Practice of Kinetics (Comprehensive Chemical Kinetics, Volume 1)

IndexAabsorption cross section, chemical, 140absorption of radiation, 35—, and intermittent illumination, 50—, determination of, 55, 63absorption spectra, and determination of intermediates,290-294—, and flash photolysis, 119—, and photochemistry, 35—, of hydrated electron, 122accelerated flow method, 164accelerators, see particle acceleratorsacetaldehyde, as actinometer, 61—, as radical trap, 75—, cool flame, emission of, 286—, —, products of, 281—, decomposition of, 2, 3, 5—, —, and D substitution, 78—, —, chain initiation and termination, 3—, —, order, 2, 14—, —, steady state, time to, 4, 5—, from C a H 4 0 pyrolysis, determination byIR, 90—, reaction + CH 3 , 3, 76—, reaction + NO, 73—, reaction + 0 2 , mass spectrometric study,95acetone, as actinometer, 61—, from Me 3 CO decomposition, 4, 316—, polymerisation in presence of H halides, 71—, thermal conductivity of, 82—, triplet state, quenching of, 5acetylene, as dosimeter, 68—, chemisorption on metals, 190—, collision cross-section for electrons, 330—, determination by gas chromatography, 80—, determination by interferometry, 103—, determination by mass spectrometry, 302—, emission from vibrational!^ excited, 287—, flames, determination of electrons in, 329,330—, —, study of negative ions in by mass spectrometry,308—, from photolysis C 3 H 6 , 63—, reaction + O, ions from by mass spectrometry,307—, reaction + O a -f C 5 H u N0 2 +J>bEt4, flashphotolysis, 120'acetyl radicals, in decomposition of CH 3 CJi6,3acid-base reactions, and fluorescence quenching,156—, rate data for, 162acids, determination by spectroscopy, 290—, effect on EtOH NMR lines, 148—, reaction + hydrated electron, 123actinometry, 35, 61, 62activated complex, see transition stateactivation energy, and explosion, 18—, and microcatalytic reactor, 235—, and NO+O s reaction, 289—, and thermograms, 257-260—, calculation of, 404-406—, for desorption from Sash filament method,195—, of catalytic reaction, and mass transfer,224, 230—, of CH 3 +halogens and H halides, 74—, of diffusion controlled reactions, 253—, of H+D a O, 317—, of N+O a , 167—, of 0+N 2 0, 318—, of radical reactions, 116, 117—, —, and enthalpies, 3, 4active centres, reaction + isoprene, kineticsof, 410-418adiabatic compression, and shock waves, 125—, principle of method, 127adiabatic propagation of sound waves, 139adiabatic reactions, pressure effects in, 2, 17—, rate coefficients for, 30adsorbed volume, determination of, 187-197adsorbed weight, determination of, 197-199adsorption, at liquid interface, 263—, from solution, 249-251—, kinetics of, 189—, of H halides on glass, 10—, of H 2 and H a O on glass, 11—, on semiconductors, 212, 213—, types of, 180ageing, of Hg vapour lamps, 44—, of reaction vessels, 11, 26air, range of high energy particles in, 66alcohols, effect on dissociation constant of aminopyrenes,156aldehydes, determination by polarography, 96—, determination in combustion systems, 280,281, 290alkali metals, adsorption on W, thermionicemission study, 201alkyl halides, pyrolysis of to give carbonaceousfilm, 11—, reaction -f Co(CN) s 8 -, 166alkyl nitrites, pyrolysis of to give carbonaceousfilm, 11