LYSOL Power Free All-Purpose Cleaner ... - Reckitt Benckiser

...MATERIAL SAFETY DATA SHEETspaceProduct NamespaceCAS #space1. Product and Company IdentificationLYSOL® Power & Free All-Purpose Cleaner - TriggerMixtureThis MSDS is designed for workplace employees, emergency personnel and for otherconditions and situations where there is a greater potential for large-scale or prolongedexposure, in accordance with requirements of the Canadian Workplace HazardousMaterials Information System (WHMIS).This MSDS is not applicable for consumer use of our products. For consumer use, allprecautionary and first aid language is provided on the product label in accordance withthe applicable government regulation.spaceProduct UseManufacturerspaceLEGENDHMIS/NFPASevereSerious43Moderate 2Slight 1Minimal 0spaceEmergency OverviewAll purpose cleanerReckitt Benckiser (Canada) Inc.1680 Tech Avenue Unit #2Mississauga, ON L4W 5S9In Case of Emergency: 1-800-338-6167Transportation Emergencies: 24 Hour Number:North America: CHEMTREC: 1-800-424-9300Outside North America: 1-703-527-3887Health * 1Flammability 1Physical Hazard 0Personal ProtectionB2. Hazards Identification11 0This product is regulated by Health Canada as a disinfectant. Extensive testing has beencompleted to show that it is safe and effective when used as directed.Avoid contact with eyes, skin and clothing. Avoid breathing vapours and mists.spacePotential short term health effectsRoutes of exposurespacespacespaceEyesSkinInhalationspaceIngestionspaceTarget organsspaceChronic effectsspaceSigns and symptomsspacePotential environmental effectsspaceIngredient(s)Hydrogen peroxideCitric acidKeep out of reach of children.Eye, Skin contact, Inhalation, Ingestion.Mildly irritating to the eyes.Slightly irritating to the skin.Not expected to be a skin sensitizer.None expected during normal conditions of use.Health injuries are not known or expected under normal use.Eyes. Respiratory system. Skin.The finished product is not expected to have chronic health effects.Symptoms may include redness, oedema, drying, defatting and cracking of the skin.Symptoms of overexposure may be headache, dizziness, tiredness, nausea andvomiting.Components of this product have been identified as having potentialenvironmental concerns.3. Composition/Information on IngredientsCAS #7722-84-177-92-9Percent0.5 - 1.50.5 - 1.5#22862 Page 1 of 7 Issue date 21-Aug-2012

....spaceFirst aid proceduresEye contactspacespaceSkin contactInhalationspaceIngestionspaceNotes to physicianspaceGeneral advice4. First Aid MeasuresCheck for and remove any contact lenses. If in eyes, IMMEDIATELY rinse eyes withwater. Remove any contact lenses and continue rinsing eyes for at least 15 minutes. Getmedical attention immediately.Get medical attention immediately. In case of contact, immediately flush skin with plentyof water while removing contaminated clothing and shoes. Wash clothing before reuse.Move exposed person to fresh air. Get medical attention immediately.Call medical doctor or poison control center immediately. Wash out mouth with water.Treat patient symptomatically.If you feel unwell, seek medical advice (show the label where possible). Ensure thatmedical personnel are aware of the material(s) involved, and take precautions to protectthemselves. Show this safety data sheet to the doctor in attendance. Avoid contact witheyes and skin. Keep out of reach of children.5. Fire-fighting MeasuresspaceFlammable propertiesspaceExtinguishing mediaspaceSuitable extinguishing mediaUnsuitable extinguishing media Not availablespaceProtection of firefightersSpecific hazards arising from Not availablethe chemicalspaceProtective equipment forfirefighersspaceHazardous combustion productsspaceExplosion dataSensitivity to mechanical impact Not availablespaceSensitivity to static dischargespacePersonal precautionsspaceEnvironmental precautionsspaceMethods for containmentspaceMethods for cleaning upNot flammable by WHMIS criteria.Treat for surrounding material.Firefighters should wear full protective clothing including self contained breathingapparatus.May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides ofsulphur.Not available6. Accidental Release MeasuresKeep unnecessary personnel away. Do not touch or walk through spilled material. Do nottouch damaged containers or spilled material unless wearing appropriate protectiveclothing. Keep people away from and upwind of spill/leak.Do not discharge into lakes, streams, ponds or public waters.Inform the relevant authorities if the product has caused environmental pollution.Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basementsor confined areas.Before attempting clean up, refer to hazard data given above. Small spills may beabsorbed with non-reactive absorbent and placed in suitable, covered, labelledcontainers. Prevent large spills from entering sewers or waterways. Contact emergencyservices and supplier for advice. Never return spills in original containers for re-use.spaceHandling7. Handling and StorageEnsure adequate ventilation.Use good industrial hygiene practices in handling this material.When using do not eat or drink. Avoid contact with skin and clothing.Avoid contact with eyes.Avoid breathing vapours or mists of this product.Do not ingest.Keep container tightly closed.Wash thoroughly after handling.#22862 Page 2 of 7 Issue date 21-Aug-2012

