Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

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3 APPARATUS 59Fig. 46. Christiansen filter. From ref. 157.3.3.5 Uniform density filtersUniform density filters provide the means of varying the intensity of photochemicalradiation. They are made by the vacuum deposition of thin metal films onquartz plates.3.3.6 Measurement of the intensity of radiation(a) ThermopilesAn absolute method for measuring intensities is to use a calibrated thermopile,bolometer or radiometer and galvanometer system; the first of these is the mostsuitable. Calibration may be carried out at the National Physical Laboratoriesand The National Bureau of Standards, or by using one of their carbon filamentlamps. The thermopiles consist of a bank of interconnected fine-wire thermocouples(Fig. 47). One circuit uses a photoelectric amplifier for the measuring galvanometer(Fig. 48)15*. The image of a tungsten filament F, is projected onto a photocellC by means of a lens L and the galvanometer mirror M. The cell is divided intotwo parts with a common electrode. When the galvanometer is in its null positionthe filament image is symmetrically placed with respect to the two halves. If Mis deflected, the symmetry is destroyed and C registers the effect. Fuller detailsare given in refs. 9 and 22c.References pp. 104-111
60 EXPERIMENTAL METHODS FOR SLOW REACTIONSFig. 47. A line thermopile; (a) arrangement of thermocouple wires, (b) close-up. From ref. 9.\F(.a)(b)Fig. 48. Photoelectric amplifier for a galvanometer. From ref. 158.
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COMPREHENSIVE CHEMICAL KINETICS
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P.O.ELSEVIER PUBLISHING COMPANY335
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Contributors to Volume 1L. BATTDepa
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XCONTENTS4.3 Gas chromatography ...
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XI1CONTENTS4.6 Magnetic measurement
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4 EXPERIMENTAL METHODS FOR SLOW REA
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110 EXPERIMENTAL METHODS FOR SLOW R
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Chapter 2Experimental Methods for t
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114 EXPERIMENTAL METHODS FOR FAST R
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;,124 EXPERIMENTAL METHODS FOR FAST
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178 REFERENCES46 M. EIGEN AND L. DE
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Chapter 3Experimental Methods for t
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182 EXPERIMENTAL METHODS FOR HETERO
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~~~ ._190 EXPERIMENTAL METHODS FOR
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192 EXPERIMENT A L MET H 0 D S F 0
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194 EXPERIMENT A L MET H o D s F o
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206 EXPERXMENTAL METHODS FOR HETERO
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222 EXPERIMENT A L METHODS F 0 R HE
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230 EXPERIMENT A L METHOD s FOR HET
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236 EXPERIMENT A L METHOD s FOR HE
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242 EXPERIMENT A L ME TH 0 D S FOR
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248 EXPERIMENT A L METHOD s F o R H
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254 EXPERIMENTAL MET HODS FOR HETER
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258 EXPERIMENT A L METHODS F 0 R HE
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266 EXPERIMENT A L MET H o D s F o
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270 EXPERIMENTAL MET HODS FOR HE TE
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274 EXPERIMENT A L METHOD s FOR HE
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280 DETECTION AND ESTIMATION OF INT
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344 TREATMENT OF EXPERIMENTAL DATAf
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346 TREATMENT OF EXPERIMENTAL DATAp
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348 TREATMENT OF EXPERIMENTAL DATAg
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350 TREATMENT OF EXPERIMENTAL DATAT
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352 TREATMENT OF EXPERIMENTAL DATAW
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354 TREATMENT OF EXPERIMENTAL DATA[
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358 TREATMENT OF EXPERIMENTAL DATA(
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370 TREATMENT OF EXPERIMENTAL DATAc
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382 TREATMENT OF EXPERIMENTAL DATAa
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41 2 TREATMENT OF EXPERIMENTAL DATA
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41 8 TREATMENT OF EXPERIMENTAL DATA
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420 TREATMENT OF EXPERIMENTAL DATAA
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IndexAabsorption cross section, che
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424 INDEXbenzyl chloride, matrix ph
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426 INDEXchlorine (contdj—, react
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428 INDEXdeuterium oxide, addition
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430 INDEXentropy change, in radical
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432 INDEXfrequency of oscillation,
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434 INDEXhydrogen atoms (contdj—,
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436 INDEXisotopes (contd.J—, use
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438 INDEXmethyl radicals, chain ter
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440 INDEXoctadiene, ESR determinati
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442 INDEXphotoelectric measurement,
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444 INDEXrad, definition of, 66radi
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446 INDEXSchmidt number, and mass t
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448 INDEXTtailing reducer, in gas c
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450 INDEXviscosity, and diffusion c
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Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

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