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CTA Report, Draft 1, ISP Review - US Chemical Safety and Hazard ...

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Table 2<br />

Dust Properties for Determining Fire <strong>and</strong> Explosion <strong>Hazard</strong>s (a)<br />

Elements Properties Significance<br />

Fuel<br />

Explosion<br />

Severity (Kst)<br />

value<br />

Maximum rate of pressure rise normalized to a 1.0-m 3<br />

volume, which is a relative measurement of energy of the<br />

dust explosion. The greater the Kst value, the more<br />

energetic the explosion.<br />

Moisture content Affects ease of ignition <strong>and</strong> ability to sustain an explosion.<br />

Increasing moisture content increases ignition energy (for<br />

some dusts, the increase may be exponential) <strong>and</strong> reduces<br />

explosion severity (i.e., water vapor acts as inert heat sink).<br />

Ignition Minimum ignition<br />

energy (MIE)<br />

Provides information on the lowest energy required to ignite<br />

the most readily ignitable dust/air mixture at atmospheric<br />

pressure <strong>and</strong> room temperature; a combustible dust with a<br />

low MIE is easily ignited. Ignition energies for dust clouds<br />

are usually higher than for gases or vapors—typically a<br />

fraction of a millijoule for gases <strong>and</strong> 1–10 millijoules for<br />

dust.<br />

Oxygen Oxygen content Less oxygen in the air reduces explosion severity by<br />

limiting rate of combustion <strong>and</strong> increases ignition energy.<br />

Suspension/<br />

confinement<br />

Degree of<br />

dispersion<br />

Particle<br />

size/shape<br />

Minimum<br />

explosive<br />

concentration<br />

(MEC)<br />

Usually dependent on the way dust is dispersed <strong>and</strong> level<br />

of turbulence. An evenly suspended <strong>and</strong> less turbulent<br />

dust cloud is more easily ignited <strong>and</strong> burns more easily.<br />

Reduction in particle size increases surface area <strong>and</strong><br />

decreases MIE; the smaller the dust particle, the more<br />

easily it is suspended. Particles with high surface area per<br />

unit volume exhibit low MIE, low MEC, <strong>and</strong> high Kst.<br />

(a) This table highlights the main characteristics of combustible dusts.<br />

Dusts, like gases <strong>and</strong> vapors, form explosive clouds only if<br />

dust concentration lies between certain limits, known as the<br />

lower (LEL) <strong>and</strong> upper explosive limit. For dusts, LEL is<br />

also commonly referred to as MEC.<br />

50

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