Clairol Professional Basic White Powder Lightener

Material Safety Data SheetIssuing Date: 24-May-2013 Revision Date: 24-May-2013 Version 1Product ID: 010610061. PRODUCT AND COMPANY IDENTIFICATIONProduct nameProduct TypeRecommended useSynonymsManufacturerE-mail AddressEmergency telephoneBASIC WHITE POWDER LIGHTENERFinished Product - Consumer (Retail) and Professional UsePersonal Beauty Care ProductNo information availableThe Procter & Gamble CompanySharon Woods Innovation Center11510 Reed Hartman HighwayCincinnati OH 45202pgsds.im@pg.comTransportation (24 HR)CHEMTREC - 1-800-424-9300(U.S./ Canada) or 1-703-527-3887Mexico toll free in country: 01-800-681-95312. HAZARDS IDENTIFICATIONEmergency OverviewHarmful if swallowedRisk of serious damage to eyesIrritating to respiratory system and skinMay cause sensitization by inhalation and skin contactOSHA Regulatory StatusWHMISConsumer Products as defined by the U.S. Consumer Product Safety Act which are usedas intended (typical consumer duration and frequency) are exempt from the OSHA HazardCommunication Standard. When used in a professional setting (at a much higher frequencyand duration than a typical consumer) this material would be considered hazardous by theOSHA Hazard Communication Standard (29 CFR 1910.1200).Not subject to WHMIS classification._____________________________________________________________________________________________Page 1 / 9

01061006 - BASIC WHITE POWDER LIGHTENER Revision Date: 24-May-2013_____________________________________________________________________________________________Principle Routes of ExposureGeneral HazardsEye Contact. Ingestion. Skin Contact. Inhalation.This is a personal care or cosmetic product that is safe for consumers and other usersunder normal and reasonably foreseeable use3. COMPOSITION/INFORMATION ON INGREDIENTSChemical Name CAS-No Weight %Dipotassium peroxodisulphate 7727-21-1 15 - 40Diammonium peroxodisulphate 7727-54-0 10 - 30Disodium metasilicate 6834-92-0 10 - 30Octadecanoic acid, sodium salt (1:1) 822-16-2 7 - 13Sulfuric acid monododecyl ester sodium salt (1:1) 151-21-3 1 - 5Glycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-,sodium salt (1:2)139-33-3 1 - 54. FIRST AID MEASURESGeneral adviceEye ContactSkin ContactIngestionInhalationProtection of First-aidersMost important symptoms/effects,acute and delayedNotes to PhysicianWhen symptoms persist or in all cases of doubt seek medical advice.Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Consult aphysician. Get medical attention immediately if symptoms occur.If skin problems occur, discontinue use. May cause an allergic skin reaction. Wash offimmediately with soap and plenty of water. Remove and wash contaminated clothing beforere-use. If symptoms persist, call a physician.If swallowed. Clean mouth with water and afterwards drink plenty of water. Do NOT inducevomiting. Never give anything by mouth to an unconscious person. Consult a physician.Move to fresh air. Get medical attention if irritation persists. May cause allergic respiratoryreaction. Get medical attention immediately if symptoms occur.Use personal protective equipment.None known.Treat symptomatically.5. FIRE-FIGHTING MEASURESFlash PointSuitable extinguishing mediaNo information availableDry chemical, CO 2, water spray or alcohol-resistant foam.Extinguishing media which shall notNo information availablebe used for safety reasonsSpecial HazardThese are strong oxidizers and will react vigorously or explosively with many materialsincluding fuels_____________________________________________________________________________________________Page 2 / 9

