AMechanistic Approach.”56. M. Stratakis, M. Orfanopoulos, Tetrahedron 56, 1595 (2000), Review. "Regioselectivity in the EneReaction of Singlet Oxygen with Alkenes"57. M. Hatzimarinaki, G. Vassilikogiannakis, M. Orfanopoulos, Tetrahedron Lett., 41, 4667, (2000) "Stereochemistry and Steric Isotope Effect on the [2 + 2] Photocycloaddition ofDimethyl-p-Methoxystyrene to C 60 : The Nature of the Transition State Structures"58. G. Vassilikogiannakis, Y. Elemes, M. Orfanopoulos, J. Am. Chem. Soc 122, 9540, (2000)"Stereochemistry of the Trazollinedione-Alkene Ene reaction: A Stereospecific Suprafacial Transformation"59. G. Vassilikogiannakis, M. Stratakis, M. Orfanopoulos , Org. Lett 2, 2245, (2000) "Isotope Effects and synSelectivity in the Ene Reaction of Triazolinedione with Conjugated Enones: Aziridinium Imide or an OpenIntermediate Mechanism? "60. G. Vassilikogiannakis, M. Hatzimarinaki, M. Orfanopoulos, J. Org. Chem. 65, 8180, (2000) Mechanism ofthe [2 + 2] Photocycloaddition of Fullerene C 60 with Styrenes61. N. Chronakis, M. Orfanopoulos, Tetrahedron Lett. in 42, 1201, (2001) “Concerted Diels-Alder ReactionBetween Anthracene and C 60 "62. N. Chronakis, M. Orfanopoulos, Org. Lett 3, 345, (2001) “[4+2] Cycloadditions of Rigid s-cis Dienes to C 60 .A Synchronous Diels-Alder Reaction”63. Y. S. Angelis. N.S. Hatzakis, I. Smonou and M. Orfanopoulos, Tetrahedron Lett., 42, 3753, (2001)“Oxidation of Benzyl Alcohols by Dimethyldioxirane. The Question of Concerted versus stepwiseMechanisms Probed by Kinetic Isotope Effects.”64. M. Stratakis, M. Hatzimarinaski, M. Orfanopoulos, J. Org. Chem. 66, 3682, (2001)“Stereochemistry in thereaction of 4-methyl-1,2,4-triazoline-3,5-dione (MTAD) with -dimethyl-p-methoxystyrene. Are openbiradicals the reaction intermediates?65. N. Chronakis, G. C. Vougioukalakis, M. Orfanopoulos, Org. Lett 4, 945, (2002) “Synthesis and SelfPhotooxygenation of Alkenyl-Linked [60]Fullerene Derivatives. A Regioselective Ene Reaction”66. N. Chronakis, G. Froudakis, M. Orfanopoulos, J. Org. Chem. 67, 3284, (2002), “Stereochemistry of the[4+2] Cycloadditions of trans,trans- and cis,trans-2,4-Hexadiene to C 60 ”67. W. Adam, O. Krebs, M. Orfanopoulos, M. Stratakis, J. Org. Chem. 67, 8395, (2002), “Control ofRegioselectivity by the lone Substituent through Steric and Electronic Effects in the Nitrosoarene EneReaction of Deutetium-Labeled Trisubstituted Alkenes”68. W. Adam, N. Bottke, O. Krebs, I. Lykakis, M. Orfanopoulos, M. Stratakis, J. Am. Chem. Soc 124, 14403,(2002) “Ene Reactions of Singlet Oxygen, Triazolinedione, and Nitrosoarene with ChiralDeuterium-Labeled Allylic Alcohols: The Interdependence of Diastereoselectivity and RegioselectivityDiscloses Mechanistic Insights into the Hydroxy-Group Directivety”6