..spaceStoragespaceExposure limit valuesIngredient(s)Citric acidStore in areas inaccessible to small children. Keep securely closed. Refillable. Refilltrigger bottle only with this product. If not refilling, discard in trash or offer for recycle. Donot reuse this trigger for any other purpose.Store in a closed container away from incompatible materials.Store in original container, protected from direct sunlight, in a dry, cool, well ventilatedarea, and away from food and drink.Do not freeze.Store at room temperature.It is a violation of Federal law to use this product in a manner inconsistent with itslabeling.8. Exposure Controls / Personal ProtectionExposure limit valuesACGIH-TLVTWA: 10 mg/m3Hydrogen peroxidespaceACGIH-TLVTWA: 1 ppmEngineering controlsGeneral ventilation normally adequate.spacePersonal protective equipmentConsult the product label for special protection or precautions that have been identifiedfor using this product under directed consumer use conditions. The followingrecommendations are given for workplace employees, emergency personnel and forother conditions and situations where there is a greater potential for large-scale orprolonged exposure.Eye / face protectionNot required under normal use conditions. Safety glasses with side-shields or full eye& face protection should be worn if risk assessment indicates this is necessary for theworkplace or emergency responders.spaceHand protectionNot required under normal use conditions. Chemical resistant, impervious glovesshould be worn if risk assessment indicates this is necessary for the workplace oremergency responders.spaceSkin and body protection As required by employer code.Usual safety precautions while handling the product will provide adequateprotection against injury or irritation.Emergency responders should wear impermeable clothing and footwear whenresponding to a situation where contact with the liquid is possible.spaceRespiratory protectionWhere exposure guideline levels may be exceeded, use an approved NIOSH respirator.Emergency responders should wear self-contained breathing apparatus (SCBA) to avoidinhalation of vapours generated by this product during a spill or other clean-upoperations.spaceGeneral hygiene considerations Handle in accordance with good industrial hygiene and safety practice.When using do not eat or drink.Wash hands before breaks and immediately after handling the product.spaceAppearanceLiquidspaceColourClearspaceFormaqueous solutionspaceOdourCharacteristicspaceOdour thresholdNot availablespacePhysical stateLiquidspacepH 2.1 - 3.5spaceFreezing pointspaceBoiling pointspacePour pointspaceEvaporation RatespaceFlash pointspaceAuto-ignition temperature9. Physical and Chemical PropertiesNot availableNot availableNot availableNot available> 93.3 °C (> 199.94 °F) closed cupNot available#22862 Page 3 of 7 Issue date 21-Aug-2012

..spaceFlammability limits in air, lower, % Not availableby volumespaceFlammability Limits in Air, Upper, % Not availableby VolumespaceVapour pressureNot availablespaceVapour densityNot availablespaceSpecific gravity 1.000 - 1.005spaceOctanol/water coefficientspaceSolubility (H2O)Not availableComplete10. Stability and ReactivityspaceReactivityspacePossibility of hazardous reactionsspaceChemical stabilityspaceConditions to avoidspaceIncompatible materialsThis product may react with oxidizing agents.Hazardous polymerisation does not occur.Stable under recommended storage conditions.Do not freezeExposure to moisture.Keep away from extreme heat.DO NOT MIX WITH BLEACH or use in conjunction with other household products.Caustics. Acids. Oxidizers.CORROSIVE TO METALSspaceHazardous decomposition products May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides ofsulphur.spaceComponent analysis - LC50Ingredient(s)11. Toxicological InformationLC50Citric acidHydrogen peroxidespaceComponent analysis - Oral LD50Ingredient(s)Not availableNot availableLD50Citric acidHydrogen peroxidespaceEffects of acute exposurespacespaceEyeSkinInhalationspaceIngestionspaceSensitisationspaceChronic effectsspaceCarcinogenicityspaceMildly irritating to the eyes.5040 mg/kg mouse; 3000 mg/kg rat75 mg/kg rat; 2000 mg/kg mouseSlightly irritating to the skin.Not expected to be a skin sensitizer.None expected during normal conditions of use.Health injuries are not known or expected under normal use.The finished product is not expected to have chronic health effects.The finished product is not expected to have chronic health effects.The finished product is not expected to have chronic health effects.MutagenicityThe finished product is not expected to have chronic health effects.spaceReproductive effectsThe finished product is not expected to have chronic health effects.spaceTeratogenicityThe finished product is not expected to have chronic health effects.spaceName of Toxicologically Synergistic Not availableProducts#22862 Page 4 of 7 Issue date 21-Aug-2012

