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CTA Report, Draft 1, ISP Review - US Chemical Safety and Hazard ...

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Flammability<br />

No. Stability Criteria<br />

4<br />

Severe<br />

3<br />

Serious<br />

2<br />

Moderate<br />

1<br />

Slight hazard<br />

0<br />

Minimal<br />

Table E-1<br />

HMIS Defined Degrees of Flammability <strong>Hazard</strong><br />

Materials that rapidly or<br />

completely vaporize at<br />

atmospheric pressure <strong>and</strong><br />

normal ambient temperature,<br />

or that are readily dispersed<br />

in air <strong>and</strong> readily burn<br />

Liquids <strong>and</strong> solids that can be<br />

ignited under almost all<br />

ambient temperature<br />

conditions; materials that<br />

produce hazardous<br />

atmospheres with air under<br />

almost all ambient<br />

temperatures—or, unaffected<br />

by ambient temperatures, are<br />

readily ignited under almost<br />

all conditions<br />

Materials that must be<br />

moderately heated or<br />

exposed to relatively high<br />

ambient temperatures before<br />

ignition; materials that would<br />

not under normal conditions<br />

form hazardous atmospheres<br />

with air, but under high<br />

ambient temperatures or<br />

moderate heating may<br />

release sufficient quantities of<br />

vapor to produce hazardous<br />

atmospheres with air<br />

Materials that must be<br />

preheated before ignition;<br />

materials that require<br />

considerable preheating for<br />

ignition or combustion under<br />

all ambient temperature<br />

conditions<br />

Typically Includes<br />

Flammable gases<br />

Flammable cryogenic materials<br />

Any liquid or gaseous material that is liquid while<br />

under pressure <strong>and</strong> has a flash point below 73°F <strong>and</strong><br />

a boiling point below 100°F (NFPA Class IA)<br />

Materials that ignite spontaneously in air<br />

Liquids with a flash point below 73°F <strong>and</strong> a boiling<br />

point at or above 100°F (NFPA Class IB); also liquids<br />

with a flash point at or above 73°F <strong>and</strong> a boiling point<br />

below 100°F<br />

Materials that—because of physical form or<br />

environmental conditions—can form explosive<br />

mixtures with air <strong>and</strong> are readily dispersed in air, such<br />

as dusts of combustible solids <strong>and</strong> mists of flammable<br />

or combustible liquid droplets<br />

Materials that burn with extreme rapidity, usually by<br />

reason of self-contained oxygen (e.g., dry<br />

nitrocellulose <strong>and</strong> many organic peroxides)<br />

Liquids with a flash point at or above 100°F but not<br />

exceeding 200°F (i.e., NFPA Classes II <strong>and</strong> IIIA)<br />

Solid materials in the form of coarse dusts that may<br />

burn rapidly but generally do not form explosive<br />

atmospheres<br />

Solid materials in a fibrous or shredded form that may<br />

burn rapidly <strong>and</strong> create flash fire hazards, such as<br />

cotton, sisal, <strong>and</strong> hemp<br />

Solids <strong>and</strong> semisolids that readily give off flammable<br />

vapors<br />

Materials that burn in air when exposed to a<br />

temperature of 1,500°F for 5 minutes or less<br />

Liquids, solids, <strong>and</strong> semisolids with a flash point<br />

above 200°F (NFPA Class IIIB)<br />

Most ordinary combustible materials<br />

Materials that do not burn Any material that does not burn in air when exposed<br />

to a temperature of 1,500°F for 5 minutes<br />

122

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