Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

INDEX 439—, preparation of film of, 183—, Raney, preparation of, 221nickel chloride, for magnetic susceptibility calibration,208nickel electrode, for vibrating condenser method,207nickel formate, decomposition of, 247nickel ions, H z O exchange and, by NMR, 149nickel oxide, chemisorption on, 190—, determination O using, 326, 327—, extinction coefficient of C 2 H 4 adsorbedon, 217—, o-p H t conversion on, 236—, with Fe a 0 3 , sintering of, 256niobium, chemical transport of, 248—, chemisorption on, 190—, cleaning surface of, 182—, preparation of films of, 183nitric oxide, as radical trap, 72, 73, 316—, as,scavenger in radiolysis, 70—, catalysis of o-p H 2 conversion by, 317—, coupling in ESR, 312—, determination by gas chromatography,80—, effect on H a +CI 2 reaction, 76—, excited, and flash photolysis, 293—, in flames, determination of, 287—, ionisation potential of, 284—, quenching by, 5—, reaction + H, 2, 78—, reaction + O and N, 78, 91, 167, 289, 303,320—, reaction + 0 3 , 289nitrobenzene, as Kerr cell filter, 153nitrogen, as carrier gas in gas chromatography,79, 84, 234—, as energy transfer agent, 16, 17—, chemisorption on metals, 190—, collision cross-section for electrons, 330—, desorption from W, kinetics by flash filament,196—, determination by gas chromatography, 80—, effective diffusivity of, 228—, excited, calorimetric determination of, 327—, —, reaction + 0 3 , 283, 305, 323—, in determination of pure diffusivity, 226,227—, in Hg lamps, 41—, liquid, in slush baths, 31, 32—, matrix of, for trapped radicals, 332, $35—, number of collisions of with surface, 187—, radioactive, production of, 67—, solid, luminescence of by ion bombardment,333—, sticking coefficient of, 187—, thermal conductivity of, 82nitrogen atoms, calorimetric determinationof in matrix, 333—, determination by effusion gauge, 328—, — gas titration, 78, 167, 320, 322—, — mass spectroscopy, 299, 300, 303—, — pressure measurement, 324—, — uv spectroscopy, 89, 90—, ESR study of, 313—, reaction + H 2 S, 313—, reaction + NO, 91, 167, 303, 320—, reaction + 0 2 , 167—, reaction + O a , 303—, recombination, emission from, 322nitrogen dioxide, adsorption of, magneticsusceptibility study* 208—, decoupling and ESR, 312—, determination by spectroscopy, 89, 90—, determination by thermal conductivity,97—, determination of O using, 78, 320, 321—, excited, from NO + O s , 289—, flash photolysis of, 293, 305—, reaction + H, 78, 292, 303, 320—, reaction + O, 303nitrogen resonance lamp, 52nitrogen trioxide, determination by IR spectroscopy,90nitrosyl chloride, as actinometer, 61nitrosyl halides, flash photolysis of, 293nitrous oxide, as actinometer, 61as dosimeter in radiolysis, 68as electron trap, 6, 70chemisorption on oxides, 190decomposition of, energy transfer in, 17—, hot O in, 283—, in shock tube, 305for O determination in flames, 318nitroxyl radical (HNO), decomposition of,15—, emission from, 2NS radical, excitedj ESR study of, 313fl-type semiconductor, and adsorption, 213,214, 216nuclear magnetic moment, 143nuclear magnetic resonance, and adsorptionstudies, 208-210—, and analysis, 89—, spectral line broadening, 115, 142-149—, theory of, 142-147nuclear recoil processes, as hot atom sources,: 65, 67nuclei, for solid decomposition, 246nylon threads, use with Langmuir trough,267