01061006 - BASIC WHITE POWDER LIGHTENER Revision Date: 24-May-2013_____________________________________________________________________________________________Special protective equipment forfire-fightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gear.6. ACCIDENTAL RELEASE MEASURESPersonal precautionsAdvice for emergency respondersEnvironmental precautionsMethods for ContainmentMethods for Cleaning upAvoid dust formation. Avoid contact with the skin and the eyes.Use personal protective equipment.Household: Do not discharge product into natural waters without pre-treatment oradequate dilution. Non-household: Should not be released into the environment.Non-household: Prevent further leakage or spillage if safe to do so. Prevent product fromentering drains.Non-household: Avoid dust formation. Clean up promptly by scoop or vacuum. Keep insuitable, closed containers for disposal. Dispose of in accordance with local regulations.7. HANDLING AND STORAGEAdvice on safe handlingTechnical measures/StorageconditionsKeep out of the reach of children. Observe label precautions.Keep out of the reach of children. Keep containers tightly closed in a dry, cool andwell-ventilated place.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONExposure GuidelinesChemical Name ACGIH TLV OSHA PEL NIOSH IDLH P&G OEL Mexico OELDipotassiumTWA: 0.1 mg/m 3- -peroxodisulphatePersulfateDiammonium TWA: 0.1 mg/m 3- -peroxodisulphatePersulfateChemical Name Alberta Quebec Ontario TWAEV British ColumbiaDipotassiumTWA: 0.1 mg/m 3 TWA: 0.1 mg/m 3peroxodisulphateDiammoniumperoxodisulphateTWA: 0.1 mg/m 3 TWA: 0.1 mg/m 3Engineering MeasuresNot applicable.Personal Protective EquipmentEye ProtectionHand ProtectionSkin and body protectionRespiratory protectionThermal hazardsSafety glasses with side-shields.Rubber/latex/neoprene or other suitable chemical resistant gloves.Wear protective gloves/clothing.Use only with adequate ventilationNot applicable._____________________________________________________________________________________________Page 3 / 9

01061006 - BASIC WHITE POWDER LIGHTENER Revision Date: 24-May-2013_____________________________________________________________________________________________Hygiene measuresHandle in accordance with good industrial hygiene and safety practice. Use personalprotective equipment as required.Environmental Exposure Controls See Section 6.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical State @20°CAppearanceOdorsolidwhite. powder.SharpProperty Values NotepH VALUENo information availablemelting/freezing pointNo information availableBoiling point/boiling range No information availableFlash PointNo information availableEvaporation RateNo information availableflammability (solid, gas)No information availableFlammability Limits in AirUpper Flammability Limit No information availablelower flammability limitNo information availablevapor pressureNo information availableVapor DensityNo information availableRelative DensityNo information availableWater solubilityNo information availableSolubility in other solvents No information availablePartition coefficient: n-octanol/waterNo information availableAutoignition Temperature No information available .decomposition temperature No information available.Viscosity of ProductNo information availableBulk DensityNo information availableChemical NamePartition Coefficient (n-octanol/water)Sulfuric acid monododecyl ester sodium salt (1:1) -2.03 (at 20 C; Computational Approach in OECD Guideline 107)Glycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, sodium salt-4.3(shake-flask; 25 C and pH 4.5)(1:2)VOC ContentProducts comply with US state and federal regulations for VOC content in consumerproducts.Oxidizing propertiesNo information available10. STABILITY AND REACTIVITYReactivityStabilityHazardous PolymerizationHazardous ReactionsConditions to AvoidMaterials to AvoidNone under normal use conditions.Stable under normal conditions.Hazardous polymerization does not occur.None under normal processing.Heat, flames and sparks. Protect from light.Strong reducing agents. Organic material. Alkaline.Hazardous Decomposition Products None under normal use._____________________________________________________________________________________________Page 4 / 9

01061006 - BASIC WHITE POWDER LIGHTENER Revision Date: 24-May-2013_____________________________________________________________________________________________Product Information11. TOXICOLOGICAL INFORMATIONAcute ToxicityPrinciple Routes of ExposureInhalationSkin ContactIngestionEye ContactRisk of serious damage to eyes. May be harmful if swallowed. Irritating to respiratorysystem and skin.Eye Contact. Ingestion. Skin Contact. Inhalation.Irritating to respiratory system. May cause sensitization by inhalation.Irritating to skin. May cause sensitization by skin contact.Harmful if swallowed.Risk of serious damage to eyes.Chemical Name LD50 Oral LD50 Dermal LC50 InhalationDipotassium peroxodisulphate = 802 mg/kg ( Rat ) - -Diammonium peroxodisulphate = 495 mg/kg ( Rat ) - = 520 mg/L ( Rat ) 1 hDisodium metasilicate 1280.00 mg/kg (rat) > 5000 mg/kg bw (Guideline:EPA OPPTS 870.1200, Rat,Read across information(Potassium silicate solution) isprovided.)Sulfuric acid monododecyl ester 1200 mg/kg bw (OECD 401, > 2000 mg/kg bw (Expertsodium salt (1:1)Rat )assessment)Glycine,N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, sodium salt (1:2)Chronic toxicity> 2.06 mg/L air (Guideline: EPAOPPTS 870.1300, Rat, Readacross information (Potassiumsilicate solution) is provided.)> 3900 mg/m 3 ( Rat ) 1 h2800 mg/kg bw (Rat) - 1 - 5 mg/l (rat) (4hCorrosivitySensitizationNeurological EffectsReproductive toxicityMUTAGENIC EFFECTSDevelopmental ToxicityTeratogenicityCarcinogenicityNo known effect.May cause sensitization by inhalation and skin contact.No known effect.The product contains no substances known to be hazardous to health in concentrationswhich need to be taken into account.There are no known mutagenic chemicals in this product.No known effect.No known effect.Contains no ingredients above reportable quantities listed as a carcinogen._____________________________________________________________________________________________Page 5 / 9

