Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

INDEX 437—, and study of intermediates, 294-308—, and study of isotope exchange on catalysts,235, 237—, for determination of t-butyl nitrite, 316—, for determination of HD in flames, 172—, for following reactions, 92-95—, ion-molecule reactions in, 64—, quadrupole, 244, 245—, —, and very low pressure flow, 26—, time-of-flight, for concentration measurementsin flames, 171—, —, for determination of intermediates,295, 297, 305mass transfer, and adsorption in solution, 250—, and catalytic reactions in solution, 251,252—, and effectiveness factor, 228—, and effusion gauges, 327—, to catalyst, 222-224mass transfer coefficient, 223, 252matrix, photolysis in, 5—, trapping radicals in, 310, 311, 331-333Maxwell-Boltzmann distribution, and temperaturein flames, 169mechanism, determination of, 2-6, 398, 399,419—, from molecular beam results, 174, 175mercuric chloride, from Hg photosensitisedHC1 decomposition, 78mercury, and photochemical systems, 34—, excited states of, 37, 77, 294—, —, quenching of, 99—, for manometers, 12, 29—, mirror of, to remove O atoms, 326—, spectrum of in matrix, 334mercury cut-offs, see cut-offsmercury dimethyl, decomposition of and massspectroscopy, 299, 300mercury electrode, dropping, for study of adsorptionfrom solution, 250, 251—, for polarograpy, 158mercury lamps, 36-48—, circuits for, 43, 44—, commercial, 40—, emission spectra of, 45—, energy distribution in, 43—, high pressure, 42, 43, 45, 46—, low pressure, 38-42—, medium pressure, 42, 44—, point source, 46, 48, 49—, use in photoelectric emission stuoUetf, 201mercury photosensitisation, 77—, and mass spectroscopy of radicals, 301 *—, of H 2 decomposition, 317—, of HC1 decomposition, 78mercury resonance radiation, 39metal cathodes, in photoemission, 201, 202metal diaphragm gauges, 14metal films, see also films—, preparation by evaporation, 182-184metal ions, complex formation, study by T-jump, 136—, —, study by ultrasonic absorption, 141—, H a O exchange, NMR study, 149—, role in reaction of radical ion and parentmolecule, 151metals, adsorption from solution on, 250, 251—, chemisorption on, 190—, conductivity of and adsorption, 211-213—, dissolution of, 253—, mirrors of, to detect radicals, 72, 314, 315—, molten, as thermostat liquids, 8^-, oxidation of, 245, 246—, supported, for IR studies of adsorption,217metal surfaces, cleaning of, 181—, sticking coefficient on, 187metal vessels, 10, 64methacrylic acid, polymerisation of, ESR study,311methane, chemisorption on metals, 190—, determination by gas chromatography, 80—, — gas titration, 78—, — mass spectroscopy, 281—, efficiency in energy transfer, 17—, from photolysis of C a H 9 , 63—, in radiolysis of Me*N 2 , 63—» pyrolysis of, 315—, —, on C filament, mass spectroscopicstudy, 294—, radiolysis of, 70—, rate of formation in pulsed illumination, 51—, reaction H- I a » 89—, reaction 4- O a , mass spectroscopic study,302—, reaction + O a +O s , IR study, 90—, reaction -f radicals, 3—, thermal conductivity of, 82methanol, determination by mass spectroscopy,281—, exchange with metal ions by NMR, 149—, thermal conductivity of, 82methyl iodide, photolysis of and o-p H a conversion,72—, reaction *f K, molecular beam study, 173,175—, reaction + OH~, rate expression for, 396methyl nitric oxide, determination by IR spectroscopy,90methyl nitrite, determination by polarography,96