...12. Ecological InformationspaceEcotoxicitySee belowEcotoxicity - Freshwater Algae - Acute Toxicity DataHydrogen peroxide 7722-84-1 72 Hr EC50 Chlorella vulgaris: 2.5 mg/LEcotoxicity - Freshwater Fish - Acute Toxicity DataCitric acid 77-92-9 96 Hr LC50 Lepomis macrochirus: 1516 mg/L [static]Hydrogen peroxide 7722-84-1 96 Hr LC50 Pimephales promelas: 16.4 mg/L; 96 Hr LC50 Lepomis macrochirus:18-56 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss: 10.0-32.0 mg/L [static]Ecotoxicity - Water Flea - Acute Toxicity DataCitric acid 77-92-9 72 Hr EC50 Daphnia magna: 120 mg/LHydrogen peroxide 7722-84-1 24 Hr EC50 Daphnia magna: 7.7 mg/L; 48 Hr EC50 Daphnia magna: 18 - 32 mg/L[Static]spacePersistence and degradability Not availablespaceBioaccumulation/accumulation Not availablespaceMobility in environmental media Not availablespaceEnvironmental effectsNot availablespaceAquatic toxicityNot availablespacePartition coefficientNot availablespaceChemical fate informationNot availablespaceOther adverse effectsNot availablespaceDisposal instructionsspaceWaste from residues / unusedproductsspaceContaminated packaging13. Disposal ConsiderationsDispose in accordance with all applicable regulations.Not availableNot available14. Transport InformationspaceU.S. Department of Transportation (DOT)UN 1760, Corrosive liquids, n.o.s. (Citric acid, Hydrogenperoxide), Class 8, PG III, Limited QuantityspaceTransportation of Dangerous Goods (TDG - Canada)UN 1760, CORROSIVE LIQUID, N.O.S. (CITRIC ACID,HYDROGEN PEROXIDE), Class 8, PG III, LimitedQuantity#22862 Page 5 of 7 Issue date 21-Aug-2012

..spaceIMDG (Marine Transport)UN 1760, CORROSIVE LIQUID, N.O.S. (Citric acid,Hydrogen peroxide), Class 8, PG III, Limited QuantityspaceIATA/ICAO (Air)UN 1760, Corrosive liquid, n.o.s. (Citric acid, Hydrogenperoxide), Class 8, PG IIIspaceCanadian federal regulations15. Regulatory InformationThis product has been classified in accordance with the hazard criteria of the ControlledProducts Regulations and the MSDS contains all the information required by theControlled Products Regulations.Product Registration: Registered with TPD, DIN 02382846All components of this product are either on the Domestic Substances List (DSL), theNon-Domestic Substances List (NDSL) or exempt.spaceCanada - WHMIS - Ingredient Disclosure ListCitric acid 77-92-9 1 %Hydrogen peroxide 7722-84-1 1 %spaceWHMIS classification Exempt - Registered product - (DIN 02382946)Inventory StatusCountry(s) or regionCanadaCanadaInventory NameDomestic Substances List (DSL)Non-Domestic Substances List (NDSL)On Inventory (Yes/No)*YesNoA "Yes" indicates that all components of this product comply with the inventory requirements administered by the governingcountry(s)spaceDisclaimer16. Other InformationThis product should only be used as directed on the label and for the purpose intended.To the best of our knowledge, the information contained herein is accurate. However,neither the above named supplier nor any of its subsidiaries assumes any liabilitywhatsoever for the accuracy or completeness of the information contained herein. Finaldetermination of suitability of any material is the sole responsibility of the user. Allmaterials may present unknown hazards and should be used with caution. Althoughcertain hazards are described herein, we cannot guarantee that these are the onlyhazards that exist.#22862 Page 6 of 7 Issue date 21-Aug-2012

spaceFurther information LYSOL® Power & Free All-Purpose Cleaner - Trigger - Citrus Sparkle Zest - 22 fl. oz (1pt. 6 fl. oz.) (650 mL) - 8005137 v1.0LYSOL® Power & Free All-Purpose Cleaner - Trigger - Oxygen Splash - 22 fl. oz (1 pt.6 fl. oz.) (650 mL) - 8006668 v1.0spaceIssue date21-Aug-2012spaceEffective Date21-Aug-2012spaceExpiry Date21-Aug-2015spacePrepared by Reckitt Benckiser Regulatory Department 800-333-3899spaceOther InformationFor an updated MSDS, please contact the supplier/manufacturer listed on the firstpage of the document.This MSDS conforms to the ANSI Z400.1/Z129.1-2010 Standard.#22862 Page 7 of 7 Issue date 21-Aug-2012