01061006 - BASIC WHITE POWDER LIGHTENER Revision Date: 24-May-2013_____________________________________________________________________________________________EcotoxicityAcute Toxicity12. ECOLOGICAL INFORMATIONChemical Name Toxicity to algae Toxicity to fish Toxicity tomicroorganismsDiammoniumperoxodisulphateDisodium metasilicateSulfuric acid monododecylester sodium salt (1:1)Glycine,N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, sodium salt(1:2)- LC50 96 h = 103 mg/LLepomis macrochirusstatic LC50 96 h =76.3 mg/LOncorhynchus mykissstatic LC50 96 h = 323mg/L Poeciliareticulata207 mg/L(Desmodesmussubspicatus; Basis foreffect: Biomass, Readacross data on SolubleSilicates)210 mg/L (Guideline:ISO 7346-1;Brachydanio rerio )> 120 mg/L (DIN 29 mg/L (OECD 203,38412, part 9; Pimephales promelas,Desmodesmus flow-through)subspicatus, based ongrowth rate)> 60 mg/L (Readacross data onFe(III)EDTA; OECD201; static;Pseudokirchnerellasubcapitata)41 mg/L (Read acrossdata onEthylenediaminetetraacetic acid; static;Lepomis macrochirus )Toxicity to daphniaand other aquaticinvertebrates- EC50 48 h = 120 mg/LDaphnia magna1000 mg/L (Guideline: 1700 mg/L (Guideline:DIN 38412-27; EU Method C.2;Pseudomonas putida ) Daphnia magna. Readacross data (ofpotassiumdichromate). )135 mg/L (Activatedsludge, respirationrate)EC10: > 500 mg/L(OECD 209; static;activated sludge,domestic)5.55 mg/L(Ceriodaphnia dubia,flow-through)140 mg/L (Guideline:DIN 38412, part 11;static; Daphniamagna)Toxicity to otherorganisms----Chemical Name Toxicity to algae Toxicity to fish Toxicity toMicroorganismsSulfuric acid monododecylester sodium salt (1:1)Glycine,N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, sodium salt(1:2)30 mg/L (DIN 38412, > 1.357 mg/Lpart 9; Desmodesmus (Pimephales promelas,subspicatus, based on 42 d)biomass)48.4 mg/L (Readacross data onFe(III)EDTA; OECD201; static;Pseudokirchnerellasubcapitata)Persistence and degradability .>=25.7 mg/L (Readacross data onCaNa2EDTA; OECD210; flow-through;Danio rerio)Toxicity to daphniaand other aquaticinvertebrates25 mg/L (Guideline:EEC GuidelineXI/681/86, Draft 4;semi-static; Daphniamagna)Toxicity to otherorganismsChemical Name Ready Test Results Other Degradability / Persistence TestResultsDisodium metasilicateReadily eliminable from waterSulfuric acid monododecyl ester sodium salt (1:1) 95% (OECD 301 B; 28 d, CO2 evolution )Glycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-,sodium salt (1:2)Bioaccumulative potential .54.9% (Guideline: PN-88/C-05561; O2consumption)0-20% (CO2 evolution in soil)Chemical NameGlycine, N,N'-1,2-ethanediylbis[N-(carboxymethyl)-, sodium salt (1:2)Bioconcentration factor (BCF)1.8 (Read across data on Ethylenediaminetetraacetic acid (EDTA),tetrasodium salt; Lepomis macrochirus)MobilityNo information available._____________________________________________________________________________________________Page 6 / 9

01061006 - BASIC WHITE POWDER LIGHTENER Revision Date: 24-May-2013_____________________________________________________________________________________________Other adverse effectsNo information available13. DISPOSAL CONSIDERATIONSWaste from Residues / UnusedProductsContaminated packagingCalifornia Hazardous Waste Codes(non-household setting)Household: Do not discharge product into natural waters without pre-treatment oradequate dilution. Non-household: Should not be released into the environment. Disposeof in accordance with local regulations.Dispose of in accordance with local regulations.33114. TRANSPORT INFORMATIONDOTUN/ID noUN1479Proper shipping nameOxidizing solid, n.o.s.Hazard Class 5.1Packing groupIIIDescriptionUN1479, Oxidizing solid, n.o.s (Dipotassium Peroxodisulphate, DiammoniumPeroxodisulphate), 5.1, III, Ltd. Qty.Emergency Response Guide 140NumberTDGUN/ID noUN1479Proper shipping nameOxidizing solid, n.o.s.Hazard Class 5.1Packing groupIIIDescriptionUN1479, Oxidizing solid, n.o.s (Dipotassium Peroxodisulphate, DiammoniumPeroxodisulphate), 5.1, III, Ltd. Qty.MEXUN/ID noUN1479Proper shipping nameOxidizing solid, n.o.s.Hazard Class 5.1Packing groupIIIDescriptionUN1479, Oxidizing solid, n.o.s (Dipotassium Peroxodisulphate, DiammoniumPeroxodisulphate), 5.1, III, Ltd. Qty.IATAUN/ID noUN1479Proper shipping nameOxidizing solid, n.o.s.Hazard Class 5.1Packing groupIIIERG Code5LDescriptionUN1479, Oxidizing solid, n.o.s (Dipotassium Peroxodisulphate, DiammoniumPeroxodisulphate), 5.1, III, Ltd. Qty.ICAOUN/ID noUN1479_____________________________________________________________________________________________Page 7 / 9

01061006 - BASIC WHITE POWDER LIGHTENER Revision Date: 24-May-2013_____________________________________________________________________________________________Proper shipping nameOxidizing solid, n.o.s.Hazard Class 5.1Packing groupIIIDescriptionUN1479, Oxidizing solid, n.o.s (Dipotassium Peroxodisulphate, DiammoniumPeroxodisulphate), 5.1, III, Ltd. Qty.IMDG/IMOUN/ID noUN1479Proper shipping nameOxidizing solid, n.o.s.Hazard Class 5.1Packing groupIIIEmS No.F-A, S-QDescriptionUN1479, Oxidizing solid, n.o.s (Dipotassium Peroxodisulphate, DiammoniumPeroxodisulphate), 5.1, III, Ltd. Qty.U.S. Federal Regulations15. REGULATORY INFORMATIONSARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemicalor chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:Chemical Name CAS-No Weight % SARA 313 - ThresholdValues %Diammonium peroxodisulphate 7727-54-0 21.52 1.0SARA 311/312 Hazard CategoriesAcute Health HazardyesChronic Health HazardNoFire HazardNoSudden Release of Pressure HazardNoReactive HazardyesCERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material.Food and Drug Administration (FDA)The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safeto use as per directions on container, box or accompanying literature (where applicable).Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air ActAmendments of 1990.Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42).U.S. State RegulationsCalifornia Proposition 65This product is not subject to warning labeling under California Proposition 65Chemical NameNew JerseyDipotassium peroxodisulphateXDiammonium peroxodisulphateX_____________________________________________________________________________________________Page 8 / 9

01061006 - BASIC WHITE POWDER LIGHTENER Revision Date: 24-May-2013_____________________________________________________________________________________________Chemical NameDipotassium peroxodisulphateChemical NameDipotassium peroxodisulphateMassachusettsXPennsylvaniaXInternational RegulationsCanadaWHMIS Hazard ClassNot subject to WHMIS classificationThis product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and theMSDS contains all the information required by the CPR. This product is regulated by the Food and Drug Administration of HealthCanada and is therefore exempt from the requirements of CEPA.International InventoriesTSCAProduct is a personal care product and regulated under FDADSLExemptNDSLExemptPerfumes contained with the products comply with appropriate IFRA guidance.LegendTSCA - United States Toxic Substances Control Act Section 8(b) Inventory16. OTHER INFORMATIONIssuing Date:Revision Date:24-May-201324-May-2013DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any other materials or in any process, unlessspecified in the textEnd of MSDS_____________________________________________________________________________________________Page 9 / 9